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ChemicalBook--->CAS DataBase List--->26550-55-0

26550-55-0

26550-55-0 Structure

26550-55-0 Structure
IdentificationBack Directory
[Name]

(S)-(+)-1-Methoxy-2-propanol
[CAS]

26550-55-0
[Synonyms]

(S)-1-methoxypropanol
(S)-1-METHOXY-2-PROPANOL
(S)-1-Methoxypropan-2-ol
(S)-(+)-1-METHOXY-2-PROPANOL
(S)-2-HYDROXY-1-METHOXYPROPANE
(S)-(+)-1-METHOXY-2-PROPANOL 98%
(S)-(+)-1-Methoxy-2-propanol,99%
(S)-(+)-1-Methoxy-2-propanol
(S)-(+)-1-Methoxy-2-propanol, 99% 1ML
(S)-(+)-1-Methoxy-2-propanol, 99% 5ML
(S)-(+)-PROPYLENE GLYCOL 1-METHYL ETHER
(S)-(+)-1-Methoxy-2-propanol >=98.5% (sum of enantiomers)
[Molecular Formula]

C4H10O2
[MDL Number]

MFCD01632588
[MOL File]

26550-55-0.mol
[Molecular Weight]

90.12
Chemical PropertiesBack Directory
[Appearance]

Colorless to light yellow liqui
[Melting point ]

-84.2°C (estimate)
[alpha ]

20 º (c=10, CHCl3)
[Boiling point ]

118-119 °C
[density ]

0.921 g/mL at 20 °C(lit.)
[refractive index ]

n20/D 1.403
[Fp ]

33 °C
[storage temp. ]

Flammables area
[solubility ]

Chloroform (Sparingly), Methanol (Slightly)
[form ]

Liquid
[pka]

14.49±0.20(Predicted)
[color ]

Clear colorless
[optical activity]

[α]20/D +22±2°, c = 10% in chloroform
[BRN ]

1718940
[Stability:]

Volatile
[InChIKey]

ARXJGSRGQADJSQ-BYPYZUCNSA-N
[CAS DataBase Reference]

26550-55-0
Hazard InformationBack Directory
[Chemical Properties]

Colorless to light yellow liqui
[Uses]

(S)-(+)-1-Methoxy-2-propanol can be used as a reactant to prepare:
  • (S)-1-methoxypropan-2-yl 4-methylbenzenesulfonate by reacting with tosyl chloride in the presence of pyridine.
  • Thiazolopyridine urea derivatives.
  • Quinazoline derivatives as potential inhibitors of EGFR/HER-2 tyrosine kinases.

[Purification Methods]

Wash the ethers with aqueous NaHCO3 in the presence of solid NaCl, dry them with MgSO4 and fractionally distil them. The RS-acetate [108-65-6] M 132.2 has b 145-146o/atm. The R(+) and S(-) enantiomers have [] D ±20.5o (c 10, H2O). [Beilstein 1 II 536, 1 III 2146, 1 IV 2471.]
Safety DataBack Directory
[Hazard Codes ]

F
[Risk Statements ]

10-15
[Safety Statements ]

24-43-7/8-16
[RIDADR ]

UN 3092 3/PG 3
[WGK Germany ]

3
[HazardClass ]

3
[PackingGroup ]

[HS Code ]

29094990
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