| Identification | More | [Name]
Ruthenium(III) chloride | [CAS]
14898-67-0 | [Synonyms]
RUTHENIUM(+3)CHLORIDE HYDRATE
RUTHENIUM CHLORIDE, HYDROUS
RUTHENIUM(III) CHLORIDE
RUTHENIUM(III) CHLORIDE HYDRATE
RUTHENIUM(III) CHLORIDE N-HYDRATE
RUTHENIUM TRICHLORIDE HYDRATE
RUTHENIUM TRICHLORIDE N-HYDRATE
RutheniumchloridehydrateRu
activated alumin(I)um oxide
Ruthenium(III) chloride hydrate, 99.98% metals basis
Ruthenium(III) chloride hydrate, ReagentPlus®,
RUTHENIUM(III) CHLORIDE HYDRATE (35-40% RU)
RUTHENIUM (III) CHLORIDE HYDRATE (40-43% RU) (99.9%-RU)
RUTHENIUM CHLORIDE HYDRATE
RUTHENIUM CHLORIDE, HYDRATED REAGENT
Ruthenium chloride (RuCl3), hydrate
ruthenium(iii) chloride hydrate, premion
RUTHENIUM(III)CHLORIDEHYDRATE,35-42%RU
Ruthenium(III)-chlorid-hydrat
Active oxidative aluminum | [EINECS(EC#)]
233-167-5 | [Molecular Formula]
Cl3Ru | [MDL Number]
MFCD00149844 | [Molecular Weight]
207.43 | [MOL File]
14898-67-0.mol |
| Chemical Properties | Back Directory | [Appearance]
dark brown to black powder | [Melting point ]
>300°C | [density ]
3.11 g/cm3 | [storage temp. ]
Store at +5°C to +30°C. | [solubility ]
Water (Slightly) | [form ]
Powder | [color ]
Dark brown to black | [PH]
<2 (H2O, 20℃)Aqueous solution | [Water Solubility ]
soluble | [Sensitive ]
Hygroscopic | [Merck ]
14,8302 | [Stability:]
hygroscopic | [InChI]
InChI=1S/3ClH.H2O.Ru/h3*1H;1H2;/q;;;;+3/p-3 | [InChIKey]
BIXNGBXQRRXPLM-UHFFFAOYSA-K | [SMILES]
[Ru](Cl)(Cl)Cl.O | [CAS DataBase Reference]
14898-67-0(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns.
R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R22:Harmful if swallowed. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S61:Avoid release to the environment. Refer to special instructions safety data sheet . | [RIDADR ]
UN 3260 8/PG 2
| [WGK Germany ]
2
| [RTECS ]
VM2650000 | [TSCA ]
Yes | [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
28439000 |
| Hazard Information | Back Directory | [Chemical Properties]
Ruthenium(III) chloride hydrate(14898-67-0) appears as dark brown to black powder. It cannot dissolve in cold water or carbon disulfide, but it can decompose in hot water. It is also insoluble in ethanol, but it can dissolve in hydrochloric acid. When combined with potassium iodide solution, it forms a precipitate of iodide. When reacted with hydrogen sulfide, it forms a precipitate of ruthenium trisulfide. It can react with ammonia, potassium cyanide, and potassium nitrite to form corresponding ammonia, cyanide, and nitroso complexes. It can also be reduced to blue divalent ruthenium ions by sodium amalgam or titanium trichloride. | [Application]
Ruthenium hydrated oxide, prepared from RhCl3 when deposited on titania nanotubes can be used as a catalyt system for selective oxidation of alcohols by oxygen. | [Uses]
Catalyzes the synthesis of 2-ethyl-3-methylquinolines from primary aromatic amines and triallylamine.1 | [Preparation]
Ruthenium(III) chloride hydrate can be synthesized by directly combining ruthenium metal and chlorine at high temperature. Alternatively, adding hydrochloric acid to ruthenium hydroxide and subsequently evaporating, concentrating, and crystallizing the mixture can also produce the desired compound. | [General Description]
Ruthenium(III) chloride hydrate, also called Ruthenium(III) trichloride hydrate, is widely used as a starting material in Ruthenium chemistry. It is used in the determination of sulfites, the manufacture of chlororuthenates, and as an electrode coating material.
| [Purification Methods]
Dissolve the salt in H2O, filter and concentrate to crystallisation in the absence of air to avoid oxidation. Evaporate the solution in a stream of HCl gas while being heated just below its boiling point until a syrup is formed and finally to dryness at 80-100o and dried in a vacuum over H2SO4. When heated at 700o in the presence of Cl2 the insoluble -form is obtained [Grube in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol II p 1598 1965, Carlsen et al. J Org Chem 46 3936 1981]. |
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