Identification | More | [Name]
1,2-Difluorobenzene | [CAS]
367-11-3 | [Synonyms]
1,2-DIFLUOROBENZENE O-DIFLUOROBENZENE 1,2-Difluorbenzol 1,2-difluroethylene Benzene, o-difluoro- benzene,1,2-difluoro- Benzene,o-difluoro- difluorobenzene o-difluoro-benzen ortho-Difluorobenzene 2-Difluorobenzene 1,2-Difluorobenzene,98+% o-Difluorobenzene,99% 1,2-Difluorobenzene 98% 1,2-Dfluorobenzene | [EINECS(EC#)]
206-680-7 | [Molecular Formula]
C6H4F2 | [MDL Number]
MFCD00000284 | [Molecular Weight]
114.09 | [MOL File]
367-11-3.mol |
Chemical Properties | Back Directory | [Appearance]
colourless liquid | [Melting point ]
−34 °C(lit.)
| [Boiling point ]
92 °C(lit.)
| [density ]
1.158 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.443(lit.)
| [Fp ]
36 °F
| [storage temp. ]
Flammables area | [solubility ]
Chloroform, Methanol | [form ]
Liquid | [color ]
Clear colorless | [Specific Gravity]
1.158 | [Stability:]
Stable. Incompatible with strong oxidizing agents. Highly flammable. Note low flash point. | [Water Solubility ]
Not miscible or difficult to mix in water. | [BRN ]
1905113 | [Dielectric constant]
14.26 | [CAS DataBase Reference]
367-11-3(CAS DataBase Reference) | [NIST Chemistry Reference]
Benzene, 1,2-difluoro-(367-11-3) | [Storage Precautions]
Heat sensitive | [EPA Substance Registry System]
367-11-3(EPA Substance) |
Safety Data | Back Directory | [Hazard Codes ]
F,Xn | [Risk Statements ]
R11:Highly Flammable. R20:Harmful by inhalation. | [Safety Statements ]
S7:Keep container tightly closed . S16:Keep away from sources of ignition-No smoking . S29:Do not empty into drains . S33:Take precautionary measures against static discharges . S7/9:Keep container tightly closed and in a well-ventilated place . | [RIDADR ]
UN 1993 3/PG 2
| [WGK Germany ]
3
| [RTECS ]
CZ5655000
| [Hazard Note ]
Flammable | [HazardClass ]
3 | [PackingGroup ]
II | [HS Code ]
29036990 |
Raw materials And Preparation Products | Back Directory | [Raw materials]
Hydrochloric acid-->Fluoroboric acid | [Preparation Products]
2,3-Difluorophenylboronic acid-->Benzeneacetonitrile, 2-fluoro-alpha,alpha-dimethyl--->2-Chloro-1-(3,4-difluoro-phenyl)-ethanone-->2,3-Difluorobenzaldehyde-->2,3-Difluorophenol-->CHEMBRDG-BB 4003866-->(S)-2-(3,4-Difluorophenyl)oxirane-->1,2-difluoro-4,5-dinitrobenzene-->(1R,2R)-2-(3,4-difluorophenyl)cyclopropane carboxaMide-->4,7-Bis(5-broMothiophen-2-yl)-5,6-difluorobenzo[c][1,2,5] thiadiazole-->(1S)-2-chloro-1-(3,4-difluorophenyl)-1-ethanol-->(1R,2R)-2-(3,4-difluorophenyl)cyclopropanecarboxylic acid-->2-Bromo-4,5-difluorobenzonitrile-->3,4-Difluorobenzyl chloride-->METHYL 3,4-DIFLUOROBENZOATE-->1,4-DIBROMO-2,3-DIFLUOROBENZENE |
Hazard Information | Back Directory | [Chemical Properties]
colourless liquid | [Uses]
1,2-Difluorobenzene is used in electrochemical analysis of transition metal complexes. 1,2-difluorobenzene is also a potent inhibitor of NMDA receptor. | [Definition]
ChEBI: A difluorobenzene carrying fluoro groups at positions 1 and 2. | [General Description]
1,2-Difluorobenzene undergoes defluorination under very mild conditions by H2 in the presence of NaOAc over rhodium pyridylphosphine and bipyridyl complexes tethered on a silica-supported palladium catalyst. |
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