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ChemicalBook--->CAS DataBase List--->14618-45-2

14618-45-2

14618-45-2 Structure

14618-45-2 Structure
IdentificationMore
[Name]

3-(TRIFLUOROACETYL)INDOLE
[CAS]

14618-45-2
[Synonyms]

2,2,2-TRIFLUORO-1-(1H-INDOL-3-YL)-1-ETHANONE
3-(TRIFLUOROACETYL)INDOLE
3-(TRIFLUOROACETYL)INDOLE 99%
[Molecular Formula]

C10H6F3NO
[MDL Number]

MFCD00182114
[Molecular Weight]

213.16
[MOL File]

14618-45-2.mol
Chemical PropertiesBack Directory
[Melting point ]

211-214 °C(lit.)
[Boiling point ]

308.6±37.0 °C(Predicted)
[density ]

1.423±0.06 g/cm3(Predicted)
[storage temp. ]

Sealed in dry,Room Temperature
[form ]

Solid
[pka]

14.31±0.30(Predicted)
[CAS DataBase Reference]

14618-45-2(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[WGK Germany ]

3
[HazardClass ]

IRRITANT
Hazard InformationBack Directory
[Uses]

  • Reactant for enantioselective synthesis of indoles via palladium-catalyzed kinetic asymmetrical alkylation
  • Reactant for preparation of N-pyridinyl indolecarboxamides via amidation of aminopyridine derivatives. with indolecarboxylic acid
  • Reactant for preparation of mast cell tryptase inhibitors, starting from indoles; using amidation as the key step
  • Reactant for formation of Michael adducts via Baylis-Hillman reaction
  • Reactant for preparation of indolecarboxamides via haloform cleavage of (trifluoroacetyl)indole with lithium dialkylamides
[Uses]

Reactant for enantioselective synthesis of indoles via palladium-catalyzed kinetic asymmetrical alkylation. Reactant for preparation of N-pyridinyl indolecarboxamides via amidation of aminopyridine derivatives. with indolecarboxylic acid 2 Reactant for preparation of mast cell tryptase inhibitors, starting from indoles; using amidation as the key step 3 Reactant for formation of Michael adducts via Baylis-Hillman reaction 4 Reactant for preparation of indolecarboxamides via haloform cleavage of (trifluoroacetyl)indole with lithium dialkylamides.
[General Description]

3-(Trifluoroacetyl)indole is a heterocyclic trifluoromethyl ketone. One of the methods reported for its synthesis is by the reaction of indole with trifluoroacetic anhydride.
Spectrum DetailBack Directory
[Spectrum Detail]

3-(TRIFLUOROACETYL)INDOLE(14618-45-2)FT-IR
3-(TRIFLUOROACETYL)INDOLE(14618-45-2)IR
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

14618-45-2(sigmaaldrich)
[TCI AMERICA]

3-(Trifluoroacetyl)indole(14618-45-2)
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