| Identification | More | [Name]
Hexylamine | [CAS]
111-26-2 | [Synonyms]
1-Amine-n-hexane
1-AMINOHEXANE
1-HEXYLAMINE
AMINE C6
ETHYL-N-BUTYLAMINE
HEXYLAMINE
MONO-N-HEXYLAMINE
N-HEXYLAMINE
RARECHEM AL BW 0240
1-Aminohexan
1-Aminohexane,1-Hexanamine
1-Hexanamin
1-Hexanamine
ent16554
Hexylamin
hexylamine,[liquid]
n-C6H13NH2
NORMAL HEXYL AMINE
aminohexane
n-Hexylamin | [EINECS(EC#)]
203-851-8 | [Molecular Formula]
C6H15N | [MDL Number]
MFCD00008240 | [Molecular Weight]
101.19 | [MOL File]
111-26-2.mol |
| Chemical Properties | Back Directory | [Appearance]
colourless liquid | [Melting point ]
−23 °C(lit.)
| [Boiling point ]
131-132 °C(lit.)
| [density ]
0.766 g/mL at 25 °C(lit.)
| [vapor pressure ]
10.6 hPa (20 °C) | [FEMA ]
4243 | [refractive index ]
n20/D 1.418(lit.)
| [Fp ]
27 °C
| [storage temp. ]
Flammables area | [solubility ]
14g/l | [form ]
Liquid | [pka]
10.56(at 25℃) | [color ]
Clear colorless to slightly yellow | [Odor]
at 0.10 % in propylene glycol. ammoniacal musty fishy | [PH]
11.6 (10g/l, H2O, 20℃) | [Stability:]
Stable. Incompatible with acids, acid anhydrides, acid chlorides, carbon dioxide, strong oxidizing agents. | [explosive limit]
2.1-9.3%(V) | [Odor Type]
fishy | [Water Solubility ]
14 g/L (20 ºC) | [Sensitive ]
Air Sensitive | [JECFA Number]
1588 | [BRN ]
1731298 | [Dielectric constant]
4.0800000000000001 | [InChIKey]
BMVXCPBXGZKUPN-UHFFFAOYSA-N | [LogP]
2.06-2.31 at 25℃ | [Uses]
Toxic by ingestion, inhalation, and skin
absorption. Flammable, moderate fire risk. | [CAS DataBase Reference]
111-26-2(CAS DataBase Reference) | [NIST Chemistry Reference]
1-Hexanamine(111-26-2) | [EPA Substance Registry System]
111-26-2(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
C,F,Xi | [Risk Statements ]
R10:Flammable.
R21/22:Harmful in contact with skin and if swallowed .
R35:Causes severe burns.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S16:Keep away from sources of ignition-No smoking . | [RIDADR ]
UN 2734 8/PG 1
| [WGK Germany ]
1
| [RTECS ]
MQ4540000
| [F ]
34 | [Autoignition Temperature]
270 °C | [Hazard Note ]
Irritant/Flammable/Corrosive/Air Sensitive | [TSCA ]
Yes | [HazardClass ]
8 | [PackingGroup ]
II | [HS Code ]
29159020 | [HS Code ]
29211980 | [Hazardous Substances Data]
111-26-2(Hazardous Substances Data) | [Toxicity]
LD50 orally in Rabbit: 240 mg/kg |
| Raw materials And Preparation Products | Back Directory | [Raw materials]
Phosphorus pentachloride-->Hexanamide, N-hexyl--->DI-N-HEXYLAMINE-->1H-Isoindole-1,3(2H)-dione, 2-hexyl--->TRI-N-HEXYLAMINE-->1,2-Benzenedimethanol | [Preparation Products]
6-N-HEXYLAMINOPURINE-->Hexyl isocyanate-->5-PyriMidinecarboxylic acid, 4-[1,1'-biphenyl]-4-yl-1-[6-[[2-(butylaMino)-1-[3-(Methoxycarbonyl)-4-(2-Methoxy-2-oxoethoxy)phenyl]-2-oxoethyl]hexylaMino]-6-oxohexyl]-1,2,3,4-tetrahydro-6-Methyl-2-oxo-, phenylMethyl ester-->Triethyl 1,3,5-benzenetricarboxylate-->HEXANAMIDE-->N-METHYLHEXYLAMINE-->N,N-DIMETHYLHEXYLAMINE-->2-BROMOBENZO[B]THIOPHENE-->3-(HEXYLAMINO)PROPIONITRILE |
| Hazard Information | Back Directory | [General Description]
A water-white liquid with an amine-like odor. Flash point 85°F. Boiling point 132°F. Less dense than water and poorly soluble in swater. Hence floats on water. May be toxic by inhalation, ingestion or skin absorption. | [Reactivity Profile]
HEXYLAMINE neutralize acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides. | [Air & Water Reactions]
Highly flammable. Slightly soluble in water. | [Health Hazard]
Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution. | [Chemical Properties]
Colorless to yellow liquid; fishy aroma.
| [Chemical Properties]
colourless liquid | [Chemical Properties]
n-Hexylamine is a colorless, flammable liquid, slightly soluble in water
and soluble in alcohol and ether. | [Definition]
ChEBI: A 6-carbon primary aliphatic amine. | [Aroma threshold values]
High strength odor; fishy type, recommend smelling in a 0.10% solution or less | [Synthesis Reference(s)]
The Journal of Organic Chemistry, 55, p. 2271, 1990 DOI: 10.1021/jo00295a002
Synthesis, p. 605, 1981 | [Flammability and Explosibility]
Flammable | [Purification Methods]
Dry with, and fractionally distil the hexylamine from, KOH or CaH2. Store away from CO2. [Beilstein 4 IV 709.] |
|
|