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ChemicalBook--->CAS DataBase List--->41459-42-1

41459-42-1

41459-42-1 Structure

41459-42-1 Structure
IdentificationMore
[Name]

3-Bromo-2-(bromomethyl)propionic acid
[CAS]

41459-42-1
[Synonyms]

3-BROMO-2-(BROMOMETHYL)PROPANOIC ACID
3-BROMO-2-(BROMOMETHYL)PROPIONIC ACID
BETA,BETA'-DIBROMOISOBUTYRIC ACID
Propanoic acid, 3-bromo-2-(bromomethyl)-
3-BROMO-2-(BROMOMETHYL)PROPIONIC ACID, 9 7%
bis(bromomethyl)acetic acid
β,β'-dibromoisobutyric acid
3-BROMO-2-(BROMOMETHYL)PROPIONIC ACID (KG LEVEL)
[Molecular Formula]

C4H6Br2O2
[MDL Number]

MFCD00010643
[Molecular Weight]

245.9
[MOL File]

41459-42-1.mol
Chemical PropertiesBack Directory
[Appearance]

off-white to brown crystalline powder
[Melting point ]

98-101 °C(lit.)
[Boiling point ]

286.7±30.0 °C(Predicted)
[density ]

2.121±0.06 g/cm3(Predicted)
[storage temp. ]

2-8°C
[solubility ]

Soluble in acetic acid.
[form ]

Crystalline Powder
[pka]

3.33±0.11(Predicted)
[color ]

Off-white to brown
[BRN ]

1752505
[CAS DataBase Reference]

41459-42-1(CAS DataBase Reference)
[NIST Chemistry Reference]

Propionic acid, 3-bromo-2-(bromomethyl)-(41459-42-1)
Safety DataBack Directory
[Hazard Codes ]

C
[Risk Statements ]

R34:Causes burns.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 3261 8/PG 2
[WGK Germany ]

3
[F ]

8
[HazardClass ]

8
[PackingGroup ]

III
[HS Code ]

29159000
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Diethyl ether-->Sulfuric acid-->Toluene-->Nitric acid-->Sodium sulfate-->Formaldehyde-->Hydrogen bromide-->Diethyl malonate-->Ammonium sulfate-->Diisopropyl ether-->Potassium bicarbonate-->Diethyl bis(hydroxymethyl)malonate
[Preparation Products]

ALPHA-BROMOCROTONICACID-->2-(BROMOMETHYL)ACRYLIC ACID-->tert-butyl 3-bromo-2-(bromomethyl)propanoate
Hazard InformationBack Directory
[Chemical Properties]

off-white to brown crystalline powder
[Uses]

3-Bromo-2-(bromomethyl)propionic acid acts as an organic building block for the preparation of beta-substituted acrylates. It is used in the preparation of t-butyl 2-(phenylthiomethyl) propenoate, t-butyl 3-(phenylthio)-2-(phenylthiomethyl)propenoate and 3-(phenylthio)-2-(phenyl-sulfinylmethyl)propenoate. Further, it plays an important role in the synthesis of beta-lactams by cyclization of the corresponding amide.
[General Description]

3-Bromo-2-(bromomethyl)propionic acid reacts with alkaline arsenite to yield (RS)-3-arsono-2-(hydroxymethyl)propionic acid.
Spectrum DetailBack Directory
[Spectrum Detail]

3-Bromo-2-(bromomethyl)propionic acid(41459-42-1)MS
3-Bromo-2-(bromomethyl)propionic acid(41459-42-1)1HNMR
3-Bromo-2-(bromomethyl)propionic acid(41459-42-1)IR1
3-Bromo-2-(bromomethyl)propionic acid(41459-42-1)IR2
3-Bromo-2-(bromomethyl)propionic acid(41459-42-1)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

3-Bromo-2-(bromomethyl)propionic acid, 97%(41459-42-1)
[Alfa Aesar]

3-Bromo-2-(bromomethyl)propionic acid, 98%(41459-42-1)
[Sigma Aldrich]

41459-42-1(sigmaaldrich)
[TCI AMERICA]

3-Bromo-2-(bromomethyl)propionic Acid,>92.0%(GC)(41459-42-1)
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