Identification | More | [Name]
P-TOLYL DISULFIDE | [CAS]
103-19-5 | [Synonyms]
4-TOLYL DISULFIDE CRESYL DISULFIDE DICRESYL DISULFIDE DI-P-TOLYL DISULFIDE P-TOLYL DISULFIDE 1-Methyl-4-[(4-methylphenyl)disulfanyl]benzene 4,4’-dimethyldiphenyldisulphide 4-Methylphenyl disulfide 4-methylphenyldisulfide Biodylon Bis(4-methylphenyl) disulfide bis(4-methylphenyl)disulfide Bis(4-tolyl) disulfide bis(4-tolyl)disulfide bis(p-methylphenyl)disulfide Bis(p-tolyl) disulfide bis(p-tolyl)disulfide Di(4-methylphenyl)disulfide Di-4-tolyl disulfide di-4-tolyldisulfide | [EINECS(EC#)]
203-087-5 | [Molecular Formula]
C14H14S2 | [MDL Number]
MFCD00008547 | [Molecular Weight]
246.39 | [MOL File]
103-19-5.mol |
Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S37/39:Wear suitable gloves and eye/face protection . | [RIDADR ]
UN 3335 | [WGK Germany ]
3
| [RTECS ]
JO1526250
| [TSCA ]
T | [HS Code ]
29309090 |
Hazard Information | Back Directory | [Chemical Properties]
COLORLESS TO LIGHT YELLOW CRYSTALLINE SOLID | [Uses]
4-Methylphenyl Disulfide can be useful in electrochemical regioselective C(sp2)-H selenylation and sulfenylation of substituted 2-amino-1,4-naphthoquinones. | [Synthesis Reference(s)]
The Journal of Organic Chemistry, 46, p. 2408, 1981 DOI: 10.1021/jo00324a046 Tetrahedron Letters, 34, p. 903, 1993 DOI: 10.1016/S0040-4039(00)77450-8 | [Purification Methods]
Purify it by chromatography on alumina using hexane as eluent, then crystallise it from MeOH, and/or distil it in a vacuum. [Kice & Bowers J Am Chem Soc 84 2384 1962, Beilstein 6 H 245, 6 I 212, 6 II 400, 6 III 1432, 6 IV 3206.] |
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