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ChemicalBook--->CAS DataBase List--->3615-41-6

3615-41-6

3615-41-6 Structure

3615-41-6 Structure
IdentificationMore
[Name]

alpha-L-Rhamnose
[CAS]

3615-41-6
[Synonyms]

6-DEOXY-L-MANNOSE
ALPHA-RHAMNOSE
ISO-DULCITE
ISODULCITOL
L-MANNOMETHYLOSE
L-(+)-RHAMNOSE
L-RHAMNOSE
RHAMNOSE
6-Deoxyhexopyranose
6-deoxy-l-mannos
6-Deoxymannose
Isoducitol
L-Mannopyranose, 6-deoxy-
Locaose
Mannose, 6-deoxy-
Rhamnopyranose
Rhamnopyranose, L-
L-Mannose, 6-deoxy-
(3R,4R,5S,6S)-6-methyloxane-2,3,4,5-tetrol
6-Deoxy-L-mannose
[EINECS(EC#)]

222-793-4
[Molecular Formula]

C6H12O5
[MDL Number]

MFCD00136036
[Molecular Weight]

164.16
[MOL File]

3615-41-6.mol
Chemical PropertiesBack Directory
[Appearance]

White crystals. For equilibrium mixture optical rotation is +9.18 degrees. Very soluble in water and in methanol; soluble in absolute alcohol.
[Melting point ]

91-95°C
[Boiling point ]

251.61°C (rough estimate)
[density ]

1.3058 (rough estimate)
[FEMA ]

3730
[refractive index ]

1.6400 (estimate)
[storage temp. ]

Sealed in dry,2-8°C
[form ]

Solid
[pka]

12.50±0.20(Predicted)
[color ]

White to off-white
[Odor]

at 100.00 %. odorless
[Odor Type]

odorless
[Water Solubility ]

521.5g/L(40 ºC)
[Merck ]

8172
[LogP]

-2.17 at 25℃
[Uses]

Synthetic sweetener research.
[CAS DataBase Reference]

3615-41-6(CAS DataBase Reference)
[NIST Chemistry Reference]

L-Mannose, 6-deoxy-(3615-41-6)
[EPA Substance Registry System]

3615-41-6(EPA Substance)
Hazard InformationBack Directory
[Chemical Properties]

L-Rhamnose has no odor, but has a very sweet taste.
[Chemical Properties]

White crystals. For equilibrium mixture optical rotation is +9.18 degrees. Very soluble in water and in methanol; soluble in absolute alcohol.
[Definition]

ChEBI: The acyclic form of L-rhamnose.
[Flammability and Explosibility]

Notclassified
[Purification Methods]

Crystallise the rhamnose from H2O or EtOH. It crystallises easily as the monohydrate by evaporating a solution in MeOH (90%) and H2O (10%). It is also purified by dissolving in a small volume of EtOH, adding a few drops of H2O and cooling. 1H NMR in D2O at 44o contains 60% -pyranose and 40% -pyranose forms [Angyal Adv Carbohydr Chem 42 15 1984.] [Smith J Chem Soc 1035 1940, McGeachin & Beevers Acta Cryst 10 227,230 197, Beilstein 1 IV 4261.]
Spectrum DetailBack Directory
[Spectrum Detail]

alpha-L-Rhamnose(3615-41-6)MS
alpha-L-Rhamnose(3615-41-6)13CNMR
alpha-L-Rhamnose(3615-41-6)IR1
alpha-L-Rhamnose(3615-41-6)IR2
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

3615-41-6(sigmaaldrich)
[TCI AMERICA]

L-(+)-Rhamnose  Monohydrate,>98.0%(LC)(3615-41-6)
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