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ChemicalBook--->CAS DataBase List--->130004-33-0

130004-33-0

130004-33-0 Structure

130004-33-0 Structure
IdentificationBack Directory
[Name]

(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE
[CAS]

130004-33-0
[Synonyms]

Chloro[(S)-(-)-2,2'
(S)-RuCl[(p-cymene(BINAP)Cl
[RuCl(p-cymene)((S)-binap)]Cl
S-(-)-BINAP-CHLORO(P-CYMENE)RUTHENIUM CHLORIDE
[bis(diphenylphosphino)binaphthyl]chloro(p-cumene)RuCl
(S)-RuCl[(p-cyMene(BINAP)]Cl, 11% Ru, Product of UMicore
-binaphthyl](p-cymene)ruthenium(II) chloride,[RuCl(p-cymene)((S)-binap)]Cl
(R)-(+)-2,2'-[BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]CHLORO(P-CYMENE)RUTHENIUM
(S)-(-)-2,2''-BIS(DIPHENYLPHOSPHINO)-1,1''-BINAPHTHYL]CHLORO(P-CYMENE)RUTHENIUM
[2,2'-Bis(diphenylphosphino)-1,1'-binaphthalene]chloro(p-cymene)ruthenium Chloride
(S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLO
[(R)-2,2'-BIS-(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]-CHLORO-(P-CYMENE)-RUTHENIUMCHLORIDE
[(S)-2,2'-BIS-(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]-CHLORO-(P-CYMENE)-RUTHENIUMCHLORIDE
(S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE
(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE
(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthalenechloro(p-cymene)ruthenium chloride,9
CHLORO[(S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL](P-CYMENE)RUTHENIUM (II) CHLORIDE
CHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL](P-CYMENE)RUTHENIUM (II) CHLORIDE
Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p-
(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthalenechloro(p-cymene)ruthenium chloride, ca 5% MeOH of cryst.
(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthalenechloro(p-cymene)ruthenium chloride, ca 5% MeOH of cryst., 97+%
(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthalenechloro(p-cyMene)rutheniuM chloride, 97+%, ca 5% MeOH of cryst.
Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-binap)]Cl
(RutheniuM(1+),[1,1'-(1S)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-kP]]chloro[(1,2,3,4,5,6-h)-1-Methyl-4-(1-
(RutheniuM(1+),[1,1'-(1S)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-kP]]chloro[(1,2,3,4,5,6-h)-1-Methyl-4-(1-Methylethyl)benzene]-,chloride (1:1) )
[Molecular Formula]

C54H46Cl2P2Ru
[MDL Number]

MFCD00134456
[MOL File]

130004-33-0.mol
[Molecular Weight]

928.87
Chemical PropertiesBack Directory
[Appearance]

Brown crystalline powder
[Melting point ]

>100°C
[storage temp. ]

Freezer (-20°C)
[solubility ]

Chloroform (Sparingly)
[form ]

Powder
[color ]

orange
[Sensitive ]

Air Sensitive
Hazard InformationBack Directory
[Chemical Properties]

Brown crystalline powder
[Uses]

Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26
[WGK Germany ]

3
[HS Code ]

28439000
Questions And AnswerBack Directory
[Reaction]

This catalyst has shown to effect the highly enantioselective hydrogenation of functionalized ketones where the substituents are dialkylamino, hydoxy, siloxy, carbonyl, ester, amide or thioester. Reactions of 130004-33-0
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