| Identification | More | [Name]
N-AMINOPHTHALIMIDE | [CAS]
1875-48-5 | [Synonyms]
2-AMINOISOINDOLINE-1,3-DIONE
N-AMINOPHTHALIMIDE
N,N-PHTHALOYLHYDRAZINE, UNSYM
SPECS AQ-344/40414632
Aminophthalimidetech
N-AMINOPHTHALIMIDE, TECH., 90%
N-Aminophthalimide, 90%, tech.
2-Amino-2H-isoindole-1,3-dione
Phthalimidylamine | [EINECS(EC#)]
217-505-9 | [Molecular Formula]
C8H6N2O2 | [MDL Number]
MFCD00005895 | [Molecular Weight]
162.15 | [MOL File]
1875-48-5.mol |
| Chemical Properties | Back Directory | [Appearance]
white to off-white crystalline powder | [Melting point ]
200-202 °C(lit.)
| [Boiling point ]
288.82°C (rough estimate) | [density ]
1.3264 (rough estimate) | [refractive index ]
1.5770 (estimate) | [storage temp. ]
2-8°C
| [solubility ]
Solubility in hot methanol almost transparent. | [form ]
powder to crystal | [pka]
-1.73±0.20(Predicted) | [color ]
White to Light yellow | [BRN ]
383756 | [InChI]
InChI=1S/C8H6N2O2/c9-10-7(11)5-3-1-2-4-6(5)8(10)12/h1-4H,9H2 | [InChIKey]
KSILMCDYDAKOJD-UHFFFAOYSA-N | [SMILES]
C1(=O)C2=C(C=CC=C2)C(=O)N1N | [CAS DataBase Reference]
1875-48-5(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xn | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin .
R42/43:May cause sensitization by inhalation and skin contact . | [Safety Statements ]
S22:Do not breathe dust .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37:Wear suitable protective clothing and gloves .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [WGK Germany ]
3
| [F ]
9 | [HS Code ]
29251900 |
| Hazard Information | Back Directory | [Chemical Properties]
white to off-white crystalline powder | [Uses]
It is employed in the aziridination of chiral N-enoyl sultams. It is also used in the synthesis of n-phthalimidoaziridines | [Purification Methods]
The imide has been recrystallised from 96% EtOH (solubility is ~2% at boiling temperature) to form a yellow solution. It sublimes in vacuo at ca 150o. It solidifies after melting, and remelts at 338-341o (see phthalhydrazide in “Heterocyclic Compounds, Chapter 4”). [Beilstein 22/11 V 122.] |
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