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ChemicalBook--->CAS DataBase List--->132-53-6

132-53-6

132-53-6 Structure

132-53-6 Structure
IdentificationMore
[Name]

2-Nitroso-1-naphthol
[CAS]

132-53-6
[Synonyms]

1,2-NAPHTHOQUINONE 2-OXIME
2-NITROSO-1-NAPHTHOL
BETA-NITROSO-ALPHA-NAPHTHOL
CI NO 10010
LABOTEST-BB LT00068475
1-Naphthalenol,2-nitroso-
1-Naphthol, 2-nitroso-
2-nitroso-1-naphthaleno
2-nitroso-1-Naphthalenol
2-nitroso-1-naphtho
2-Nitrosonaphthol
beta-Nitrosonaphthol
C.I. 76610
ci76610
2-Nitroiso-1-Naphthol
2-nitroso-1-naphthol (beta-alpha)
2-NITROSO-1-NAPHTHOL R. G.
2-Nitroso-1-NaphtholGr
1-hydroxy-2-nitrosonaphthalene
C.I.Oxidation Base 15
[EINECS(EC#)]

205-064-5
[Molecular Formula]

C10H7NO2
[MDL Number]

MFCD00003932
[Molecular Weight]

173.17
[MOL File]

132-53-6.mol
Chemical PropertiesBack Directory
[Appearance]

yellow-greenish to yellow-brownish powder
[Melting point ]

150-155 °C (dec.)(lit.)
[Boiling point ]

303.81°C (rough estimate)
[density ]

1.2427 (rough estimate)
[refractive index ]

1.5200 (estimate)
[Colour Index ]

10010
[form ]

Solid
[pka]

7.47±0.10(Predicted)
[color ]

Yellow needles from H2O or C6H6
[Odor]

Odorless
[Water Solubility ]

SLIGHTLY SOLUBLE
[BRN ]

1867919
[CAS DataBase Reference]

132-53-6(CAS DataBase Reference)
[NIST Chemistry Reference]

1-Naphthalenol, 2-nitroso-(132-53-6)
[EPA Substance Registry System]

132-53-6(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
[WGK Germany ]

3
[RTECS ]

QL4550000
[F ]

8
[HS Code ]

2929900090
[Safety Profile]

Moderately toxic by ingestion. Many nitroso compounds are carcinogens. Questionable carcinogen with experimental tumorigenic data. When heated to decomposition it emits toxic fumes of NOx. See also NITROSO COMPOUNDS.
[Hazardous Substances Data]

132-53-6(Hazardous Substances Data)
[Toxicity]

LD orl-rat: >500 mg/kg NCNSA6 5,35,53
Raw materials And Preparation ProductsBack Directory
[Raw materials]

1-Naphthol-->Congo red paper-->1,4-Naphthoquinone 1-oxime-->4-nitrosonaphthalen-1-ol-->1-Hydroxy-2-naphthoic acid-->2-NITRONAPHTHALENE-->2-Naphthylamine-->1,2-NAPHTHOQUINONE-->Cyclopropylamine
[Preparation Products]

2-Nitro-1-naphthol
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

2-Nitroso-1-naphthol(132-53-6).msds
Hazard InformationBack Directory
[Chemical Properties]

yellow-greenish to yellow-brownish powder
[General Description]

2-nitroso-1-naphthol helps in the extraction of cobalt ion as it is used as a selective complexing agent. It is used in the separation and preconcentration of Th(IV), Ti(IV), Fe(III), Pb(II) and Cr(III) by solid phase extraction.
[Purification Methods]

Purify the naphthol by recrystallisation from pet ether (b 60-80o) or by dissolving it in hot EtOH, followed by successive addition of small volumes of water (m 158o dec). It also crystallises from *C6H6 or H2O. Crystallisation from *C6H6/pet ether gives m (106-109 o, also 109.5o). It has max at 274.5 and 382nm (CHCl3). It complexes with metals. [Beilstein 7 H 712, 7 I 385, 7 II 647, 7 III 3688, 7 IV 2419.]
Spectrum DetailBack Directory
[Spectrum Detail]

2-Nitroso-1-naphthol(132-53-6)MS
2-Nitroso-1-naphthol(132-53-6)IR1
2-Nitroso-1-naphthol(132-53-6)IR2
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

2-Nitroso-1-naphthol, 97%(132-53-6)
[Sigma Aldrich]

132-53-6(sigmaaldrich)
[TCI AMERICA]

2-Nitroso-1-naphthol,>98.0%(GC)(T)(132-53-6)
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