| Identification | More | [Name]
Titanium ethoxide | [CAS]
3087-36-3 | [Synonyms]
ETHYL ORTHOTITANATE
ETHYL TITANATE
ETHYL TITANATE(IV)
ORTHOTITANIC ACID TETRAETHYL ESTER
Tetraethoxy titanium
TETRAETHYL ORTHOTITANATE
TETRAETHYL TITANATE
TITANIC ACID TETRAETHYL ESTER
TITANIUM ETHOXIDE
TITANIUM ETHYLATE
TITANIUM(IV) ETHOXIDE
TITANIUM (IV) TETRAETHOXIDE
TITANIUM TETRAETHOXIDE
TITANIUM TETRAETHYLATE
VERTEC(TM) ET
Ethanol, titanium(4+) salt
Ethanol,titanium(4+)salt
ethanol,titanium(4++)salt
titanium(4+) ethanolate
TITANIUM(IV) ETHOXIDE APPROX. 80% | [EINECS(EC#)]
221-410-8 | [Molecular Formula]
C8H20O4Ti | [MDL Number]
MFCD00009071 | [Molecular Weight]
228.11 | [MOL File]
3087-36-3.mol |
| Chemical Properties | Back Directory | [Appearance]
colourless liquid | [Melting point ]
54°C | [Boiling point ]
150-152 °C10 mm Hg(lit.)
| [density ]
1.088 g/mL at 25 °C(lit.)
| [vapor pressure ]
57.26hPa at 19.6℃ | [refractive index ]
n20/D 1.505(lit.)
| [Fp ]
84 °F
| [storage temp. ]
2-8°C
| [solubility ]
Soluble in organic solvents. | [form ]
Liquid | [color ]
Pale yellow | [Specific Gravity]
1.107 (20℃) | [Stability:]
Stability Incompatible with strong oxidizing agents, strong acids. May decompose upon exposure to air or moisture. | [Water Solubility ]
reacts | [Sensitive ]
Moisture Sensitive | [BRN ]
3678992 | [Exposure limits]
ACGIH: TWA 200 ppm; STEL 400 ppm
OSHA: TWA 400 ppm(980 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 400 ppm(980 mg/m3); STEL 500 ppm(1225 mg/m3) | [InChIKey]
JMXKSZRRTHPKDL-UHFFFAOYSA-N | [CAS DataBase Reference]
3087-36-3(CAS DataBase Reference) | [NIST Chemistry Reference]
Ti(OEt)4(3087-36-3) | [Storage Precautions]
Moisture sensitive | [EPA Substance Registry System]
3087-36-3(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R10:Flammable.
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection .
S16:Keep away from sources of ignition-No smoking . | [RIDADR ]
UN 1993 3/PG 3
| [WGK Germany ]
3
| [F ]
3-10-21 | [TSCA ]
Yes | [HazardClass ]
4.1 | [PackingGroup ]
III | [HS Code ]
29051900 |
| Hazard Information | Back Directory | [Chemical Properties]
colourless liquid | [Uses]
Titanium(IV) ethoxide is used in organic synthesis and material science. It is involved in the synthesis of anti-perspirants and antifungal agents. Furthermore, it is used to prepare carbon films in association with silicon dioxide. It is also used as a precursor for the synthesis of Ti4+ ions titanium nanoparticles by various methods. | [Application]
Titanium(IV) ethoxide can be used:
As an activator and dehydrating agent for by condensation of (S)-(+)-p-toluenesulfinamide with aldehydes and ketones to form sulfinimines.
As a Ti4+ ion source to form complexes of titanium (IV) acrylate with methacrylic acid.
As a catalyst to synthesize esters of sterically hindered alcohols via transesterification reactions. | [Flammability and Explosibility]
Flammable | [Materials Uses]
Titanium ethoxide is used widely as a precursor for the synthesis of Ti4+ ions titania nanoparticles by various techniques such as :
in the sol-gel synthesis of free-standing ferroelectric lead zirconate titanate nanoparticles
spherical titania cores, produced either by hydrolysis of Ti(IV) ethoxide droplets in contact with water vapor or
by preadsorption of the titanium alkoxides into/onto the clay mineral platelets and their subsequent hydrolysis and calcination. |
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