Identification | Back Directory | [Name]
(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE | [CAS]
130004-33-0 | [Synonyms]
Chloro[(S)-(-)-2,2' (S)-RuCl[(p-cymene(BINAP)Cl [RuCl(p-cymene)((S)-binap)]Cl S-(-)-BINAP-CHLORO(P-CYMENE)RUTHENIUM CHLORIDE [bis(diphenylphosphino)binaphthyl]chloro(p-cumene)RuCl (S)-RuCl[(p-cyMene(BINAP)]Cl, 11% Ru, Product of UMicore -binaphthyl](p-cymene)ruthenium(II) chloride,[RuCl(p-cymene)((S)-binap)]Cl (R)-(+)-2,2'-[BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]CHLORO(P-CYMENE)RUTHENIUM (S)-(-)-2,2''-BIS(DIPHENYLPHOSPHINO)-1,1''-BINAPHTHYL]CHLORO(P-CYMENE)RUTHENIUM [2,2'-Bis(diphenylphosphino)-1,1'-binaphthalene]chloro(p-cymene)ruthenium Chloride (S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLO [(R)-2,2'-BIS-(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]-CHLORO-(P-CYMENE)-RUTHENIUMCHLORIDE [(S)-2,2'-BIS-(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]-CHLORO-(P-CYMENE)-RUTHENIUMCHLORIDE (S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE (R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthalenechloro(p-cymene)ruthenium chloride,9 CHLORO[(S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL](P-CYMENE)RUTHENIUM (II) CHLORIDE CHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL](P-CYMENE)RUTHENIUM (II) CHLORIDE Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p- (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthalenechloro(p-cymene)ruthenium chloride, ca 5% MeOH of cryst. (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthalenechloro(p-cymene)ruthenium chloride, ca 5% MeOH of cryst., 97+% (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthalenechloro(p-cyMene)rutheniuM chloride, 97+%, ca 5% MeOH of cryst. Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-binap)]Cl (RutheniuM(1+),[1,1'-(1S)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-kP]]chloro[(1,2,3,4,5,6-h)-1-Methyl-4-(1- (RutheniuM(1+),[1,1'-(1S)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-kP]]chloro[(1,2,3,4,5,6-h)-1-Methyl-4-(1-Methylethyl)benzene]-,chloride (1:1) ) | [Molecular Formula]
C54H46Cl2P2Ru | [MDL Number]
MFCD00134456 | [MOL File]
130004-33-0.mol | [Molecular Weight]
928.87 |
Chemical Properties | Back Directory | [Appearance]
Brown crystalline powder | [Melting point ]
>100°C | [storage temp. ]
Freezer (-20°C) | [solubility ]
Chloroform (Sparingly) | [form ]
Powder | [color ]
orange | [Sensitive ]
Air Sensitive |
Questions And Answer | Back Directory | [Reaction]
This catalyst has shown to effect the highly enantioselective hydrogenation of functionalized ketones where the substituents are dialkylamino, hydoxy, siloxy, carbonyl, ester, amide or thioester.
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