| Identification | More | [Name]
TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE | [CAS]
13170-43-9 | [Synonyms]
TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE
(Trimethylsilyl)methylmagnesium chloride solution
(trimethylsilyl)methylmagnesium chl. sol
Trimethylsilylmethylmagnesium chloride (20% in ethyl ether
(TRIMETHYLSILYLMETHYL)MAGNESIUM CHLORIDE , 1.0M SOLUTION IN DIETHYL ETHER
(TRIMETHYLSILYL)METHYLMAGNESIUM CHL. SOL , 1 M IN DIETH.ETHER
[(Trimethylsilyl)methyl]magnesium Chloride 1.0 M In Diethyl Ether
[(Trimethylsilyl)methyl]magnesium Chloride, 1.0 M In Tetrahydrofuran
(Trimethylsilyl)methylmagnesium chloride, 1.1M solution in THF
Trimethylsiylmethylmagnesium chloride
Trimethylsilylmethylmagnesium Chloride (20% in Ethyl Ether, ca. 1mol/L)
(Trimethylsilyl)methylmagnesium chloride, 1,3m solution in THF
(Trimethylsilyl)methylmagnesium chloride1.3M solution in THFAcroSeal§3
(Trimethylsilylmethyl)chloromagnesium
Trimethylsilylmethylchloromagnesium | [Molecular Formula]
C4H11ClMgSi | [MDL Number]
MFCD00009916 | [Molecular Weight]
146.97 | [MOL File]
13170-43-9.mol |
| Chemical Properties | Back Directory | [Melting point ]
105.8-106.4 °C | [density ]
1.04
| [Fp ]
-40°C | [storage temp. ]
Flammables + water-Freezer (-20°C)e area | [solubility ]
Sol ethereal solvents; reacts with protic solvents. | [form ]
Low Melting Solid | [color ]
Clear colorless to yellow to greenish | [Specific Gravity]
0.912 | [Hydrolytic Sensitivity]
8: reacts rapidly with moisture, water, protic solvents | [Sensitive ]
Air & Moisture Sensitive | [BRN ]
3587255 | [CAS DataBase Reference]
13170-43-9(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
F+,C | [Risk Statements ]
R12:Extremely Flammable.
R14:Reacts violently with water.
R22:Harmful if swallowed.
R34:Causes burns.
R66:Repeated exposure may cause skin dryness or cracking.
R67:Vapors may cause drowsiness and dizziness. | [Safety Statements ]
S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S43:In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add-Never use water) .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 3399 4.3/PG 1
| [WGK Germany ]
1
| [F ]
10 | [TSCA ]
No | [HazardClass ]
8 | [PackingGroup ]
II | [HS Code ]
29319090 |
| Hazard Information | Back Directory | [Chemical Properties]
Grey liquid | [Uses]
Reagent used in a variety of nickel catalyzed reactions including alkenation of dithioacetals, cross-coupling with aryl triflates and carbamates, and cross-coupling with vinyl selenides. | [Uses]
Trimethylsilylmethylmagnesium
Chloride is used in the methylenation of carbonyl compounds; provides a variety of
methods to prepare allylsilanes.It participates in the reactions of Peterson Alkenation, Reaction with Carboxylic Acid Derivatives, Reaction with Alkyl Halides, Reaction with Sulfur Compounds, Reaction with Other Electrophiles, Cross-coupling Reactions, Carbometalation, and as a Generator of Alkyl Radicals from Alkyl Halides in
the Presence of Cobalt Catalysts etc. | [Preparation]
From (chloromethyl)trimethylsilane and
magnesium in an ethereal solvent. | [reaction suitability]
reaction type: Grignard Reaction |
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