Identification | More | [Name]
3-BENZYLIDENE-2,4-PENTANEDIONE | [CAS]
4335-90-4 | [Synonyms]
3-BENZYLIDENE-2,4-PENTANEDIONE (2,2-diacetylvinyl)benzene 1,1-Diacetyl-2-phenylethylene 2,4-Pentanedione, 3-(phenylmethylene)- 2,4-Pentanedione, 3-benzylidene- 2-Acetyl-1-phenyl but-1-en-3-one 3-(phenylmethylene)-4-pentanedione 3-benzylidene-4-pentanedione 3-Benzylideneacetylacetone Benzalacetylacetone Benzylidene acetylacetone 3-Acetyl-4-phenyl-3-buten-2-one~(2-Benzylidene)acetylacetone 3-(phenylmethylene)pentane-2,4-dione (2-benzylidene)acetylacetone 3-acetyl-4-phenyl-3-buten-2-one 3-Benzylidenepentane-2,4-Dione | [EINECS(EC#)]
224-382-5 | [Molecular Formula]
C12H12O2 | [MDL Number]
MFCD00014990 | [Molecular Weight]
188.22 | [MOL File]
4335-90-4.mol |
Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36:Wear suitable protective clothing . | [WGK Germany ]
3
| [RTECS ]
SA1930000
| [TSCA ]
Yes |
Hazard Information | Back Directory | [Uses]
3-Benzylidene-2,4-pentanedione may be used in the preparation of:
- Five membered cyclic oxyphosphoranes by reacting with phosphonite esters.
- 5-Hydroxy-N-substituted-2H-pyrrol-2-ones by reacting with alkyl isocyanides.
- 3-Benzylidene-2,4-bis (trimethylsilyloxy)-1,4-pentadiene via trimethylsilylation.
| [Synthesis Reference(s)]
Synthetic Communications, 26, p. 3025, 1996 DOI: 10.1080/00397919608004607 | [General Description]
3-Benzylidene-2,4-pentanedione (BPD) can be prepared by reacting benzaldehyde with 2,4-pentanedione in the presence of a base. |
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