| Identification | Back Directory | [Name]
METOLCARB | [CAS]
1129-41-5 | [Synonyms]
MTMC
s1065
Kumiai
drc3341
Dicresyl
DRC 3341
Tumacide
METACRATE
tsumaunka
METOLCARB
NSC 91193
OFUNACK M
TSUMACIDE
ai3-27694
Metholcarb
mtmc (jmaf)
METACRATE(R)
Metolcarb 10
TsuMacide solution
Metolcarb W.P.(25%)
metolcarb (bsi,iso)
Metholcarb E.C.(20%)
METOLCARB PESTANAL
m-cresylmethylcarbamate
M-TOLYL METHYLCARBAMATE
3-Tolyl methylcarbamate
m-Cresyl methylcarbamate
m-toly-n-methylcarbamate
META-TOLYLMETHYLCARBAMATE
dicresyln-methylcarbamate
3-Tolyl N-methylcarbamate
3-tolyl-n-methylcarbamate
m-Tolyl-N-methylcarbamate
Dicresyl N-methylcarbamate
m-Cresyl N-methylcarbamate
m-Tolyl-N-methoxycarbamate
Metolcarb 500mg [1129-41-5]
m-methylphenylmethylcarbamate
3-methylphenylmethylcarbamate
3-Methylphenyl Methylcarbamate
methyl-carbamicaci3-tolylester
methylcarbamicacidm-tolylester
methyl-carbamicacim-tolylester
m-Methylphenyl methylcarbamate
3-methylphenyln-methylcarbamate
3-Methylphenyl N-methylcarbamate
3-Methylphenyl-N-methylcarbamate
Methylcarbamic acid m-tolyl ester
ETHYL ACETATE SPECTRANAL REAG. ACS
N-Methylcarbamic acid 3-methylphenyl
m-tolylesterkyselinymethylkarbaminove
methyl-carbamicaci3-methylphenylester
Carbamic acid, methyl-, 3-tolyl ester
Carbamic acid, methyl-, m-tolyl ester
m-Cresyl ester of N-methylcarbamic acid
m-Tolylester kyseliny methylkarbaminove
Carbamicacid,methyl-,3-methylphenylester
Carbamic acid, methyl-, 3-methylphenyl ester
m-tolylesterkyselinymethylkarbaminove(czech)
metolcarb (ISO) m-tolyl methylcarbamate MTMC
N-methylcarbamic acid (3-methylphenyl) ester
Metolcarb: (Methylcarbamic acid m-tolyl ester) | [EINECS(EC#)]
214-446-0 | [Molecular Formula]
C9H11NO2 | [MDL Number]
MFCD00053076 | [MOL File]
1129-41-5.mol | [Molecular Weight]
165.19 |
| Chemical Properties | Back Directory | [Appearance]
Metolcarb is a colorless crystalline
solid. | [Melting point ]
74-77 °C | [Boiling point ]
293.03°C (rough estimate) | [density ]
1.1603 (rough estimate) | [vapor pressure ]
0.145 Pa (20 °C) | [refractive index ]
1.5270 (estimate) | [Fp ]
>100 °C | [storage temp. ]
0-6°C | [solubility ]
Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly) | [form ]
Solid | [pka]
12.38±0.46(Predicted) | [Water Solubility ]
2600 mg l-1 (30 °C) | [color ]
White to Off-White | [CAS DataBase Reference]
1129-41-5 | [EPA Substance Registry System]
Metolcarb (1129-41-5) |
| Safety Data | Back Directory | [Hazard Codes ]
Xn,N | [Risk Statements ]
22-51/53 | [Safety Statements ]
61-60 | [RIDADR ]
2757 | [RTECS ]
FC8050000 | [HazardClass ]
6.1(b) | [PackingGroup ]
III | [Safety Profile]
Poison by ingestion and
skin contact. Moderately toxic by inhalation.
Mutation data reported. When heated to
decomposition it emits toxic fumes of NOx.
See also CARBAMATES. | [Hazardous Substances Data]
1129-41-5(Hazardous Substances Data) |
| Hazard Information | Back Directory | [General Description]
Colorless crystalline solid. METOLCARB is an insecticide for the control of rice leafhoppers, planthoppers, codling moth, citrus mealybug, onion thrips, fruit flies, bollworms and aphids. Not registered as a pesticide in the U.S. | [Air & Water Reactions]
Soluble in water. | [Reactivity Profile]
METOLCARB is a carbamate ester. Carbamates are chemically similar to, but more reactive than amides. Like amides they form polymers such as polyurethane resins. Carbamates are incompatible with strong acids and bases, and especially incompatible with strong reducing agents such as hydrides. Flammable gaseous hydrogen is produced by the combination of active metals or nitrides with carbamates. Strongly oxidizing acids, peroxides, and hydroperoxides are incompatible with carbamates. | [Health Hazard]
High oral and skin toxicity, and moderate inhalation toxicity. (Non-Specific -- Carbamates) Some carbamates appear to be carcinogenic, teratogenic, and/or mutagenic. Carbamates are cholinesterase inhibitors. | [Fire Hazard]
As for other solid carbamate pesticides, container may explode in heat of fire. Fire and runoff from fire control water may produce irritating or poisonous gases. Emits toxic fumes of nitrogen oxides when heated to decomposition. Avoid decomposing heat. | [Potential Exposure]
Metolcarb is an insecticide used for
the control of rice leafhoppers, plant-hoppers; codling
moth; citrus mealy bug; onion thrips; fruit flies; bollworms
and aphids. Not registered as a pesticide in the United
States. | [First aid]
If this chemical gets into the eyes, remove any
contact lenses at once and irrigate immediately for at
least 15 minutes, occasionally lifting upper and lower lids.
Seek medical attention immediately. If this chemical contacts
the skin, remove contaminated clothing and wash
immediately with soap and water. Speed in removing material
from skin is of extreme importance. Shampoo hair
promptly if contaminated. Seek medical attention immediately.
If this chemical has been inhaled, remove from exposure,
begin rescue breathing (using universal precautions,
including resuscitation mask) if breathing has stopped and
CPR if heart action has stopped. Transfer promptly to a
medical facility. When this chemical has been swallowed,
get medical attention. Give large quantities of water and
induce vomiting. Do not make an unconscious person
vomit. Keep victim quiet and maintain normal body temperature.
Carefully observe victim since effects may be
delayed. | [Shipping]
UN2757 Carbamate pesticides, solid, toxic,
Hazard Class: 6.1; Labels: 6.1-Poisonous materials.
UN3077 Environmentally hazardous substances, solid, n.o.s.,
Hazard class: 9; Labels: 9-Miscellaneous hazardous material,
Technical Name Required. | [Incompatibilities]
Carbamates are incompatible with reducing
agents such as hydrides, strong acids, oxidizing acids,
peroxides, and bases. Contact with active metals or nitrides
cause the release of flammable, and potentially explosive,
hydrogen gas. May react violently with bromine, ketones.
Incompatible with azo dyes, caustics, ammonia, amines,
boranes, hydrazines, strong oxidizers. | [Description]
Metolcarb (17), m-tolyl methylcarbamate
(IUPAC), C9H11NO2, MW 165.2, mp 76–77 ?C, is a colorless
solid that is moderately soluble in water and is readily
soluble in polar organic solvents. | [Chemical Properties]
Metolcarb is a colorless crystalline
solid. | [Waste Disposal]
Consult with environmental
regulatory agencies for guidance on acceptable disposal
practices. Generators of waste containing this contaminant
(≥100 kg/mo) must conform to EPA regulations
governing storage, transportation, treatment, and waste
disposal. In accordance with 40CFR165, follow recommendations
for the disposal of pesticides and pesticide
containers. Must be disposed properly by following package
label directions or by contacting your local or federal
environmental control agency, or by contacting your
regional EPA office. | [Uses]
Metolcarb is used to control planthoppers, leafhoppers and other
sucking pests on rice. It is also used for control of citrus mealybugs, onion
thrips, Mediterranean fruit flies, pink bollworms and cotton aphids. | [Definition]
ChEBI: Metolcarb is a carbamate ester. It has a role as an EC 3.1.1.7 (acetylcholinesterase) inhibitor, a carbamate insecticide, an acaricide and an agrochemical. It is functionally related to a methylcarbamic acid and a m-cresol. | [Preparation]
Metolcarb is produced by the reaction between 3-
methylphenol and Metolcarb. | [Agricultural Uses]
Insecticide, Acaricide: Metolcarb is an insecticide for the control of rice
green leafhoppers, plant-hoppers, codling moth, citrus
mealy bug, onion thrips, fruit flies, bollworms and aphids.
Not registered for use in the U.S. Not listed for use in EU
countries. | [Trade name]
DRC 3341®; KUMIAI®; METACRATE®;
S 1065®; SOGATOX DUST® 22; TSUMACIDE®;
TSUMAUNKA®; VADEN® | [Metabolic pathway]
The main pathways of metabolism of metolcarb in plants, mammals and
insects involve ring-methyl, N-methyl and phenyl-ring hydroxylation
and conjugation. Carbamate ester hydrolysis is a minor reaction. Further
oxidation of a ring-hydroxymethyl moiety to carboxyl occurs in rats and
insects. | [storage]
Color Code—Blue: Health Hazard/Poison: Storein a secure poison location. Prior to working with thischemical you should be trained on its proper handling andstorage. Store in tightly closed containers in a cool, wellventilated area away from oxidizers. Where possible, automatically pump liquid from drums or other storage containers to process containers |
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| Company Name: |
Spectrum Chemical Manufacturing Corp.
|
| Tel: |
021-021-021-67601398-809-809-809 15221380277 |
| Website: |
www.spectrumchemical.com/oa_html/index.jsp?minisite=10020&respid=22372&language=us |
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