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ChemicalBook--->CAS DataBase List--->42196-31-6

42196-31-6

42196-31-6 Structure

42196-31-6 Structure
IdentificationMore
[Name]

PALLADIUM(II) TRIFLUOROACETATE
[CAS]

42196-31-6
[Synonyms]

PALLADIUM(II) TRIFLUOROACETATE
PALLADIUM TRIFLUOROACETATE
TRIFLUOROACETIC ACID PALLADIUM(II) SALT
2,7-DICHLORO-9-FLUORENONE, TECH., 90%
PALLADIUM (II) TRIFLUOROACETATE 97+%
Palladium(II) trifluoroacetate, 99+%
Palladium(II)trifluoroacetate,98+%
Palladium(II)trifluoroacetate,min.97%
Palladium(II) trifluoroacetate 98%
trifluoroacetic acid, palladium salt
Palladium(II) trifluoroacetate, min. 97%
[Molecular Formula]

C4F6O4Pd
[MDL Number]

MFCD00013204
[Molecular Weight]

332.45
[MOL File]

42196-31-6.mol
Chemical PropertiesBack Directory
[Appearance]

tan to brown powder
[Melting point ]

~220 °C
[storage temp. ]

Inert atmosphere,Room Temperature
[solubility ]

Soluble in diethyl ether and acetone. Insoluble in benzene, chloroform and trifluoroacetic acid.
[form ]

Powder
[color ]

Brown
[Hydrolytic Sensitivity]

4: no reaction with water under neutral conditions
[Sensitive ]

Hygroscopic
[InChIKey]

WEJWWPJAIXRLIJ-UHFFFAOYSA-M
[CAS DataBase Reference]

42196-31-6(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection .
[WGK Germany ]

3
[F ]

3-10
[Hazard Note ]

Irritant
[TSCA ]

No
[HS Code ]

28439000
Hazard InformationBack Directory
[Chemical Properties]

tan to brown powder
[Uses]

[Uses]

Palladium(II) Trifluoroacetate is a pallaium salt of Trifluoroacetic Acid (T786035), a solvent used in a variety of organic synthesis and chemical processes. Also used in the synthesis of anticancer agents as well as phospholipase D inhibitors.
[reaction suitability]

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: C-H Activation
[Purification Methods]

Suspend it in trifluoroacetic acid and evaporate it on a steam bath a couple of times. The residue is then dried in vacuum (40-80o) to give a brown powder. It is hygroscopic. [Stephenson et al. J Chem Soc 3632 1965, Trost & Metzner J Am Chem Soc 102 3572 1980.]
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Palladium(II) trifluoroacetate, 97%(42196-31-6)
[Alfa Aesar]

Palladium(II) trifluoroacetate, 97%(42196-31-6)
[Sigma Aldrich]

42196-31-6(sigmaaldrich)
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