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ChemicalBook--->CAS DataBase List--->125051-32-3

125051-32-3

125051-32-3 Structure

125051-32-3 Structure
IdentificationBack Directory
[Name]

BIS(2,6-DIFLUORO-3-(1-HYDROPYRROL-1-YL)PHENYL)TITANOCENE
[CAS]

125051-32-3
[Synonyms]

784
LS 784
PI 784
FMT,784
APi-784
YF-PI 784
)phenyl]-
HRcure-784
Easepi 784
OMNIRED 784
Irgacure 784
lencolo 5021
Photoinitiator FMT
Photoinitiator-784
photo sensitizer 784
UV Photoinitiator 784
Photoinitiator JMT-784
Bis (eta 5-2,4-cyclopentadien-1-yl)
Sinocure? 784 / Omnirad 784 / Irgacure 784
bis(cyclopentadienyl)bis(2,6-difluoro-3-(1H-pyrro
Bis(cyclopenta-1,3-diene)bis(1-(2,4-difluorophenyl
1-(2,4-Difluorophenyl)-1H-pyrrole titanium complex
Bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]titanocene
Bis(2,6-difluoro-3-(1-hydropyrro-1-yl)-phenyl)titanocene
BIS(2,6-DIFLUORO-3-(1-HYDROPYRROL-1-YL)PHENYL)TITANOCENE
Bis(2,6-difluoro-3-(1-hydropyrrol-1-yl)phenyl)titanocene 99%
Double (1-(2,4-difluorophenyl)-3-pyrrole) titanium dihydroxide
Dicyclopentadienylbis[2,6-difluoro-3-(1-pyrrolyl)phenyl]titanium
BIS(2,6-DIFLUORO-3-(1-HYDROPYRROL-1-YL)PHENYL)TITANOCENE###125051-32-3
bis(η-cyclopentadienyl)-bis(2,6-difluoro-3-[pyrrol-1-yl]-phenyl)titanium
Bis(cyclopenta-1,3-diene)bis(1-(2,4-difluorophenyl)-3H-pyrrol-3-yl)titanium
BIS(2,6-DIFLUORO-3-(1-HYDROPYRROL-1-YL)PHENYL)TITANOCENE ISO 9001:2015 REACH
titanium,bis(.eta.5-2,4-cyclopentadien-1-yl)bis[2,6-difluoro-3-(1h-pyrrol-1-yl
Bis(cyclopenta-1,3-diene)bis(1-(2,4-difluorophenyl)-3h-pyrrol-3-yl)titanium, 98
Bis(η5-2,4-cyclopentadien-1-yl)bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]titanium
Titanium, bis(h5-2,4-cyclopentadien-1-yl)bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]-
Titanium, bis(η5-2,4-cyclopentadien-1-yl)bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]-
Titanium, bis(.eta.5-2,4-cyclopentadien-1-yl)bis2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl-
Bis(.eta.5-2,4-cylcopentadien-1-yl)-bis(2,6-difluoro-3-(1H-pyrrol-1-yl)-Phenyl)titanium
Titanium, bis(hapto-5-2,4-cyclopentadien-1-yl)bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]-
[EINECS(EC#)]

412-000-1
[Molecular Formula]

C30H22F4N2Ti 10*
[MDL Number]

MFCD00274256
[MOL File]

125051-32-3.mol
[Molecular Weight]

534.37
Chemical PropertiesBack Directory
[Melting point ]

160-170°C
[density ]

1.43 at 20℃
[vapor pressure ]

0-0.001Pa at 25-50℃
[storage temp. ]

below 5° C
[form ]

Powder
[Hydrolytic Sensitivity]

4: no reaction with water under neutral conditions
[InChI]

InChI=1S/2C10H6F2N.2C5.Ti/c2*11-8-3-4-10(9(12)7-8)13-5-1-2-6-13;2*1-2-4-5-3-1;/h2*1-6H;;;/q4*-1;+4
[InChIKey]

HRVFAWAOUBYIBB-UHFFFAOYSA-N
[SMILES]

FC1=C(N2C=CC=C2)C=CC(F)=[C-]1[Ti+4]12345678([C-]9=C(C=CC(N%10C=CC=C%10)=C9F)F)(C9=C1[C-]2C3=C49)C1=C5C6=C7[C-]81
[LogP]

9.5 at 20℃
[Surface tension]

72.4mN/m at 10g/L and 20℃
[EPA Substance Registry System]

Titanium, bis(.eta.5-2,4-cyclopentadien-1-yl)bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]- (125051-32-3)
Safety DataBack Directory
[Hazard Codes ]

F,Xn,N
[Risk Statements ]

36/37/38-51/53-62-48/22-11
[Safety Statements ]

26-36/37/39-61-36/37-33-22-7
[TSCA ]

Yes
[HS Code ]

2914199090
Hazard InformationBack Directory
[Description]

Bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]titanocene, also known as Photosensitizer Irgacure 784, is an excellent photoinitiator used in a variety of holography material systems. It belongs to titanium‐complex free radical photoinitiator. As a highly active orange solid photoinitiator, Bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]titanocene has good photoactivity, thermal stability, and low toxicity. Irgacure 784 has high solubility doped in liquid methyl methacrylate (MMA) monomer, far more than the photoinitiator PQ[1-2].
[Uses]

BIS(2,6-DIFLUORO-3-(1-HYDROPYRROL-1-YL)PHENYL)TITANOCENE is a highly active orange solid photoinitiator with good photoactivity, thermal stability and low toxicity. As an active diluent, it is mainly used for UV and visible light curing of unsaturated prepolymers together with single or multi-functional vinyl monomers and oligomers.
[Hazard]

Toxic to aquatic life with long lasting effects [Hazardous to the aquatic environment, long-term hazard]; Flammable solid [Danger Flammable solids]; Suspected of damaging fertility or the unborn child [Warning Reproductive toxicity]
[References]

[1] Liu Y, et al. Volume holographic recording in Irgacure 784-doped PMMA photopolymer. Optics Express, 2017; 25: 20654-20662.
[2] Li Z, et al. Near‐Infrared‐Induced Cationic Polymerization Initiated by Using Upconverting Nanoparticles and Titanocene. Macromolecular Rapid Communications, 2019; 40: 1900047.
Spectrum DetailBack Directory
[Spectrum Detail]

BIS(2,6-DIFLUORO-3-(1-HYDROPYRROL-1-YL)PHENYL)TITANOCENE(125051-32-3)FT-IR
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