Identification | Back Directory | [Name]
BIS(2,6-DIFLUORO-3-(1-HYDROPYRROL-1-YL)PHENYL)TITANOCENE | [CAS]
125051-32-3 | [Synonyms]
784 LS 784 PI 784 FMT,784 APi-784 YF-PI 784 )phenyl]- HRcure-784 Easepi 784 OMNIRED 784 Irgacure 784 lencolo 5021 Photoinitiator FMT Photoinitiator-784 photo sensitizer 784 UV Photoinitiator 784 Photoinitiator JMT-784 Bis (eta 5-2,4-cyclopentadien-1-yl) Sinocure? 784 / Omnirad 784 / Irgacure 784 bis(cyclopentadienyl)bis(2,6-difluoro-3-(1H-pyrro Bis(cyclopenta-1,3-diene)bis(1-(2,4-difluorophenyl 1-(2,4-Difluorophenyl)-1H-pyrrole titanium complex Bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]titanocene Bis(2,6-difluoro-3-(1-hydropyrro-1-yl)-phenyl)titanocene BIS(2,6-DIFLUORO-3-(1-HYDROPYRROL-1-YL)PHENYL)TITANOCENE Bis(2,6-difluoro-3-(1-hydropyrrol-1-yl)phenyl)titanocene 99% Double (1-(2,4-difluorophenyl)-3-pyrrole) titanium dihydroxide Dicyclopentadienylbis[2,6-difluoro-3-(1-pyrrolyl)phenyl]titanium BIS(2,6-DIFLUORO-3-(1-HYDROPYRROL-1-YL)PHENYL)TITANOCENE###125051-32-3 bis(η-cyclopentadienyl)-bis(2,6-difluoro-3-[pyrrol-1-yl]-phenyl)titanium Bis(cyclopenta-1,3-diene)bis(1-(2,4-difluorophenyl)-3H-pyrrol-3-yl)titanium BIS(2,6-DIFLUORO-3-(1-HYDROPYRROL-1-YL)PHENYL)TITANOCENE ISO 9001:2015 REACH titanium,bis(.eta.5-2,4-cyclopentadien-1-yl)bis[2,6-difluoro-3-(1h-pyrrol-1-yl Bis(cyclopenta-1,3-diene)bis(1-(2,4-difluorophenyl)-3h-pyrrol-3-yl)titanium, 98 Bis(η5-2,4-cyclopentadien-1-yl)bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]titanium Titanium, bis(h5-2,4-cyclopentadien-1-yl)bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]- Titanium, bis(η5-2,4-cyclopentadien-1-yl)bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]- Titanium, bis(.eta.5-2,4-cyclopentadien-1-yl)bis2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl- Bis(.eta.5-2,4-cylcopentadien-1-yl)-bis(2,6-difluoro-3-(1H-pyrrol-1-yl)-Phenyl)titanium Titanium, bis(hapto-5-2,4-cyclopentadien-1-yl)bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]- | [EINECS(EC#)]
412-000-1 | [Molecular Formula]
C30H22F4N2Ti 10* | [MDL Number]
MFCD00274256 | [MOL File]
125051-32-3.mol | [Molecular Weight]
534.37 |
Chemical Properties | Back Directory | [Melting point ]
160-170°C | [density ]
1.43 at 20℃ | [vapor pressure ]
0-0.001Pa at 25-50℃ | [storage temp. ]
below 5° C | [form ]
Powder | [Hydrolytic Sensitivity]
4: no reaction with water under neutral conditions | [InChI]
InChI=1S/2C10H6F2N.2C5.Ti/c2*11-8-3-4-10(9(12)7-8)13-5-1-2-6-13;2*1-2-4-5-3-1;/h2*1-6H;;;/q4*-1;+4 | [InChIKey]
HRVFAWAOUBYIBB-UHFFFAOYSA-N | [SMILES]
FC1=C(N2C=CC=C2)C=CC(F)=[C-]1[Ti+4]12345678([C-]9=C(C=CC(N%10C=CC=C%10)=C9F)F)(C9=C1[C-]2C3=C49)C1=C5C6=C7[C-]81 | [LogP]
9.5 at 20℃ | [Surface tension]
72.4mN/m at 10g/L and 20℃ | [EPA Substance Registry System]
Titanium, bis(.eta.5-2,4-cyclopentadien-1-yl)bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]- (125051-32-3) |
Hazard Information | Back Directory | [Description]
Bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]titanocene, also known as Photosensitizer Irgacure 784, is an excellent photoinitiator used in a variety of holography material systems. It belongs to titanium‐complex free radical photoinitiator. As a highly active orange solid photoinitiator, Bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]titanocene has good photoactivity, thermal stability, and low toxicity. Irgacure 784 has high solubility doped in liquid methyl methacrylate (MMA) monomer, far more than the photoinitiator PQ[1-2].
| [Uses]
BIS(2,6-DIFLUORO-3-(1-HYDROPYRROL-1-YL)PHENYL)TITANOCENE is a highly active orange solid photoinitiator with good photoactivity, thermal stability and low toxicity. As an active diluent, it is mainly used for UV and visible light curing of unsaturated prepolymers together with single or multi-functional vinyl monomers and oligomers. | [Hazard]
Toxic to aquatic life with long lasting effects [Hazardous to the aquatic environment, long-term hazard]; Flammable solid [Danger Flammable solids]; Suspected of damaging fertility or the unborn child [Warning Reproductive toxicity] | [References]
[1] Liu Y, et al. Volume holographic recording in Irgacure 784-doped PMMA photopolymer. Optics Express, 2017; 25: 20654-20662. [2] Li Z, et al. Near‐Infrared‐Induced Cationic Polymerization Initiated by Using Upconverting Nanoparticles and Titanocene. Macromolecular Rapid Communications, 2019; 40: 1900047.
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