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ChemicalBook--->CAS DataBase List--->26218-75-7

26218-75-7

26218-75-7 Structure

26218-75-7 Structure
IdentificationMore
[Name]

6-BROMOPYRIDINE-2-CARBOXYLIC ACID METHYL ESTER
[CAS]

26218-75-7
[Synonyms]

6-BROMO-2-PYRIDINE CARBOXYLIC ACID METHYL ESTER
6-BROMOPYRIDINE-2-CARBOXYLIC ACID METHYL ESTER
METHYL 6-BROMO-2-PYRIDINECARBOXYLATE
METHYL 6-BROMOPICOLINATE
METHYL 6-BROMOPYRIDINE-2-CARBOXYLATE
RARECHEM AL BF 0899
Methyl 6-Bromoyridine-2-carboxylate
Methyl 6-bromopyridine-2-carboxylate 98%
Methyl 6-bromo-2-pyridinecarboxylate, Methyl 6-bromopicolinate
Methyl-6-bromopyridine-2-carboxylate ,97%
[EINECS(EC#)]

627-687-5
[Molecular Formula]

C7H6BrNO2
[MDL Number]

MFCD06203934
[Molecular Weight]

216.03
[MOL File]

26218-75-7.mol
Chemical PropertiesBack Directory
[Melting point ]

92-96 °C(lit.)
[Boiling point ]

289.7±20.0 °C(Predicted)
[density ]

1.579±0.06 g/cm3(Predicted)
[storage temp. ]

Keep Cold
[solubility ]

soluble in Methanol
[form ]

Crystalline Powder or Needles
[pka]

-1.03±0.10(Predicted)
[color ]

White to pale pink to pale brown to yellow
[Detection Methods]

HPLC,NMR
[InChI]

InChI=1S/C7H6BrNO2/c1-11-7(10)5-3-2-4-6(8)9-5/h2-4H,1H3
[InChIKey]

SGNCOKUHMXLGAH-UHFFFAOYSA-N
[SMILES]

C1(C(OC)=O)=NC(Br)=CC=C1
[CAS DataBase Reference]

26218-75-7(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R37/38:Irritating to respiratory system and skin .
R41:Risk of serious damage to eyes.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S39:Wear eye/face protection .
[WGK Germany ]

3
[Hazard Note ]

Harmful/Irritant/Keep Cold
[HS Code ]

29333990
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Ethyl acetate-->Methanol-->Sulfuric acid-->Thionyl chloride-->PETROLEUM ETHER-->Sodium carbonate-->Magnesium sulfate-->Sodium bicarbonate-->p-Toluenesulfonic acid-->Magnesium-->6-Bromopicolinic acid-->2,6-Dibromopyridine-->Iodomethane-->6-Bromopyridine-2-carbaldehyde
[Preparation Products]

2-(6-broMopyridin-2-yl)propan-2-ol-->Methyl 6-ethynylpyridine-2-carboxylate
Hazard InformationBack Directory
[Chemical Properties]

White to off-white solid
[Uses]

Methyl 6-bromopicolinate, also known as Methyl 6-bromopyridine-2-carboxylate, is a halogenated pyridine derivative that can be used in esterolysis reactions to form 6-Bromopicolinic acid.It can also be used in substitution reactions or cross-couplings to synthesise other pyridine compounds.
Spectrum DetailBack Directory
[Spectrum Detail]

6-BROMOPYRIDINE-2-CARBOXYLIC ACID METHYL ESTER(26218-75-7)1HNMR
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

26218-75-7(sigmaaldrich)
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