| Identification | Back Directory | [Name]
TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]CERIUM(III) | [CAS]
41836-21-9 | [Synonyms]
Ceriumtrisbistrimethylsilylamide
Cerium(3+) bis(trimethylsilyl)amide
Cerium(III) bis(trimethylsilyl)amide
HEXAMETHYLDISILAZANE CERIUM(III) SALT
cerium iii tris(hexamethyldisilazide)
CERIUM III TRIS[BIS(METHYLSILYLAMIDE)]
N,N-BIS(TRIMETHYLSILYLAMINE)CERIUM(III)
CERIUM III TRIS(BIS(TRIMETHYLSILYLAMIDE))
TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]CERIUM(III)
TrisN,N-bis(trimethylsilyl)amideücerium(III), 98%
Tris(N,N-Bis(TriMethylsilyl)AMide)CeriuM(III), 96 %
1,1,1-Trimethyl-N-(trimethylsilyl)silanamine cerium(III) salt | [Molecular Formula]
C18H54CeN3Si6 | [MDL Number]
MFCD03411241 | [MOL File]
41836-21-9.mol | [Molecular Weight]
621.27 |
| Chemical Properties | Back Directory | [Appearance]
Bright yellow crystalline powder | [Melting point ]
132-140 °C(lit.)
| [Boiling point ]
95-9°C/10-4mmHg | [Fp ]
36 °F
| [storage temp. ]
Flammables + water-Freezer (-20°C)e area | [form ]
Powder | [Water Solubility ]
Soluble in water, protic solvents. | [Sensitive ]
Moisture Sensitive |
| Hazard Information | Back Directory | [Chemical Properties]
Bright yellow crystalline powder | [Uses]
Tris[N,N-bis(trimethylsilyl)amide]cerium(III) is used as a reactant for synthesis of amidocerium(IV) oxides, Sterically encumbered N-heterocyclic carbene ligands, Lanthanide imidodiphosphinate complexes with electroluminescent properties, Lanthanide complexes of an oxazoline-phenoxide hybrid chelate. Some of the other applications include it is used as a reactant for One-electron oxidation to produce tetravalent cerium compounds, Addition-elimination reactions across the M-C bond of metal N-heterocyclic carbenes. |
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