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ChemicalBook--->CAS DataBase List--->1070663-78-3

1070663-78-3

1070663-78-3 Structure

1070663-78-3 Structure
IdentificationBack Directory
[Name]

2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos
[CAS]

1070663-78-3
[Synonyms]

BrettPhos 96%
2-(Dicyclohexylphosphino)-3,6-diMethoxy-2'-4'-6'-tri-i-propyl-1,1'
2-Dicyclohexylphosphino-2',4',6'-triisopropyl-3,6-dimethoxybiphenyl
2-Dicyclohexylphosphino-2',4',6'-triisopropyl-3,6-diMethoxybiphenyl, 97+%
2-(Dicyclohexylphosphino)3,6-dimethoxy-2′,4′,6′-triisopropyl-1,1′-biphenyl
2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-bipheny
2-(Dicyclohexyl phosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenly
dicyclohexyl-[3,6-dimethoxy-2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane
2-(Dicyclohexylphosphino)-3,6-diMethoxy-2'-4' -6'-tri-i-propyl-1,1'-biphenyl
Dicyclohexyl(2',4',6'-triisopropyl-3,6-diMethoxy-[1,1'-biphenyl]-2-yl)phosphine
dicyclohexyl[3,6-dimethoxy-2',4',6'-tris(propan-2-yl)-[1,1'-biphenyl]-2-yl]phosphane
Dicyclohexyl[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine
2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl(BrettPhos)
2-Dicyclohexylphosphino-2',4',6'-tri-i-propyl-3,6-dimethoxy-1,1'-biphenyl, (BrettPhos)
2-Dicyclohexylphosphino-2',4',6'-tri-i-propyl-3,6-diMethoxy-1,1'-biphenyl, 98% (BrettPhos)
2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos
[Molecular Formula]

C35H53O2P
[MDL Number]

MFCD11973797
[MOL File]

1070663-78-3.mol
[Molecular Weight]

536.768
Chemical PropertiesBack Directory
[Melting point ]

191-193℃
[Boiling point ]

607.7±55.0 °C(Predicted)
[storage temp. ]

Refrigerator, under inert atmosphere
[solubility ]

Chloroform (Slightly), Methanol (Slightly, Sonicated)
[form ]

crystal
[color ]

white
[InChIKey]

WDVGNXKCFBOKDF-UHFFFAOYSA-N
[SMILES]

P(C1CCCCC1)(C1CCCCC1)C1=C(OC)C=CC(OC)=C1C1=C(C(C)C)C=C(C(C)C)C=C1C(C)C
Hazard InformationBack Directory
[Uses]

Ligand for the Suziki-Miyaura coupling of tosylates and mesylates.
Safety DataBack Directory
[Risk Statements ]

36/37/38
[Safety Statements ]

26-37-60
[WGK Germany ]

nwg
[TSCA ]

No
[HS Code ]

2931499090
Questions And AnswerBack Directory
[Reactions]

  1. Ligand for palladium-catalyzed cross-coupling reactions using aryl mesylates with electron-deficient anilines.
  2. Ligand for palladium-catalyzed cross-coupling of primary arylamines at low catalyst loading.
  3. Ligand for palladium-catalyzed cross-coupling of aryl iodides and primary amines.
  4. Ligand for the Suziki-Miyaura coupling of tosylates and mesylates.
  5. Ligand for the palladium-catalyzed trifluoromethylation of aryl chlorides.
  6. Ligand for the palladium-catalyzed formation of aryl-SCF3 compounds from aryl bromides.
  7. Ligand for the nickel-catalyzed cross-coupling of styrenyl epoxides with boronic acids.
  8. Ligand for the palladium-catalyzed intramolecular CH difluoroalkylation.
Reactions of 1070663-78-3_1
Reactions of 1070663-78-3_2
Spectrum DetailBack Directory
[Spectrum Detail]

2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos(1070663-78-3)1HNMR
2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos(1070663-78-3)31PNMR
2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos(1070663-78-3)FT-IR
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