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ChemicalBook--->CAS DataBase List--->354-37-0

354-37-0

354-37-0 Structure

354-37-0 Structure
IdentificationMore
[Name]

Trifluoroacetamidine
[CAS]

354-37-0
[Synonyms]

TRIFLUOROACETAMIDINE, TECH.
Trifluoroacetamidine
[EINECS(EC#)]

670-531-6
[Molecular Formula]

C2H3F3N2
[MDL Number]

MFCD00041545
[Molecular Weight]

112.05
[MOL File]

354-37-0.mol
Chemical PropertiesBack Directory
[Boiling point ]

35-37°C 11mm
[density ]

1.45
[refractive index ]

1.3801
[Fp ]

35-37°C/11mm
[storage temp. ]

Store below-20C
[form ]

liquid
[pka]

6.07±0.40(Predicted)
[color ]

Clear, yellow
[Water Solubility ]

Fully miscible in water.
[Sensitive ]

Moisture Sensitive
[BRN ]

605978
[InChI]

InChI=1S/C2H3F3N2/c3-2(4,5)1(6)7/h(H3,6,7)
[InChIKey]

NITMACBPVVUGOJ-UHFFFAOYSA-N
[SMILES]

C(N)(=N)C(F)(F)F
[CAS DataBase Reference]

354-37-0(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

C,Xi
[Risk Statements ]

R34:Causes burns.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
[RIDADR ]

3267
[Hazard Note ]

Corrosive/Irritant
[HazardClass ]

8
[PackingGroup ]

II
[HS Code ]

29252900
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Ammonia-->Trifluoroacetonitrile-->Trifluoroacetamide
[Preparation Products]

Ethyl 4-chloro-2-(trifluoromethyl)pyrimidine-5-carboxylate-->2-TRIFLUOROMETHYL-PYRIMIDINE-5-CARBALDEHYDE-->2-(TRIFLUOROMETHYL)PYRIMIDIN-5-AMINE-->(2-(TRIFLUOROMETHYL)PYRIMIDIN-5-YL)METHANOL-->(2-(TRIFLUOROMETHYL)PYRIMIDIN-5-YL)METHANAMINE-->2-(TRIFLUOROMETHYL)PYRIMIDINE-5-CARBONYL CHLORIDE-->2-(TRIFLUOROMETHYL)PYRIMIDIN-4-AMINE-->2-(TRIFLUOROMETHYL)PYRIMIDINE-5-CARBOXAMIDE-->ETHYL 2-(TRIFLUOROMETHYL)PYRIMIDINE-5-CARBOXYLATE-->[4-AMINO-2-(TRIFLUOROMETHYL)PYRIMIDIN-5-YL]METHANOL-->2-(TRIFLUOROMETHYL)PYRIMIDINE-5-CARBOXYLIC ACID-->4-CHLORO-2,6-BIS(TRIFLUOROMETHYL)PYRIMIDINE-->4-CHLORO-2-(TRIFLUOROMETHYL)PYRIMIDINE-->4-AMINO-2-(TRIFLUOROMETHYL)PYRIMIDINE-5-CARBALDEHYDE-->2-(TRIFLUOROMETHYL)-4-HYDROXYPYRIMIDINE-5-CARBOXYLIC ACID-->5-(AMINOMETHYL)-2-(TRIFLUOROMETHYL)PYRIMIDIN-4-AMINE-->4-Hydroxy-2-(trifluoromethyl)pyrimidine-->4-AMINO-2-(TRIFLUOROMETHYL)PYRIMIDINE-5-CARBONITRILE-->4-AMINO-2-(TRIFLUOROMETHYL)PYRIMIDINE-5-CARBOXYLIC ACID
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Trifluoroacetamidine(354-37-0).msds
Hazard InformationBack Directory
[Chemical Properties]

Colorless liquid
[Uses]

Trifluoroacetamidine is used as probe for determination of membrane potential and extra/intracellular volume of erythrocytes by fluorine-19 NMR studies. It is a reagent used as protected ammonia equivalent.
[Synthesis]

Trifluoroacetamidine is a vital chemical intermediate with a wide range of applications. A preparation method comprises the following steps: trifluoroacetamide is used as raw materials, polyphosphoric acid is selected as solvents under the effect of phosphorus pentoxide as dehydrating agents, and trifluoroacetonitrile can be fast prepared through a dehydration reaction. The generated trifluoroacetonitrile gas is introduced into a liquid ammonia kettle after being cooled, and the trifluoroacetamidine can be prepared.
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Trifluoroacetamidine, tech. 85%(354-37-0)
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