Identification | Back Directory | [Name]
(2R)-(-)-GLYCIDYL 4-NITROBENZOATE | [CAS]
106268-95-5 | [Synonyms]
GLYCIDYL4-NITROBENZOATE (R)-(-)-GLYCIDYL-4-NITROBENZOATE (2R)-(-)-GLYCIDYL 4-NITROBENZOATE 4-nitrobenzoate,(r)-oxiranemethano (R)-(-)-Oxirane-2-methanol 4-nitrobenzoate (2r)-(-)-(2,3-epoxypropylester)-4-nitrobenzoate (R)-(-)-Glycidyl 4-nitrobenzoate, (R)-(-)-Oxirane-2-methanol 4-nitrobenzoate | [Molecular Formula]
C10H9NO5 | [MDL Number]
MFCD00010835 | [MOL File]
106268-95-5.mol | [Molecular Weight]
223.18 |
Hazard Information | Back Directory | [Purification Methods]
Purify glycidol by fractional distillation.The 4-nitrobenzoates have m 56o (±); m 60-62o, [] D20 -37.9o (c 3.38 CHCl3) for R-(-)-isomer [106268-95-5];m 60-62o, [] D20 +38o (c 1 CHCl3) for the S-(+)-isomer [115459-65-9] and are recrystallised from Et2O or Et2O/pet ether (b 40-60o) [S-isomer: Burgos et al. J Org Chem 52 4973 1987, Sowden & Fischer J Am Chem Soc 64 1291 1942.] [Beilstein 17 I 50, 17 III/IV 985, 17/3 V 9.] |
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