Identification | More | [Name]
4-(Dimethylamino)benzophenone | [CAS]
530-44-9 | [Synonyms]
4-(DIMETHYLAMINO)BENZOPHENONE 4-(N,N-DIMETHYLAMINO)BENZOPHENONE P-(DIMETHYLAMINO)BENZOPHENONE (4-Dimethylamino-phenyl)-phenyl-methanone [4-(Dimethylamino)phenyl](phenyl)methanone [4-(dimethylamino)phenyl]phenyl-methanon [4-(Dimethylamino)phenyl]phenylmethanone 4-Dimethylaminobenzophenon Benzenamine,N,N-dimethyl-4-(phenylmethanone)- Benzophenone, 4-(dimethylamino)- Methanone,[4-(dimethylamino)phenyl]phenyl- p-Benzoyl-N,N-dimethylaniline 4-BENZOYL-N,N-DIMETHYLANILINE | [EINECS(EC#)]
208-478-4 | [Molecular Formula]
C15H15NO | [MDL Number]
MFCD00008311 | [Molecular Weight]
225.29 | [MOL File]
530-44-9.mol |
Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S37/39:Wear suitable gloves and eye/face protection . | [WGK Germany ]
3
| [TSCA ]
Yes | [HS Code ]
29223900 |
Hazard Information | Back Directory | [Chemical Properties]
YELLOW CRYSTALLINE POWDER OR CRYSTALS | [Uses]
4-(Dimethylamino)benzophenone is an important organic intermediate. It can be used in agrochemical, pharmaceutical and dyestuff field. | [Synthesis Reference(s)]
Synthesis, p. 544, 1986 DOI: 10.1055/s-1986-31696 Tetrahedron Letters, 34, p. 7595, 1993 DOI: 10.1016/S0040-4039(00)60409-4 | [Purification Methods]
Crystallise the pale green p-dimethylaminobenzophenone from EtOH. Dissolve 100g in 600mL of boiling EtOH, add 5g of charcoal, cool, isolate the solid by centrifugation and similarly wash the pale crystals with ice-cold EtOH. When filtered by suction, EtOH solution remains on the crystals and turns deep green in air. Dry it in a vacuum and store it in the dark. The hydrazone has m 128-130o and forms a ketyl with potassium. [Hurd & Webb Org Synth Coll Vol I 217 1941, Beilstein 14 H 82, 14 I 288, 14 III 218, 14 IV 248.] |
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