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ChemicalBook--->CAS DataBase List--->13323-81-4

13323-81-4

13323-81-4 Structure

13323-81-4 Structure
IdentificationMore
[Name]

ALPHA-METHYLBENZYL ALCOHOL
[CAS]

13323-81-4
[Synonyms]

(+/-)-1-PHENYLETHANOL
1-PHENYLETHANOL
1-PHENYLETHYL ALCOHOL
ALPHA-METHYLBENZYL ALCOHOL
A-METHYLBENZYL ALCOHOL
AURORA KA-7014
DL-1-Phenethylalcohol
DL-1-PHENYLETHANOL
DL-1-PHENYLETHYL ALCOHOL
DL-2-METHYL PHENYL METHANOL
DL-ALPHA-METHYLBENZYL ALCOHOL
DL-ALPHA-METHYLPHENYLCARBINOL
DL-A-METHYLBENZYL ALCOHOL
DL-METHYLPHENYLCARBINOL
DL-PHENYLMETHYLCARBINOL
DL-SEC-PHENETHYL ALCOHOL
dl-sec-phenylethanol
DL-STYRALYL ALCOHOL
FEMA 2685
MBA
[EINECS(EC#)]

202-707-1
[Molecular Formula]

C8H10O
[MDL Number]

MFCD00004508
[Molecular Weight]

122.16
[MOL File]

13323-81-4.mol
Chemical PropertiesBack Directory
[Melting point ]

19-20 °C(lit.)
[Boiling point ]

204 °C745 mm Hg(lit.)
[density ]

1.012 g/mL at 25 °C(lit.)
[vapor density ]

4.21 (vs air)
[vapor pressure ]

0.1 mm Hg ( 20 °C)
[refractive index ]

n20/D 1.527(lit.)
[Fp ]

185 °F
[Dielectric constant]

7.6(90℃)
[CAS DataBase Reference]

13323-81-4(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

R22:Harmful if swallowed.
R38:Irritating to the skin.
R41:Risk of serious damage to eyes.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S39:Wear eye/face protection .
[RIDADR ]

UN 2937 6.1/PG 3
[WGK Germany ]

1
[RTECS ]

DO9275000
[HazardClass ]

6.1
[PackingGroup ]

III
[Toxicity]

The acute oral LD50 in rats was reported as 400 mg/kg (Smyth & Carpenter, 1944). The acute dermal LD50 value in rabbits exceeded 2.5 g/kg (Moreno, 1973).
Raw materials And Preparation ProductsBack Directory
[Preparation Products]

FEMA 2686-->1-Phenylethyl chloroformate-->4-METHOXY-2-(1-PHENYL-ETHYL)-PHENOL-->1-PHENYLETHAN-1,2,2,2-D4-OL-->3-(3-METHYLPHENYL)PROPIOPHENONE
Hazard InformationBack Directory
[Chemical Properties]

Colorless liquid
[Occurrence]

Has apparently not been reported to occur in nature.
[Definition]

ChEBI: 1-phenylethanol is an aromatic alcohol that is ethanol substituted by a phenyl group at position 1. It has a role as a mouse metabolite.
[Preparation]

By hydrogenation or reduction of acetophenone; or from methyl magnesium chloride plus benzaldehyde by a Grignard-type reaction (Bedoukian, 1967).
[Metabolism]

Styrallyl alcohol is converted in rabbits into hippuric acid and methylphenylcarbinyl glucuronide, both optical forms of the carbinol behaving similarly. A small proportion (1-2%) is excreted as mandelic acid (Wjlliams, 1959).
[Purification Methods]

Purify the alcohol via its hydrogen phthalate. [See Houssa & Kenyon J Chem Soc 2260 1930.] Shake it with a solution of ferrous sulfate, and th
Spectrum DetailBack Directory
[Spectrum Detail]

ALPHA-METHYLBENZYL ALCOHOL(13323-81-4)MS
ALPHA-METHYLBENZYL ALCOHOL(13323-81-4)1HNMR
ALPHA-METHYLBENZYL ALCOHOL(13323-81-4)13CNMR
ALPHA-METHYLBENZYL ALCOHOL(13323-81-4)IR1
ALPHA-METHYLBENZYL ALCOHOL(13323-81-4)IR2
ALPHA-METHYLBENZYL ALCOHOL(13323-81-4)Raman
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

(+/-)-1-Phenylethanol, 97%(13323-81-4)
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