| Identification | More | [Name]
DIPHENYLCHLOROSILANE | [CAS]
1631-83-0 | [Synonyms]
CHLORODIPHENYLSILANE
DIPHENYLCHLOROSILANE
chlorodiphenyl-silan
Diphenylsilyl chloride
Silane, chlorodiphenyl-
CHLORODIPHENYLSILANE, TECH., 90%
Chlorodiphenylsilane, 90+% | [EINECS(EC#)]
216-634-8 | [Molecular Formula]
C12H11ClSi | [MDL Number]
MFCD00045144 | [Molecular Weight]
218.75 | [MOL File]
1631-83-0.mol |
| Chemical Properties | Back Directory | [Boiling point ]
143 °C10 mm Hg(lit.)
| [density ]
1.118 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.578(lit.)
| [Fp ]
>230 °F
| [solubility ]
sol benzene, chloroform, carbon tetrachloride, and
ether. | [Specific Gravity]
1.118 | [Water Solubility ]
Reacts with water. | [Hydrolytic Sensitivity]
8: reacts rapidly with moisture, water, protic solvents | [Sensitive ]
Moisture Sensitive | [BRN ]
2937164 | [InChIKey]
VTMOWGGHUAZESJ-UHFFFAOYSA-N | [CAS DataBase Reference]
1631-83-0(CAS DataBase Reference) | [EPA Substance Registry System]
Silane, chlorodiphenyl- (1631-83-0) |
| Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R14:Reacts violently with water.
R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 2987 8/PG 2
| [WGK Germany ]
1
| [F ]
10-21 | [TSCA ]
Yes | [HazardClass ]
8 | [PackingGroup ]
II | [HS Code ]
29319090 |
| Hazard Information | Back Directory | [Physical properties]
bp 140–145°C/7 mmHg (99–101°C/1 mmHg;
83–85°C/0.4 mmHg); d 1.137 g cm?3; n 1.5845. | [Uses]
Chlorodiphenylsilane is used in Medicine field, electronics industry, polymer materials. It is used in reduction of alcohols. | [Uses]
Organolithium and Grignard reagents react with chlorodiphenylsilane
to produce substituted alkyl- or aryldiphenylsilanes (eqs 4
and 5).
| [Preparation]
chlorodiphenylsilane may be prepared in
high yield by treatment of diphenylsilane with triphenylmethyl
chloride in refluxing benzene or with PCl5 at rt in CCl4. |
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