Identification | More | [Name]
1-(5-Chloro-2-hydroxyphenyl)ethanone | [CAS]
1450-74-4 | [Synonyms]
1-(5-CHLORO-2-HYDROXYPHENYL)-1-ETHANONE 1-(5-CHLORO-2-HYDROXYPHENYL)ETHAN-1-ONE 1-(5-CHLORO-2-HYDROXYPHENYL)ETHANONE 2'-HYDROXY-5'-CHLORO ACETOPHENONE 2-HYDROXY-5-CHLORO ACETOPHENONE 5'-CHLORO-2'-HYDROXYACETOPHENONE 5-CHLORO-2-HYDROXYACETOPHENONE AKOS BB-6937 ASISCHEM D38764 SALOR-INT L497495-1EA 2-Acetyl-4-chlorophenol Acetophenone, 5'-chloro-2'-hydroxy- Acetophenone,5-chloro-2-hydroxy- 5'-Chloro-2'-Hydroxy Acetophenone 2'-Hydorxy-5'-Chloro Acetophenone 2'-Hydorxy-5'-ChloroAcetophenone | [EINECS(EC#)]
215-916-8 | [Molecular Formula]
C8H7ClO2 | [MDL Number]
MFCD00067788 | [Molecular Weight]
170.59 | [MOL File]
1450-74-4.mol |
Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36:Wear suitable protective clothing . S37/39:Wear suitable gloves and eye/face protection . | [WGK Germany ]
3
| [Hazard Note ]
Irritant | [HS Code ]
29147000 |
Hazard Information | Back Directory | [Chemical Properties]
slightly yellow crystalline powder or chunks | [Uses]
5′-Chloro-2′-hydroxyacetophenone (5-chloro-2- hydroxyacetophenone) may be used in the synthesis of:
- 6-chloro-2-methyl-4H-chrome-4-one
- 1-(2-hydroxyphenyl)-5-phenyl-2,4-pentadien-1-ones
- 1-(2-hydroxyphenyl)-5-phenyl-2,4-pentadien-1-ones
- 2-styrenyl allyl ether
| [Preparation]
Preparation by Fries rearrangement of 4-chlorophenyl acetate with aluminium chloride without solvent between 110° and 200°(90–100% yield). | [General Description]
5′-Chloro-2′-hydroxyacetophenone (5-chloro-2- hydroxyacetophenone) on condensation with salicylhydrazide yields Schiff base, which is reported to form copper(II) complexes. Dipole moment of 5-chloro-2- hydroxyacetophenone has been evaluated in benzene solution. |
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