| Identification | More | [Name]
CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) | [CAS]
14871-41-1 | [Synonyms]
BIS(TRIPHENYLPHOSPHINE)IRIDIUMCARBONYL CHLORIDE
BIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) CARBONYL CHLORIDE
CARBONYLBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) CHLORIDE
CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I)
CHLOROCARBONYLBIS(TRIPHENYLPHOSPHINE)IRIDIUM (I)
IRIDIUM(I)BIS(TRIPHENYLPHOSPHINE)CARBONYL CHLORIDE
VASKA'S COMPLEX
carbonylchlorobis(triphenylphosphine)-iridiu
carbonylchlorobis(triphenylphosphine)iridium
CARBONYLBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I ) CHLORIDE, 99.99%
Chlorocarbonylbis(triphenylphosphine)iridium(I),99%VASKA'SCOMPLEX
vaska's catalyst
Bis-(triphenylphosphino)-iridium carbonyl chloride
Chlorocarbonylbis(triphenylphosphine)iridium(I), Iridium(I)bis(triphenylphosphine)carbonyl chloride | [EINECS(EC#)]
238-941-6 | [Molecular Formula]
C37H30ClIrOP2 | [MDL Number]
MFCD00009590 | [Molecular Weight]
780.25 | [MOL File]
14871-41-1.mol |
| Safety Data | Back Directory | [Risk Statements ]
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed . | [Safety Statements ]
S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes . | [RIDADR ]
UN2811 | [WGK Germany ]
3
| [TSCA ]
Yes | [HS Code ]
2931.90.6000 | [HazardClass ]
6.1 | [PackingGroup ]
III |
| Hazard Information | Back Directory | [Chemical Properties]
GREEN FINE CRYSTALLINE POWDER | [Uses]
Carbonylchlorobis(triphenylphosphine)iridium(I) is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuffs. |
| Questions And Answer | Back Directory | [Reaction]
- Catalyst for the intramolecular carbonylative [2+2+1] cycloaddition of allenynes.
- Catalyst for the selective hydrogenation of myrcene.
- Catalyst for silylation of ortho-functionalized aryl halides with hydrosilanes.
- Catalyst for synthesis of aldenamines from carboxamides by silane-reduction/dehydration under mild conditions.
- Hydrogen atom transfer catalyst for radical cyclizations.
- Complex for photocatalytic alkane dehydrogenation.
- Catalyst for chemoselective reductive nucleophilic addition to N-methoxyamides.
- Catalyst for chemoselective reductive alkynylation of tertiary amides.
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