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ChemicalBook--->CAS DataBase List--->31785-68-9

31785-68-9

31785-68-9 Structure

31785-68-9 Structure
IdentificationBack Directory
[Name]

9-Azabicyclo[3.3.1]nonane N-oxyl
[CAS]

31785-68-9
[Synonyms]

NPPN
ABNO
9-AZABICYCLO[3.3.1]NONANE N-OX
9-Azabicyclo[3.3.1]non-9-yloxy
9-Azabicyclo[3.3.1]nonane N-oxyl
9-Azabicyclo[3.3.1]nonane N-oxyl 95%
exe-3-methylamino-9-boc -9-azabicyclo[3.3.1]nonane
[EINECS(EC#)]

803-697-7
[Molecular Formula]

C8H14NO*
[MDL Number]

MFCD23704408
[MOL File]

31785-68-9.mol
[Molecular Weight]

140.203
Chemical PropertiesBack Directory
[Melting point ]

65-70°C
[storage temp. ]

2-8°C
[form ]

solid
[BRN ]

1681761
Safety DataBack Directory
[Symbol(GHS) ]


GHS05,GHS07
[Signal word ]

Danger
[Hazard statements ]

H302-H318
[Precautionary statements ]

P280-P301+P312+P330-P305+P351+P338+P310
[Hazard Codes ]

Xn
[Risk Statements ]

22-41-52/53
[Safety Statements ]

26-39-61
[WGK Germany ]

3
Hazard InformationBack Directory
[Uses]

9-Azabicyclo[3.3.1]nonane N-oxyl (ABNO) may be employed for the aerobic oxidation of alcohols.
[General Description]

9-Azabicyclo[3.3.1]nonane N-oxyl (ABNO) belongs to a sterically unhindered and stable class of nitroxyl radicals. It efficiently catalyzes the oxidation of alcohols to afford the corresponding carbonyl compounds. ABNO along with (MeObpy)CuI(OTf) (MeObpy =4,4′-dimethoxy-2,2′-bipyridine) comprises a catalytic system. This catalytic system is useful for the aerobic oxidation of all categories of alcohols.
[reaction suitability]

reagent type: ligand
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