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ChemicalBook--->CAS DataBase List--->2252-44-0

2252-44-0

2252-44-0 Structure

2252-44-0 Structure
IdentificationMore
[Name]

3-(Trifluoromethoxy)bromobenzene
[CAS]

2252-44-0
[Synonyms]

1-BROMO-3-(TRIFLUOROMETHOXY)BENZENE
3-BROMO-ALPHA,ALPHA,ALPHA-TRIFLUOROANISOLE
3-BROMO(TRIFLUOROMETHOXY)BENZENE
3-(TRIFLUOROMETHOXY)BROMOBENZENE
BUTTPARK 91\57-27
M-BROMO(TRIFLUOROMETHOXY)BENZENE
Anisole, m-bromo-alphaalphaalpha-trifluoro-
3-Bromo-1-(trifluoromethoxy)benzene
3-(Trifluoromethoxy)bromobenzene 99%
3-(Trifluoromethoxy)bromobenzene99%
1-BROMO-3-(TRIFLUOROMETHOXY)BENZENE/3-BROMO-TRIFLUOROMETHOXYBENZENE
1-BROMO-3-(TRIFLUOROMETHOXY)BENZENE 99%
1-Bromo-3-(trifluoromethoxy)benzene, 98+%
[Molecular Formula]

C7H4BrF3O
[MDL Number]

MFCD00040943
[Molecular Weight]

241.01
[MOL File]

2252-44-0.mol
Chemical PropertiesBack Directory
[Appearance]

Clear very faintly yellow liquid
[Boiling point ]

156-158 °C
[density ]

1.62 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.462(lit.)
[Fp ]

145 °F
[storage temp. ]

Sealed in dry,Room Temperature
[form ]

clear liquid
[color ]

Colorless to Almost colorless
[Specific Gravity]

1.64
[BRN ]

1945938
[CAS DataBase Reference]

2252-44-0(CAS DataBase Reference)
[NIST Chemistry Reference]

3-(Trifluoromethoxy)bromobenzene(2252-44-0)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S37/39:Wear suitable gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
[WGK Germany ]

3
[Hazard Note ]

Irritant
[HazardClass ]

IRRITANT
[HS Code ]

29049090
Hazard InformationBack Directory
[Chemical Properties]

Clear very faintly yellow liquid
[Uses]

1-Bromo-3-(trifluoromethoxy)benzene may be used in the preparation of 1,2-dehydro-3-(trifluoromethoxy)benzene. It may be used in the synthesis of new electronically deficient atropisomeric diphosphine ligand (S)-CF3O-BiPhep [2,2′-bis(diphenylphosphino)-6,6′-ditrifluoromethoxy-1,1′-biphenyl].
[General Description]

1-Bromo-3-(trifluoromethoxy)benzene undergoes Diels-Alder reaction with lithium diisopropylamide (LDA) in THF and furan, to yield the corresponding 1,4-dihydro-1,4-epoxy-5- or 6-(trifluoromethoxy)naphthalenes.
Spectrum DetailBack Directory
[Spectrum Detail]

3-(Trifluoromethoxy)bromobenzene(2252-44-0)MS
3-(Trifluoromethoxy)bromobenzene(2252-44-0)1HNMR
3-(Trifluoromethoxy)bromobenzene(2252-44-0)13CNMR
3-(Trifluoromethoxy)bromobenzene(2252-44-0)IR1
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

1-Bromo-3-(trifluoromethoxy)benzene, 98+%(2252-44-0)
[Sigma Aldrich]

2252-44-0(sigmaaldrich)
[TCI AMERICA]

1-Bromo-3-(trifluoromethoxy)benzene,>98.0%(GC)(2252-44-0)
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