Identification | More | [Name]
D-Glyceraldehyde | [CAS]
453-17-8 | [Synonyms]
D-(+)-GLYCERALDEHYDE D-GLYCERALDEHYDE (r)-2,3-dihydroxy-propanal Glyceraldehyde, D- Triose D-GLYCERALDEHYDE, 80-90 WT. % SOLUTION I N WATER D-GLYCERALDEHYDE MINIMUM 70% D(+)GLYCERALDEHYDE extrapure (R)-(+)-Glyceraldehyde, D-Glyceraldehyde solution D(+)-Glyceraldehyde solution (2R)-2,3-Dihydroxypropanal D-2,3-Dihydroxypropanal D-2,3-Dihydroxypropionaldehyde D-Aldotriose D-Glycerose (2R)-2,3-Dihydroxypropionaldehyde | [EINECS(EC#)]
207-217-1 | [Molecular Formula]
C3H6O3 | [MDL Number]
MFCD00064378 | [Molecular Weight]
90.08 | [MOL File]
453-17-8.mol |
Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S27:Take off immediately all contaminated clothing . S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . | [WGK Germany ]
3
| [F ]
10-23 |
Hazard Information | Back Directory | [Description]
D-(+)-Glyceraldehyde is an intermediate in carbohydrate metabolism. It is phosphorylated by triose kinase to produce D-glyceraldehyde 3-phosphate, an intermediate in glycolysis, gluconeogenesis, photosynthesis, and other metabolic pathways.1,2,3 | [Chemical Properties]
CLEAR ORANGE SYRUP | [Uses]
D-(+)-Glyceraldehyde can be utilized as a reactant in the synthesis of:
- (S)-homophenylalanine by ruthenium oxidation of a 3-amino-1,2-diol generated via coupling of an amine, and α-hydroxyaldehyde.
- β- and γ-allenols via metal-catalyzed cyclization. Allenols are used as a key precursor for the preparation of enantiopure dihydropyrans and tetrahydrooxepines.
- Isopropylidene D-glyceraldehyde intermediate, which controls the chirality in the total synthesis of prostaglandins (PGE1).
| [Uses]
D-Glyceraldehyde is the simplest of all aldoses and have been shown to be the one of the carbonyl metabolite of dietary fructose. | [Definition]
ChEBI: The D-enantiomer of glyceraldehyde. | [Purification Methods]
enantiomer [453-17-8] is a syrup (70 + % H2O) with [] D +14o (c 2, H2O) and the dimethyl acetal has b 124-127 o/14mm and []15 +21o (c 18, H2O). [Beilstein 1 H 845, 1 IV 4114.] |
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Energy Chemical
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