Identification | More | [Name]
Perylene | [CAS]
198-55-0 | [Synonyms]
LT-E602 PERYLENE Perilene Perylene> alpha-perylene Perylene, 98+% PERYLENE 99+% PERYLENE OEKANAL Perylene(Rri6401) perylene solution PERYLENE, SUBLIMED PERI-DINAPHTHALENE Perylene, 99+% 1GR PERYLENE, 50MG, NEAT Perylene(Rri6401)~95% DIBENZ[DE,KL]ANTHRACENE PERYLENE OEKANAL, 250 MG PERYLENE, SUBLIMED, 99.5+% PERYLENE, FOR FLUORESCENCE PERYLENE FOR SYNTHESIS 1 G PERYLENE FOR SYNTHESIS 5 G Perylene@50 μg/mL in Toluene Perylene 200 μg/mL In Toluene Perylene subliMed grade, >=99.5% Perylene(purifiedbysublimation)> PERYLENE, 1X1ML, CH2CL2, 2000UG/ML Perylene (purified by subliMation) Perylene (refined product of P0078) Dibenz[de,kl]anthracene
Peri-dinaphthalene | [EINECS(EC#)]
205-900-9 | [Molecular Formula]
C20H12 | [MDL Number]
MFCD00004142 | [Molecular Weight]
252.31 | [MOL File]
198-55-0.mol |
Chemical Properties | Back Directory | [Appearance]
brown solid | [Melting point ]
276-279 °C (lit.) | [Boiling point ]
400 °C | [density ]
1.35 | [vapor pressure ]
<0.001 hPa (20 °C) | [refractive index ]
1.6292 (estimate) | [Fp ]
>200 °C | [storage temp. ]
2-8°C | [solubility ]
<0.0001g/l | [form ]
Powder | [color ]
Ochre to brown | [Stability:]
Stable. Incompatible with strong oxidizing agents. Combustible. | [Water Solubility ]
INSOLUBLE | [Merck ]
14,7184 | [BRN ]
1911335 | [InChIKey]
CSHWQDPOILHKBI-UHFFFAOYSA-N | [CAS DataBase Reference]
198-55-0(CAS DataBase Reference) | [IARC]
3 (Vol. Sup 7, 92) 2010 | [NIST Chemistry Reference]
Perylene(198-55-0) | [EPA Substance Registry System]
198-55-0(EPA Substance) |
Safety Data | Back Directory | [Hazard Codes ]
Xn,T | [Risk Statements ]
R40:Limited evidence of a carcinogenic effect. R63:Possible risk of harm to the unborn child. R43:May cause sensitization by skin contact. R36/37/38:Irritating to eyes, respiratory system and skin . R23/24/25:Toxic by inhalation, in contact with skin and if swallowed . R45:May cause cancer. | [Safety Statements ]
S22:Do not breathe dust . S24/25:Avoid contact with skin and eyes . S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . S36/37:Wear suitable protective clothing and gloves . S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) . S53:Avoid exposure-obtain special instruction before use . | [RIDADR ]
2811 | [WGK Germany ]
3
| [RTECS ]
SE3794000
| [TSCA ]
Yes | [HazardClass ]
6.1(b) | [PackingGroup ]
III | [HS Code ]
29029080 | [Hazardous Substances Data]
198-55-0(Hazardous Substances Data) | [Toxicity]
mmo-sat 25 nmol/plate TXCYAC 18,219,80 |
Raw materials And Preparation Products | Back Directory | [Preparation Products]
Inositol-->Solvent Green 5-->3,10-DibroMoperylene-->1,8-DICHLORONAPHTHALENE-->3-BroMoperylene-->Phenanthridine-->2,3,6,7-TETRACHLORONAPHTHALENE-->1,4,6-TRICHLORONAPHTHALENE-->1,2,3,6,8-PENTACHLORONAPHTHALENE |
Hazard Information | Back Directory | [Chemical Properties]
brown solid | [Uses]
Perylene has been used as an acceptor for pristine C70 to be used as a sensitizer for efficient triplet-triplet annihilation upconversion; which has shown improved stability under continuous laser irradiation compared to the benchmark Pt(II)-ocetaethylprphyrin. Perylene has also been used as a dopant representing blue fluorescent dye on a white-emitting polymer film. Dyes and metabolites. | [Definition]
ChEBI: An ortho- and peri-fused polycyclic arene comprising of five benzene rings that is anthracene in which the d,e and k,l sides are fused to benzene rings. | [General Description]
Perylene molecules are fluorescent in nature. Ultraviolet photoemission spectroscopy and low energy electron diffraction of the structure of 4? thick perylene dye layers adsorbed on the surface of Ru (0001) has been investigated. | [Safety Profile]
Questionable carcinogen. Mutation data reported. Whenheated to decomposition it emits acrid smoke and irritating fumes. | [Purification Methods]
Purify perylene by silica-gel chromatography of its recrystallised picrate. [Ware J Am Chem Soc 83 4374 1961.] Crystallise it from *benzene, toluene or EtOH and sublime it at 142o in a flow of oxygen-free nitrogen. It forms a 1:1 *benzene-complex (m 223-224.5o needles from *C6H6), and a 1:2 *benzene-complex (m 154-155o from *C6H6 or H2O). The 2,4,7-trinitrofluoren-9-one has m 270-271o (from EtOH/*C6H6). [Gorman et al. J Am Chem Soc 107 4404 1985, Johansson et al. J Am Chem Soc 109 7374 1987, Beilstein 5 III 2521, 5 IV 2689.] |
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