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ChemicalBook--->CAS DataBase List--->443965-10-4

443965-10-4

443965-10-4 Structure

443965-10-4 Structure
IdentificationBack Directory
[Name]

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE
[CAS]

443965-10-4
[Synonyms]

(R)-SIPHOS
(S)-SIPHOS
N-DIMETHYL-[(R)-1,1'-SPIROBIINDANE-7,7'-DIYL]PHOSPHORAMIDITE
N-DIMETHYL-[(S)-1,1'-SPIROBIINDANE-7,7'-DIYL]PHOSPHORAMIDITE
N-Dimethyl-[(S)-1,1'-spirobiindane-7,7'-diyl]phosphoramidite ,98%
N-DIMETHYL-[(S)-1,1-SPIROBIINDANE-7,7-DIYL]PHOSPHORAMIDITE, (S)-SIPHOS
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE
(11AS)-(-)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE
N,N-Dimethylphosphoramidousacid (1S)-(2,2',3,3'-tetrahydro-1,1'-spirobi[1H-indene]-7,7'-diyl) ester
(11aS)-10,11,12,13-Tetrahydro-N,N-dimethyl-diindeno[7,1 -de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine
(11aS)-10,11,12,13-Tetrahydro-N,N-dimethyl-diindeno[7,1 -de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine,99%e.e.
Diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine,10,11,12,13-tetrahydro-N,N-dimethyl-, (11aS)- (9CI)
(11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-dimethylamine,min.98%(S)-SIPHOS
(11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1μ,7μ-fg][1,3,2]dioxaphosphocin-5-dimethylamine, N-Dimethyl-[(S)-1,1μ-spirobiindane-7,7μ-diyl]phosphoramidite
[Molecular Formula]

C19H20NO2P
[MDL Number]

MFCD08459340
[MOL File]

443965-10-4.mol
[Molecular Weight]

325.34
Chemical PropertiesBack Directory
[Melting point ]

95-96°C
[alpha ]

-502° (c 0.5, CH2Cl2)
[storage temp. ]

-20°C
[form ]

solid
[color ]

white
[Sensitive ]

moisture sensitive
Hazard InformationBack Directory
[Chemical Properties]

White to light yellow powder
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H335-H319-H315
[Precautionary statements ]

P264-P280-P305+P351+P338-P337+P313P-P264-P280-P302+P352-P321-P332+P313-P362
[HS Code ]

29252900
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Toluene-->(S)-1,1'-SPIROBIINDANE-7,7'-DIOL-->Hexamethylphosphorous triamide
Questions And AnswerBack Directory
[Reaction]

  1. Chiral ligands for the rhodium-catalyzed asymmetric hydrogenation of α-dehydroamino esters.
  2. Chiral ligands for the rhodium-catalyzed asymmetric hydrogenation of itaconic acid derivatives.
  3. Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of β-dehydroaminoesters.
  4. Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of enamides.
  5. Chiral ligands for rhodium-catalyzed asymmetric Pauson-Khand reaction.
  6. Chiral ligands for palladium-catalyzed asymmetric umpolung allylation of aldehydes. 
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