Identification | More | [Name]
(R)-(-)-ALPHA-(TRIFLUOROMETHYL)BENZYL ALCOHOL | [CAS]
10531-50-7 | [Synonyms]
(-)-PHENYL(TRIFLUOROMETHYL)CARBINOL (1R)-1-Phenyl-2,2,2-trifluoroethanol (αR)-α-(Trifluoromethyl)benzenemethanol (R)-(-)-1-PHENYL-2,2,2-TRIFLUOROETHANOL (R)-(-)-2,2,2-TRIFLUORO-1-PHENYLETHANOL (r)-(-)-α-(trifluoromethyl)benzyl alcohol (R)-(-)-α-(Trifluoromethyl)benzyl Alcohol (R)-1-Phenyl-2,2,2-trifluoroethanol, 90% ee (R)-2,2,2-Trifluoro-1-phenylethanol,99%e.e. Benzenemethanol, a-(trifluoromethyl)-, (aR)- Benzenemethanol, α-(trifluoromethyl)-, (αR)- (R)-(-)-ALPHA-(TRIFLUOROMETHYL)BENZYL ALCOHOL (R)-(-) -ALPHA-(TRIFLUOROMETHYL)BENZYL ALCOHOL 98+% (R)-(-)-ALPHA-(TRIFLUOROMETHYL)BENZYL AL COHOL, 99% (97% EE/GLC) (-)-Phenyl(trifluoromethyl)carbinol, (R)-(-)-1-Phenyl-2,2,2-trifluoroethanol | [EINECS(EC#)]
234-094-1 | [Molecular Formula]
C8H7F3O | [MDL Number]
MFCD00077844 | [Molecular Weight]
176.14 | [MOL File]
10531-50-7.mol |
Chemical Properties | Back Directory | [Melting point ]
20 °C(lit.) | [Boiling point ]
73-76 °C9 mm Hg(lit.) | [density ]
1.300 g/mL at 20 °C(lit.)
| [refractive index ]
n20/D 1.459(lit.)
| [Fp ]
189 °F
| [storage temp. ]
Keep in dark place,Inert atmosphere,Room temperature | [form ]
clear liquid | [pka]
11.91±0.10(Predicted) | [color ]
Colorless to Almost colorless | [CAS DataBase Reference]
10531-50-7(CAS DataBase Reference) |
Safety Data | Back Directory | [Hazard Codes ]
Xi,C | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36:Wear suitable protective clothing . | [RIDADR ]
NA 1993 / PGIII | [WGK Germany ]
3
| [F ]
10-23 | [HS Code ]
29062990 |
Hazard Information | Back Directory | [Uses]
(R)?-?2,?2,?2-?Trifluoro-?1-?phenylethanol is a building block used in the synthesis of mesoporous metal-organic frameworks. | [Purification Methods]
Purify the chiral alcohols by fractional distillation preferably in a vacuum. [Morrison & Ridgeway Tetrahedron Lett 573 1969, NMR: Pirkle & Beare J Am Chem Soc 90 6250 1968.] The racemate [340-05-6] has b 52-54o/2mm,57-59o/2mm, 64-65o/5mm, d 4 20 1.293, n D 20 1.457, and the 2-carbobenzoyl derivative has m 137-138o [Mosher et al. J Am Chem Soc 78 4374 1956]. [Beilstein 6 IV 3043.] |
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Company Name: |
Energy Chemical
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021-021-58432009 400-005-6266 |
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http://www.energy-chemical.com |
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