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ChemicalBook--->CAS DataBase List--->17185-29-4

17185-29-4

17185-29-4 Structure

17185-29-4 Structure
IdentificationMore
[Name]

Carbonyltris(triphenylphosphine)rhodium(I) hydride
[CAS]

17185-29-4
[Synonyms]

CARBONYLHYDRIDOTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I)
CARBONYLTRIS(TRIPHENYLPHOSPHINE)RHODIUM(1) HYDRIDE
CARBONYLTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) HYDRIDE
HYDRIDOCARBONYLTRIS(TRIPHENYLPHOSPHINE)RHODIUM (I)
TRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) CARBONYL HYDRIDE
(betab-5-23)-rhodiu
carbonylhydrotris(triphenylphosphine)rhodium
TRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) &
Carbonylhydridotris(triphenylphosphine)rhodium(I).99.9%
CARBONYLHYDIDOTRIS (TRIPHENYLPHOSPHINE) RHODIUM(I)
Hydridocarbonyltris(triphenylphosphine)rhodium(I),98%
Rhodium, carbonylhydrotris(triphenylphosphine)-, (TB-5-23)-
tris(triphenylphosphine)rhodium carbonyl hydride
Carbonyltris(triphenylphosphine)rhodium
Carbonylhydrotris(triphenylphosphin)rhodium
Carbonylhydridotris(triphenylphosphine)rhodium(I), Rh 10.0% min
Efficient hydroformylation catalyst. Unstable in solution in presence of air.
Carbonylhydridotris(triphenylphosphine)rhodium(I), Rh 11.2%
rhodium(I) tris(triphenylphosphine) carbonyl hydride
Carbonyl hydridotris(triphenylphosphine) rhodium
[EINECS(EC#)]

241-230-3
[Molecular Formula]

C55H48OP3Rh
[MDL Number]

MFCD00151644
[Molecular Weight]

920.8
[MOL File]

17185-29-4.mol
Chemical PropertiesBack Directory
[Appearance]

yellow crystals
[Melting point ]

150 °C (dec.) (lit.)
[density ]

1.33
[vapor pressure ]

0Pa at 25℃
[storage temp. ]

2-8°C
[solubility ]

Soluble in hydrocarbons (e.g. benzene and toluene) with dissociation of phosphine ligands
[form ]

crystal
[color ]

light yellow
[Hydrolytic Sensitivity]

7: reacts slowly with moisture/water
[Sensitive ]

Moisture Sensitive
[Merck ]

9758
[Exposure limits]

ACGIH: TWA 0.01 mg/m3; TWA 1 mg/m3
NIOSH: IDLH 2 mg/m3; IDLH 100 mg/m3; TWA 0.001 mg/m3; TWA 0.1 mg/m3
[InChIKey]

CEKFIOLKXHVOKA-UHFFFAOYSA-N
[CAS DataBase Reference]

17185-29-4(CAS DataBase Reference)
[NIST Chemistry Reference]

carbonyl(hydrido)tris(triphenylphosphine)rhodium(17185-29-4)
[EPA Substance Registry System]

Rhodium, carbonylhydrotris(triphenylphosphine)-, (TB-5-23)- (17185-29-4)
Safety DataBack Directory
[Hazard Codes ]

T
[Risk Statements ]

R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
[Safety Statements ]

S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37:Wear suitable protective clothing and gloves .
[RIDADR ]

UN 2811 6.1/PG 2
[WGK Germany ]

1
[F ]

10-23
[TSCA ]

Yes
[HazardClass ]

4.3
[PackingGroup ]

III
[HS Code ]

28439000
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Carbonyltris(triphenylphosphine)rhodium(I) hydride(17185-29-4).msds
Hazard InformationBack Directory
[Chemical Properties]

yellow crystals
[Uses]

Catalyst.
[Uses]

Hydrogenation, hydrosilation, isomerization, carbonylation, hydroformylation, oxidation
[Production Methods]

Carbonyltris(triphenylphosphine)rhodium(I) hydride is obtained by the reaction of a solution of RhCl3.3 H2O in alcoholic alkali with aqueous formaldehyde (the carbon monoxide source) and an excess of triphenyl phosphine. The commercial product is a microcrystalline powder with a purity of 97 % (Degussa).
Spectrum DetailBack Directory
[Spectrum Detail]

Carbonyltris(triphenylphosphine)rhodium(I) hydride(17185-29-4)IR1
Carbonyltris(triphenylphosphine)rhodium(I) hydride(17185-29-4)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Carbonyltris(triphenylphosphine)rhodium(I)hydride, 97%(17185-29-4)
[Alfa Aesar]

Carbonylhydridotris(triphenylphosphine)rhodium(I), Rh 10.0% min(17185-29-4)
[Sigma Aldrich]

17185-29-4(sigmaaldrich)
[TCI AMERICA]

Carbonyltris(triphenylphosphine)rhodium(I) Hydride(17185-29-4)
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