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ChemicalBook--->CAS DataBase List--->118-12-7

118-12-7

118-12-7 Structure

118-12-7 Structure
IdentificationMore
[Name]

1,3,3-Trimethyl-2-methyleneindoline
[CAS]

118-12-7
[Synonyms]

1,3,3-TRIMETHYL-2-METHYLENEINDOINE
1,3,3-TRIMETHYL-2-METHYLENE INDOLENINE
1,3,3'-TRIMETHYL-2-METHYLENEINDOLINE
1,3,3-TRIMETHYL-2-METHYLENEINDOLINE
2-METHYLENE-1,3,3-TRIMETHYLINDOLINE
FISCHER BASE
FISCHERS BASE
FISCHER'S BASE
1,3,3-trimethyl-2-methylene-indolin
1,3-Dihydro-1,3,3-trimethyl-2-methyleneindoline
2,3-dihydro-1,3,3-trimethyl-2-methylene-1h-indol
2,3-dihydro-1,3,3-trimethyl-2-methylene-1H-Indole
2,3-Dihydro-1,3,3-trimethyl-2-methyleneindoline
2-methylene-1,3,3-trimethyl-indolin
fischer’smethylenebase
Fischer'S methylene base
Indoline, 1,3,3-trimethyl-2-methylene-
Indoline, 2-methylene-1,3,3-trimethyl-
1,3,3-TRIMETHYL-2-METHYLENEINDOLINE, FOR PAPER CHROMATOGR.
1,3,3-Trimethyl-2-Methyleneindole
[EINECS(EC#)]

204-235-1
[Molecular Formula]

C12H15N
[MDL Number]

MFCD00005813
[Molecular Weight]

173.25
[MOL File]

118-12-7.mol
Chemical PropertiesBack Directory
[Appearance]

clear red liquid
[Melting point ]

-8 °C
[Boiling point ]

248 °C (lit.)
[density ]

0.979 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.577(lit.)
[Fp ]

215 °F
[storage temp. ]

Store below +30°C.
[solubility ]

negligible
[form ]

liquid
[pka]

2.19±0.40(Predicted)
[color ]

red
[Specific Gravity]

0.98
[Water Solubility ]

negligible
[BRN ]

131162
[CAS DataBase Reference]

118-12-7(CAS DataBase Reference)
[NIST Chemistry Reference]

1H-Indole, 2,3-dihydro-1,3,3-trimethyl-2-methylene-(118-12-7)
[EPA Substance Registry System]

118-12-7(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xn,N
[Risk Statements ]

R22:Harmful if swallowed.
R38:Irritating to the skin.
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
[Safety Statements ]

S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S57:Use appropriate container to avoid environmental contamination .
S37:Wear suitable gloves .
[RIDADR ]

UN 3082 9/PG 3
[WGK Germany ]

2
[RTECS ]

NM1926500
[F ]

23
[TSCA ]

Yes
[HazardClass ]

9
[PackingGroup ]

III
[HS Code ]

29339990
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Sodium carbonate-->Dimethyl sulfate-->p-Toluenesulfonic acid-->Aniline-->2-Butanone-->Sodium metabisulfite-->Phenylhydrazine-->Indole-->Dimethyl phthalate-->Methyl p-toluenesulfonate-->Phenylhydrazine sulfate-->Acetonitrile, (1,3-dihydro-1,3,3-trimethyl-2H-indol-2-ylidene)--->3H-Indolium, 1,2,3,3-tetramethyl--->2,3,3-Trimethylindolenine-->1-Methylindole
[Preparation Products]

ASTRAZON PINK FG-->2-[2-[4-[(4-ethoxyphenyl)methylamino]phenyl]vinyl]-5-(methoxycarbonyl)-1,3,3-trimethyl-3H-indolium chloride-->Catonic Orange G-->ASTRAZON PINK FG-->ASTRAZON ORANGE R
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

1,3,3-Trimethyl-2-methyleneindoline(118-12-7).msds
Hazard InformationBack Directory
[Chemical Properties]

clear red liquid
[Uses]

Reactant for:
  • Cycloaddition reactions
  • Preparation of red photochromic dyes
  • Synthesis of photochromic homopolymers via ring-opening metathesis polymerization
Spectrum DetailBack Directory
[Spectrum Detail]

1,3,3-Trimethyl-2-methyleneindoline(118-12-7)MS
1,3,3-Trimethyl-2-methyleneindoline(118-12-7)1HNMR
1,3,3-Trimethyl-2-methyleneindoline(118-12-7)13CNMR
1,3,3-Trimethyl-2-methyleneindoline(118-12-7)IR1
1,3,3-Trimethyl-2-methyleneindoline(118-12-7)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

1,3,3-Trimethyl-2-methyleneindoline, 98.50%(118-12-7)
[Alfa Aesar]

1,3,3-Trimethyl-2-methyleneindoline, 95%(118-12-7)
[Sigma Aldrich]

118-12-7(sigmaaldrich)
[TCI AMERICA]

1,3,3-Trimethyl-2-methyleneindoline,>95.0%(GC)(118-12-7)
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