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ChemicalBook--->CAS DataBase List--->40925-68-6

40925-68-6

40925-68-6 Structure

40925-68-6 Structure
IdentificationMore
[Name]

2-Amino-4-bromophenol
[CAS]

40925-68-6
[Synonyms]

2-AMINO-4-BROMOPHENOL
2-AMINO-4-BROMOPHENOLE
5-BROMO-2-HYDROXYANILINE
PHENOL, 2-AMINO-4-BROMO-
TIMTEC-BB SBB002114
Amino-4-bromophenol
C008373 2-Amino-4-Bromophenol
2-AMINO-4-BROMOPHENOL 98.5+%
[EINECS(EC#)]

627-173-0
[Molecular Formula]

C6H6BrNO
[MDL Number]

MFCD00235171
[Molecular Weight]

188.02
[MOL File]

40925-68-6.mol
Chemical PropertiesBack Directory
[Melting point ]

135-140°C
[Boiling point ]

282.8±25.0 °C(Predicted)
[density ]

1.768±0.06 g/cm3(Predicted)
[storage temp. ]

2-8°C
[form ]

powder to crystal
[pka]

9.19±0.18(Predicted)
[color ]

White to Gray to Brown
[BRN ]

3236448
[InChI]

InChI=1S/C6H6BrNO/c7-4-1-2-6(9)5(8)3-4/h1-3,9H,8H2
[InChIKey]

JHRIPENGTGSNPJ-UHFFFAOYSA-N
[SMILES]

C1(O)=CC=C(Br)C=C1N
[CAS DataBase Reference]

40925-68-6(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
[WGK Germany ]

3
[Hazard Note ]

Irritant
[HazardClass ]

IRRITANT
[HS Code ]

29222990
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Sodium hydroxide-->Hydrochloric acid-->Ethyl acetate-->Methanol-->Dichloromethane-->Nitric acid-->Sodium nitrite-->Sodium sulfate-->Magnesium sulfate-->Sodium chloride-->Sodium bicarbonate-->Stannous chloride-->4-Bromophenol-->Potassium peroxymonosulfate
[Preparation Products]

5-BROMO-2(3H)-BENZOXAZOLONE-->6-BROMO-2H-1,4-BENZOXAZIN-3(4H)-ONE-->Acetamide, N-(3-bromophenyl)-N-hydroxy--->INK1117-->4-AMINO-2-BROMOPHENOL-->(5-Bromo-2-hydroxyphenyl)carbamic acid tert-butyl ester
Hazard InformationBack Directory
[Description]

2-Amino-4-bromophenol is a reactant for the preparation of (aryl)oxadiazolobenzoxazinones via Suzuki-Miyaura reaction, copper-catalyzed oxidative amination of benzoxazoles and related azoles via C-H and C-N bond activation synthesis of N-(alkoxyphenyl)-aminocarbonylbenzoic acid derivatives as protein tyrosine phophatase 1B inhibitors,preparation of lipophilic deoxy-xylulose-phosphate reductoisomerase inhibitors,synthesis of benzoxazole benzenesulfonamides as allosteric inhibitors of fructose-1,6-bisphosphatase.
[Chemical Properties]

White solid
[Uses]

Reactant for:
  • Preparation of (aryl)oxadiazolobenzoxazinones via Suzuki-Miyaura reaction
  • Copper-catalyzed oxidative amination of benzoxazoles and related azoles via C-H and C-N bond activation
  • Synthesis of N-(alkoxyphenyl)-aminocarbonylbenzoic acid derivatives as protein tyrosine phophatase 1B inhibitors
  • Preparation of lipophilic deoxy-xylulose-phosphate reductoisomerase inhibitors
  • Synthesis of benzoxazole benzenesulfonamides as allosteric inhibitors of fructose-1,6-bisphosphatase
Spectrum DetailBack Directory
[Spectrum Detail]

2-Amino-4-bromophenol(40925-68-6)FT-IR
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

40925-68-6(sigmaaldrich)
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