| Identification | More | [Name]
CYCLODODECYLAMINE | [CAS]
1502-03-0 | [Synonyms]
AMINOCYCLODODECANE
CYCLODODECYLAMINE
TIMTEC-BB SBB003726
Cyclododecanamine
1-Cyclododecanamine | [EINECS(EC#)]
216-118-2 | [Molecular Formula]
C12H25N | [MDL Number]
MFCD00003718 | [Molecular Weight]
183.33 | [MOL File]
1502-03-0.mol |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [RIDADR ]
UN 3259 8/PG 3
| [WGK Germany ]
3
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| Hazard Information | Back Directory | [Chemical Properties]
CLEAR SLIGHTLY YELLOW LIQUID AFTER MELTING | [Production Methods]
Cyclododecylamine is produced by reduction of cyclododecanone oxime with sodium and an alcohol, by catalytic reduction of nitrocyclododecane with hydrogen, by Ritter reaction of cyclododecene with hydrocyanic acid, or by hydrogenation of cyclododecanone under amination conditions. The reaction of cyclododecylamine with propylene oxide leads to a product that can undergo cyclization to give the fungicide Dodemorph (BASF). The compound behaves chemically as a primary amine.
| [Purification Methods]
It can be purified via the hydrochloride salt m 274-275o (from EtOH) or the picrate m 232-234o, and the free base is distilled preferably at water-pump vacuum [Prelog et al. Helv Chim Acta 33 365 1950]. |
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