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ChemicalBook--->CAS DataBase List--->224311-49-3

224311-49-3

224311-49-3 Structure

224311-49-3 Structure
IdentificationBack Directory
[Name]

2-DI-T-BUTYLPHOSPHINO-2'-(N,N-DIMETHYLAMINO)BIPHENYL
[CAS]

224311-49-3
[Synonyms]

tBuDavePhos
98% tBuDavePhos
t-Butyl DavePhos
t-BuDavePhos 97%
2-(Di-tert-butylphosphino)-2'-
2-DI-T-BUTYLPHOSHINO-2''-(N,N-DIMETHYLAMINO)BIPHENYL
2-DI-T-BUTYLPHOSPHINO-2'-(N,N-DIMETHYLAMINO)BIPHENYL
2-DI-TERT-BUTYLPHOSHINO-2'-(N,N-DIMETHYLAMINO)BIPHENYL
2-DI-TERT-BUTYLPHOSPHINO-2'-(N,N-DIMETHYLAMINO)BIPHENYL
2-Di-t-butylphosphino-2'-(N,N-dimethylamino)biphenyl,98%
2′-(Di-tert-butylphosphino)-N,N-dimethylbiphenyl-2-amine
2-[2-(di-tert-butylphosphanyl)phenyl]-N,N-diMethylaniline
2-(Di-tert-butylphosphiNA)-2'-(N,N-diMethylaMiNA)biphenyl
2-Di-tert-butylphosphino-2'-(N,N-dimethylamino)biphenyl,98%
[2'-(DI-TERT-BUTYL-PHOSPHANYL)-BIPHENYL-2-YL]-DIMETHYL-AMINE
2'-(Di-tert-butylphosphino)-N,N-diMethyl-[1,1'-biphenyl]-2-aMine
2-Di-t-butylphosphino-2'-(N,N-dimethylamino))-1,1'-biphenyl, 98%
2-Di-t-butylphosphino-2'-(N,N-dimethylamino)biphenyl, (tBuDavePhos)
2-Di-t-butylphosphino-2'-(N,N-diMethylaMino)biphenyl,98% tBuDavePhos
2'-[Bis(1,1-dimethylethyl)phosphino]-N,N-dimethyl-[1,1'-biphenyl]-2-amine
2-Di-t-butylphosphino-2'-(N,N-dimethylamino))-1,1'-biphenyl, 98% tBuDavePhos
[1,1''-BIPHENYL]-2-AMINE, 2''-[BIS(1,1-DIMETHYLETHYL)PHOSPHINO]-N,N-DIMETHYL-
[EINECS(EC#)]

607-073-3
[Molecular Formula]

C22H32NP
[MDL Number]

MFCD03426986
[MOL File]

224311-49-3.mol
[Molecular Weight]

341.47
Chemical PropertiesBack Directory
[Appearance]

White crystals or crystalline powder
[Melting point ]

115-117 °C
[Boiling point ]

451.6±38.0 °C(Predicted)
[storage temp. ]

Inert atmosphere,Room Temperature
[form ]

crystal
[pka]

5.07±0.18(Predicted)
[color ]

white
[Sensitive ]

Air Sensitive
[InChI]

InChI=1S/C22H32NP/c1-21(2,3)24(22(4,5)6)20-16-12-10-14-18(20)17-13-9-11-15-19(17)23(7)8/h9-16H,1-8H3
[InChIKey]

PHLPNEHPCYZBNZ-UHFFFAOYSA-N
[SMILES]

C1(C2=CC=CC=C2P(C(C)(C)C)C(C)(C)C)=CC=CC=C1N(C)C
Hazard InformationBack Directory
[Chemical Properties]

White crystals or crystalline powder
[Uses]

suzuki reaction
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

37/39-26
[WGK Germany ]

3
[TSCA ]

No
[HS Code ]

29319090
Questions And AnswerBack Directory
[Reaction]

  1. Useful ligand for Pd-catalyzed carbon-oxygen bond forming reactions.
  2. Ligand used selective Pd-catalyzed arylation of ammonia. Application to the synthesis of dibenzodiazepines.
  3. Ligand used for selective Pd-catalyzed silylation of aryl chlorides.
  4. Ligand used for Pd(0)-catalyzed direct dehydrative coupling of terminal alkynes with allylic alcohols to access 1,4-enynes. 
Reactions of 224311-49-3
Spectrum DetailBack Directory
[Spectrum Detail]

2-DI-T-BUTYLPHOSPHINO-2'-(N,N-DIMETHYLAMINO)BIPHENYL(224311-49-3)1HNMR
2-DI-T-BUTYLPHOSPHINO-2'-(N,N-DIMETHYLAMINO)BIPHENYL(224311-49-3)31PNMR
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