| Identification | Back Directory | [Name]
N-HEXYLLITHIUM | [CAS]
21369-64-2 | [Synonyms]
HEXYLLITHIUM
N-HEXYLLITHIUM
1-Lithiohexane
1-Hexyllithium
lithium,hexane
Lithium, hexyl-
hexyllithium solution
N-HEXYLLITHIUM: 25% IN HEXANE, 1.9M
HEXYLLITHIUM, 2.3M SOLUTION IN HEXANE
HEXYLLITHIUM SOLUTION, ~2.3 M IN HEXANE
Hexyllithium (30% in Hexane, ca. 2.3mol/L)
n-Hexyllithium, 33 wt.% solution in n-hexane
n-Hexyllithium, 33% (ca 2.47M) soln. in hexane
HexyllithiuM, 2.5 M solution in Hexane, SpcSeal
n-Hexyllithium33 wt.% solution in n-hexaneAcroSeal§3
n-Hexyllithium, 33 wt.% solution in n-hexane, AcroSeal | [EINECS(EC#)]
404-950-0 | [Molecular Formula]
C6H13Li | [MDL Number]
MFCD00191446 | [MOL File]
21369-64-2.mol | [Molecular Weight]
92.11 |
| Chemical Properties | Back Directory | [Appearance]
often supplied as a deep yellow solution (ca 2M) in hexane | [Boiling point ]
69 °C
| [density ]
0.708 g/mL at 25 °C
| [vapor pressure ]
26.9-39.3hPa at 20-35℃ | [Fp ]
16 °F
| [storage temp. ]
2-8°C
| [color ]
yellow-brown
| [Stability:]
Stable, but highly flammable. Reacts violently with water, releasing flammable gas. May spontaneously inflame in air. Moisture and air sensitive. Incompatible with water, alcohols, halocarbons. | [Sensitive ]
Moisture Sensitive | [BRN ]
3600261 | [EPA Substance Registry System]
Lithium, hexyl- (21369-64-2) |
| Hazard Information | Back Directory | [Chemical Properties]
often supplied as a deep yellow solution (ca 2M) in hexane | [Description]
n-Hexyllithium [21369-64-2], C6H13Li, Mr 92.11, r 0.766 g/cm3 is a pyrophoric colorless and viscous liquid in the neat state. It is commercially available as a 33 % solution in technical-grade hexane. Its reactivity resembles that of n-butyllithium and it can thus principally be used for the same applications. An advantage is that it does not form gaseous byproducts in deprotonation reactions and on hydrolysis, but liquid hexane instead. |
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