| Identification | More | [Name]
DIETHYL PHENYLPHOSPHONATE | [CAS]
1754-49-0 | [Synonyms]
AURORA KA-1484
BENZENEPHOSPHONIC ACID DIETHYL ESTER
DIETHYL BENZENEPHOSPHONATE
DIETHYL PHENYLPHOSPHONATE
PHENYLPHOSPHONIC ACID DIETHYL ESTER
phenyl-phosphonicacidiethylester
Diethoxyphosphinylbenzene
Phenylphosphonic acid diethyl
TA03770000 | [EINECS(EC#)]
217-129-5 | [Molecular Formula]
C10H15O3P | [MDL Number]
MFCD00015136 | [Molecular Weight]
214.2 | [MOL File]
1754-49-0.mol |
| Safety Data | Back Directory | [Risk Statements ]
R22:Harmful if swallowed. | [Safety Statements ]
S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S36/37:Wear suitable protective clothing and gloves . | [RIDADR ]
2810 | [RTECS ]
TA0377000 | [PackingGroup ]
III | [HS Code ]
29319090 | [Toxicity]
mouse,LD50,intraperitoneal,790mg/kg (790mg/kg),Farmakologiya i Toksikologiya Vol. 10, Pg. 121, 1975. |
| Hazard Information | Back Directory | [Uses]
Diethyl phenylphosphonate is a liquid that can be used as an organophosphine ligand in organic synthesis. | [Synthesis Reference(s)]
Journal of the American Chemical Society, 69, p. 2020, 1947 DOI: 10.1021/ja01200a059
The Journal of Organic Chemistry, 39, p. 3612, 1974 DOI: 10.1021/jo00938a045 | [Synthesis]
A dried 25 mL flask was charge with triethyl phosphite (11.0 mmol, 1.27 mL) and benzoyl chloride (10.0 mmol, 1.72 mL). After the mixture was stirred for 12 h at room temperature, the crude product was purified by column chromatography over silica gel (300–400 mesh) using CH2Cl2 as an eluent to give analytically pure product Diethyl Phenylphosphonate. |
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