| Identification | More | [Name]
Tetrabutylammonium hexafluorophosphate | [CAS]
3109-63-5 | [Synonyms]
TETRABUTYLAMMONIUM HEXAFLUOROPHOSPHATE
TETRA-N-BUTYLAMMONIUM HEXAFLUOROPHOSPHATE
1-Butanaminium, N,N,N-tributyl-, hexafluorophosphate(1-)
tetrabutylammonium-hexafluorphosophat
TETRABUTYLAMMONIUM HEXAFLUOROPHOSPHATE, ELECTROCHEM. GRADE
Tetrabutylammoniumhexafluorophosphate,98%
Tetrabutylammonium hexafluorophosphate 98%
N,N,N-tributyl-1-butanaminium tetrafluorophosphate
Tetra-n-butylammonium hexafluorophosphate ,99% | [EINECS(EC#)]
221-472-6 | [Molecular Formula]
C16H36F6NP | [MDL Number]
MFCD00011748 | [Molecular Weight]
387.43 | [MOL File]
3109-63-5.mol |
| Chemical Properties | Back Directory | [Appearance]
off-white powder | [Melting point ]
244-246 °C (lit.) | [Boiling point ]
242-246 °C
| [storage temp. ]
Inert atmosphere,Room Temperature | [solubility ]
acetonitrile: 0.1 g/mL, clear, colorless
| [form ]
Crystalline Powder and/or Chunks | [color ]
White to off-white | [Sensitive ]
Hygroscopic | [Detection Methods]
Subtraction | [BRN ]
4056584 | [InChI]
InChI=1S/C16H36N.F6P/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;1-7(2,3,4,5)6/h5-16H2,1-4H3;/q+1;-1 | [InChIKey]
BKBKEFQIOUYLBC-UHFFFAOYSA-N | [SMILES]
[N+](CCCC)(CCCC)(CCCC)CCCC.[P-](F)(F)(F)(F)(F)F | [CAS DataBase Reference]
3109-63-5(CAS DataBase Reference) | [NIST Chemistry Reference]
Tetrabutylammonium hexafluorophosphate(3109-63-5) | [Storage Precautions]
Store under nitrogen | [EPA Substance Registry System]
3109-63-5(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi,Xn | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin .
R22:Harmful if swallowed. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37:Wear suitable protective clothing and gloves . | [RIDADR ]
1759 | [WGK Germany ]
3
| [Hazard Note ]
Irritant/Hygroscopic | [TSCA ]
Yes | [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
29239000 |
| Hazard Information | Back Directory | [Chemical Properties]
off-white powder | [Uses]
Tetrabutylammonium hexafluorophosphate can be used as a supporting electrolyte for the formation of cyclic disulfide moiety of 3,5-diimido-1,2-dithiolane derivatives by S-S coupling of dithioanilides. | [General Description]
| [Hazard]
Tetrabutylammonium hexafluorophosphate is harmful to humans and is an eye and skin irritant. It may cause severe eye irritation. It may also cause respiratory irritation. Harmful if ingested. | [Purification Methods]
Recrystallise it from saturated EtOH/water and dry it for 10hours in a vacuum at 70o. Also recrystallise it three times from absolute EtOH and dry it for 2 days in a drying pistol under a vacuum at boiling toluene temperature [Bedard & Dahl J Am Chem Soc 108 5933 1986]. It is a stable supporting electrolyte in organic solvents [Baiser in Organic Electrochemitry M. Dekker NY p228 1973.] |
|
|