Identification | More | [Name]
YTTERBIUM CHLORIDE | [CAS]
10361-91-8 | [Synonyms]
YTTERBIUM CHLORIDE YTTERBIUM(III) CHLORIDE YbCl3 Yiterbium chloride Ytterbium chloride (YbCl3) ytterbiumchloride(ybcl3) ytterbiumtrichloride YtterbiumchlorideanhydrousREOwhitepowder Ytterbium (III) chloride, anhydrous YTTERBIUM(III) CHLORIDE, ANHYDROUS, BEAD S,-10 MESH, 99.99% YTTERBIUM(III) CHLORIDE, ANHYDROUS, POW-DER, 99.9% Ytterbium(Iii)Chloride,Anhydrous,99.9% Ytterbium(III) chloride, anhydrous, 99.90% Ytterbium(III)chloride,anhydrous(99.9%-Yb)(REO) ytterbium(iii) chloride, ultra dry YTTERBIUM(III) CHLORIDE, ANHYDROUS: 99.9% (REO) Ytterbium Chloride Anhydrous Ytterbium(III) chloride, ultra dry, 99.99% (REO) Ytterbium(III) chloride, 35% min w/w aq. soln., 99.9% (REO) Ytterbium(iii) chloride, 99.90%, anhydrous | [EINECS(EC#)]
233-800-5 | [Molecular Formula]
Cl3Yb | [MDL Number]
MFCD00011288 | [Molecular Weight]
279.4 | [MOL File]
10361-91-8.mol |
Chemical Properties | Back Directory | [Appearance]
white powder | [Melting point ]
875 °C(lit.) | [density ]
1.48^3^0 | [storage temp. ]
Inert atmosphere,Room Temperature | [solubility ]
soluble in H2O | [form ]
powder
| [color ]
Off-white | [Water Solubility ]
Soluble in water. | [Crystal Structure]
AlCl3 type | [Sensitive ]
Hygroscopic | [crystal system]
Monoclinic | [Merck ]
14,10105 | [Space group]
C2/m | [Lattice constant]
a/nm | b/nm | c/nm | α/o | β/o | γ/o | V/nm3 | 0.673 | 1.165 | 0.638 | 90 | 110.4 | 90 | 0.468 |
| [Stability:]
hygroscopic | [CAS DataBase Reference]
10361-91-8(CAS DataBase Reference) | [EPA Substance Registry System]
Ytterbium chloride (YbCl3) (10361-91-8) |
Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36:Wear suitable protective clothing . | [WGK Germany ]
2
| [RTECS ]
ZG2100000
| [TSCA ]
Yes | [HS Code ]
28273985 | [Safety Profile]
Poison by
intraperitoneal route. Mtldly toxic by
ingestion. An experimental teratogen. A skin
and eye irritant. When heated to
SYN: YTTERBIUM TRICHLORIDE
decomposition it emits toxic fumes of Cl-.
See also YITERBIUM, RARE EARTHS,
and CHLORIDES. |
Hazard Information | Back Directory | [Chemical Properties]
Ytterbium(III) chloride (YbCl3) is a white powdery monoclinic crystals. It reacts with NiCl2 to form a very effective catalyst for the reductive dehalogenation of aryl halides. It is used in catalysis and as a NMR shift reagent in biology. It can also be used to track the digestion process in all animals. Ytterbium(III) Chloride is a typical starting material for the production of Yb metal. It is also used a a source of Yb3+ ion for doping into laser host materials. | [Uses]
Used as laboratory reagent, optical glasses, structural ceramics, catalysts, electrical components and photo-optical material. Applied with NiCl2 to form a very effective catalyst for the reductive dehalogenation of aryl halides. Ytterbium(III) chloride is a powerful catalyst for the formation of acetals using trimethyl orthoformate and also used to track digestion in animals. | [Definition]
ChEBI: Ytterbium(III) chloride is the trichloride salt of ytterbium(III). It has a role as a NMR shift reagent. It contains a ytterbium(3+). | [Preparation]
Anhydrous ytterbium(III) chloride can be produced by the ammonium chloride route. In the first step, ytterbium oxide is heated with ammonium chloride to produce the ammonium salt of the pentachloride: Yb2O3 + 10NH4Cl → 2(NH4)2YbCl5 + 6H2O + 6NH3 In the second step, the ammonium chloride salt is converted to the trichlorides by heating in a vacuum at 350-400°C: (NH4)2YbCl5 → YbCl3 + 2HCl + 2NH3 | [reaction suitability]
reagent type: catalyst core: ytterbium |
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