Identification | More | [Name]
Carbonyltris(triphenylphosphine)rhodium(I) hydride | [CAS]
17185-29-4 | [Synonyms]
CARBONYLHYDRIDOTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) CARBONYLTRIS(TRIPHENYLPHOSPHINE)RHODIUM(1) HYDRIDE CARBONYLTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) HYDRIDE HYDRIDOCARBONYLTRIS(TRIPHENYLPHOSPHINE)RHODIUM (I) TRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) CARBONYL HYDRIDE (betab-5-23)-rhodiu carbonylhydrotris(triphenylphosphine)rhodium TRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) & Carbonylhydridotris(triphenylphosphine)rhodium(I).99.9% CARBONYLHYDIDOTRIS (TRIPHENYLPHOSPHINE) RHODIUM(I) Hydridocarbonyltris(triphenylphosphine)rhodium(I),98% Rhodium, carbonylhydrotris(triphenylphosphine)-, (TB-5-23)- tris(triphenylphosphine)rhodium carbonyl hydride Carbonyltris(triphenylphosphine)rhodium Carbonylhydrotris(triphenylphosphin)rhodium Carbonylhydridotris(triphenylphosphine)rhodium(I), Rh 10.0% min Efficient hydroformylation catalyst. Unstable in solution in presence of air. Carbonylhydridotris(triphenylphosphine)rhodium(I), Rh 11.2% rhodium(I) tris(triphenylphosphine) carbonyl hydride Carbonyl hydridotris(triphenylphosphine) rhodium | [EINECS(EC#)]
241-230-3 | [Molecular Formula]
C55H48OP3Rh | [MDL Number]
MFCD00151644 | [Molecular Weight]
920.8 | [MOL File]
17185-29-4.mol |
Safety Data | Back Directory | [Hazard Codes ]
T | [Risk Statements ]
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed . | [Safety Statements ]
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . S36/37:Wear suitable protective clothing and gloves . | [RIDADR ]
UN 2811 6.1/PG 2
| [WGK Germany ]
1
| [F ]
10-23 | [TSCA ]
Yes | [HazardClass ]
4.3 | [PackingGroup ]
III | [HS Code ]
28439000 |
Hazard Information | Back Directory | [Chemical Properties]
yellow crystals | [Uses]
Catalyst. | [Uses]
Hydrogenation, hydrosilation, isomerization, carbonylation, hydroformylation, oxidation | [Production Methods]
Carbonyltris(triphenylphosphine)rhodium(I) hydride is obtained by the reaction of a solution of RhCl3.3 H2O in alcoholic alkali with aqueous formaldehyde (the carbon monoxide source) and an excess of triphenyl phosphine. The commercial product is a microcrystalline powder with a purity of 97 % (Degussa). |
|
|