| Identification | More | [Name]
(1S)-(+)-3-Carene | [CAS]
498-15-7 | [Synonyms]
(1S)-3,7,7-TRIMETHYLBICYCLO[4.1.0]HEPT-3-ENE
(1S)-(+)-3-CARENE
(+)-3-CARENE
(1S)-(+)-car-3-ene
(+)-3-CARENE, TERPENE STANDARD
Bicyclo4.1.0hept-3-ene, 3,7,7-trimethyl-, (1S,6R)-
(+)-3-Carene, (1S)-3,7,7-Trimethylbicyclo[4.1.0]hept-3-ene
(1S,6R)-3-Carene
(1S,6α)-3,7,7-Trimethylbicyclo[4.1.0]hept-3-ene
(1α,6α)-3,7,7-Trimethylbicyclo[4.1.0]hepta-3-ene | [EINECS(EC#)]
207-856-6 | [Molecular Formula]
C10H16 | [MDL Number]
MFCD00066417 | [Molecular Weight]
136.23 | [MOL File]
498-15-7.mol |
| Chemical Properties | Back Directory | [Melting point ]
25°C (estimate) | [alpha ]
17 º (NEAT) | [Boiling point ]
170-172 °C(lit.) | [density ]
0.865 g/mL at 25 °C(lit.)
| [vapor pressure ]
2.73hPa at 20℃ | [refractive index ]
n20/D 1.473
| [Fp ]
131 °F
| [storage temp. ]
-20°C | [solubility ]
soluble in Acetone,Ethanol,Benzene | [form ]
liquid (clear)
| [color ]
clear very slightly yellow
| [Odor]
sweet | [optical activity]
[α]20/D +17°, neat | [Water Solubility ]
3.7mg/L at 20℃ | [Merck ]
14,1836 | [BRN ]
1902767 | [LogP]
4.38 at 37℃ | [CAS DataBase Reference]
498-15-7(CAS DataBase Reference) | [NIST Chemistry Reference]
Bicyclo[4.1.0]hept-3-ene, 3,7,7-trimethyl-, (1S)-(498-15-7) | [EPA Substance Registry System]
Bicyclo[4.1.0]hept-3-ene, 3,7,7-trimethyl-, (1S,6R)- (498-15-7) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi,N | [Risk Statements ]
R10:Flammable.
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment . | [Safety Statements ]
S36/37:Wear suitable protective clothing and gloves .
S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet . | [RIDADR ]
UN 2319 3/PG 3
| [WGK Germany ]
2
| [RTECS ]
FH8400000 | [F ]
10-23 | [HS Code ]
2902.19.0050 | [HazardClass ]
3 | [PackingGroup ]
III |
| Hazard Information | Back Directory | [Uses]
Chiral building block for the preparation of bicyclo[3.2.0]heptenes that are useful intermediates in the synthesis of (+)-lineatin and both enantiomers of capnellene. Has been converted to its corresponding allenyl allylic ether for studies of its thermal isomerization chemistry. Precursor to di(4-isocaranyl)borane, an asymmetric hydroboration reagent for olefins. | [Definition]
ChEBI: A car-3-ene (3,7,7-trimethylbicyclo[4.1.0]hept-3-ene) that has S configuration at position 1 and R configuration at position 6. | [Production Methods]
3-Carene is obtained exclusively by fractional
distillation of certain turpentines. | [General Description]
(1S)-(+)-3-Carene is a monoterpene. | [Chemical Reactivity]
3-Carene readily undergoes autoxidation and resinification in air. Addition of pyrogallol or resorcinol as stabilizers is recommended. On treatment with peracetic acid in glacial acetic acid and subsequent saponification, 3-carene is oxidized to 3,4- caranediol.
Pyrolysis at 300–580 ℃ in the presence of Fe(III) oxide on carriers gives p-cymene as the main product. |
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| Company Name: |
Energy Chemical
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021-021-58432009 400-005-6266 |
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http://www.energy-chemical.com |
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