| Identification | More | [Name]
1-Bromopyrene | [CAS]
1714-29-0 | [Synonyms]
1-BROMOPYRENE
Pyrene, 1-bromo-
2-Bromopyrene
1-Pyrenyl bromide | [EINECS(EC#)]
626-844-5 | [Molecular Formula]
C16H9Br | [MDL Number]
MFCD00015767 | [Molecular Weight]
281.15 | [MOL File]
1714-29-0.mol |
| Chemical Properties | Back Directory | [Melting point ]
102-105 °C (lit.) | [Boiling point ]
255 °C / 7mmHg | [density ]
1.4316 (rough estimate) | [refractive index ]
1.6000 (estimate) | [storage temp. ]
Keep in dark place,Sealed in dry,Room Temperature | [solubility ]
Chloroform (Soluble), DMSO (Slightly, Heated, Sonicated), Methanol (Slightly) | [form ]
Crystalline | [color ]
White to Pale Yellow | [InChIKey]
HYGLETVERPVXOS-UHFFFAOYSA-N | [CAS DataBase Reference]
1714-29-0(CAS DataBase Reference) | [NIST Chemistry Reference]
1-Bromopyrene(1714-29-0) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [WGK Germany ]
3
| [HS Code ]
29039990 |
| Hazard Information | Back Directory | [Chemical Properties]
White to yellow to light brown powder | [Uses]
1-Bromopyrene is used in the cleavage of DNA in studies. It is also used in the preparation of DNA base analogs. | [Preparation]
1-Bromopyrene is an important intermediate in the OLED material industry. The synthesis method is as follows: pyrene is dissolved in an organic solvent dichloromethane, and dibromohydantoin is added for reaction, filtered, and the obtained solid is recrystallized to obtain 1-bromopyrene. | [Synthesis Reference(s)]
Synthetic Communications, 18, p. 2207, 1988 DOI: 10.1080/00397918808082362 | [General Description]
1-Bromopyrene, a polycyclic aromatic hydrocarbon (PAH), is a mono bromo substituted pyrene derivative. Its synthesis has been reported. Its gas phase UV-absorption spectra in the UV wavelength range at elevated temperature has been studied. Electron affinitiy (EA) of 1-bromopyrene has been investigated using electron attachment desorption chemical ionization mass spectrometry (DCI-MS) and triple quadrupole tandem mass spectrometry. It participates in the synthesis of novel ruthenium (II) bipyridine or terpyridine complexes bearing pyrene moiety. The reaction of 1-bromopyrene cation radical with water in acetonitrile has been analyzed using the electron transfer stopped-flow (ETSF) method. |
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