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ChemicalBook--->CAS DataBase List--->34830-11-0

34830-11-0

34830-11-0 Structure

34830-11-0 Structure
IdentificationBack Directory
[Name]

EUROPIUM D-3-TRIFLUOROACETYLCAMPHORATE
[CAS]

34830-11-0
[Synonyms]

TFMC-EU
EU(TFC)3
GDCL3:6H2O
EU(FACAM)3
europium-tfc
EUROPIUM(TFC)3
Tri(3-trifluoro-1-hydroxyethyl
EUROPIUM D-3-TRIFLUOROACETYLCAMPHORATE
GADOLINIUM EUROPIUM D-3-TRIFLUOROACETYLCAMPHORATE
TRIS(3-TRIFLUOROACETYL-D-CAMPHORATO)EUROPIUM(III)
tris[3-(trifluoroacetyl)bornane-2-onato-O,O']europium
trifluoromethylhydroxymethylene-(-)-camphorato europium
TRIS(3-(TRIFLUOROMETHYLHYDROXYMETHYLENE)-D-CAMPHORATO)EUROP.
TRIS(TRIFLUOROMETHYLHYDROXYMETHYLENE-D-CAMPHORATO)EUROPIUM(III)
EUROPIUM TRIS[3-(TRIFLUOROMETHYLHYDROXYMETHYLENE)-(-)-CAMPHORATE]
EUROPIUM TRIS[3-(TRIFLUOROMETHYLHYDROXYMETHYLENE)-(+)-CAMPHORATE]
Tris[3-(Trifluoromethylhydroxymethylene)-D-Camphorato], Europium(
TRIS[3-(TRIFLUOROMETHYLHYDROXYMETHYLENE)-D-CAMPHORATO]EUROPIUM(III)
EUROPIUM(III)-TRIS[3-(TRIFLUOROMETHYLHYDROXYMETHYLENE)-D-CAMPHORATE]
tris[1,7,7-trimethyl-3-(trifluoroacetyl)bicyclo[2.2.1]heptan-2-onato-europiu
TRIS(3-(TRIFLUOROMETHYLHYDROXYMETHYLENE) -(+)-CAMPHORATO), EUROPIUM(III) DERI
TRIS[3-(TRIFLUOROMETHYLHYDROXYMETHYLENE)-D-CAMPHORATO], EUROPIUM(III) DERIVATIVE
TRIS-(3-(TRIFLUOROMETHYLHYDROXYMETHYLENE)-D-CAMPHORATO), EUROPIUM(III) DERIV., 95%
Tris[3-(trifluoromethylhydroxymethylene)-D-camphorato], europium(III) derivative,95%
Eu(facam)3, Eu(tfc)3, Tris(3-trifluoroacetyl-d-camphorato)europium(III), Tris[3-(trifluoromethylhydroxymethylene)-d-camphorato]europium(III)
Eu(facam)3, Eu(tfc)3, Tris(3-trifluoroacetyl-d-camphorato)europium(III), Europium(III) tris[3-(trifluoromethylhydroxymethylene)-d-camphorate], Tris[3-(trifluoromethylhydroxymethylene)-d-camphorato]europium(III)
[EINECS(EC#)]

252-232-9
[Molecular Formula]

C36H42EuF9O6
[MDL Number]

MFCD00074803
[MOL File]

34830-11-0.mol
[Molecular Weight]

893.66
Chemical PropertiesBack Directory
[Appearance]

yellow to orange powder
[Melting point ]

195-198 °C(lit.)
[form ]

solid
[optical activity]

[α]20/D +165°, c = 1% in chloroform (solvent is ethanol free)
[Water Solubility ]

Soluble in chloroform. Insoluble in water.
[Sensitive ]

Moisture Sensitive
[CAS DataBase Reference]

34830-11-0
[EPA Substance Registry System]

Europium, tris[1,7,7-trimethyl-3-(trifluoroacetyl-.kappa.O)bicyclo[2.2.1]heptan-2-onato-.kappa.O]- (34830-11-0)
Hazard InformationBack Directory
[Chemical Properties]

yellow to orange powder
[Uses]

Optically active NMR shift reagent. Used with Ag(fod) for the enantiomeric resolution of sec-butylisothiouronium chloride. Also reactant involved in synthesis of europium acetyl camphorate phosphine oxide complexes and reactions with 1,10-N,N?-phenanthroline dioxide derivatives.
Safety DataBack Directory
[Safety Statements ]

24/25
[WGK Germany ]

3
[F ]

3-10
[TSCA ]

Yes
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Ethanol-->Sodium hydroxide-->Hydrochloric acid-->Diethyl ether-->Hexane-->Sodium hydride-->Pentane-->1,2-Dimethoxyethane-->Ethyl trifluoroacetate-->D-CAMPHOR-->Europium(III) chloride hexahydrate
Spectrum DetailBack Directory
[Spectrum Detail]

EUROPIUM D-3-TRIFLUOROACETYLCAMPHORATE(34830-11-0)IR1
EUROPIUM D-3-TRIFLUOROACETYLCAMPHORATE(34830-11-0)IR2
EUROPIUM D-3-TRIFLUOROACETYLCAMPHORATE(34830-11-0)Raman
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