Identification | More | [Name]
(S)-(-)-3-TERT-BUTOXYCARBONYL-4-FORMYL-2,2-DIMETHYL-1,3-OXAZOLIDINE | [CAS]
102308-32-7 | [Synonyms]
1,1-DIMETHYLETHYL-(S)-4-FORMYL-2,2-DIMETHYL-3-OXAZOLIDINE CARBOXYLATE GARNER'S ALDEHYDE (S)-(-)-3-BOC-4-FORMYL-2,2-DIMETHYL-1,3-OXAZOLIDINE (S)-3-BOC-4-FORMYL-2,2-DIMETHYL-1,3-OXAZOLIDINE (S)-(-)-3-TERT-BUTOXYCARBONYL-4-FORMYL-2,2-DIMETHYL-1,3-OXAZOLIDINE (S)-4-FORMYL-2,2-DIMETHYL-OXAZOLIDINE-3-CARBOXYLIC ACID TERT-BUTYL ESTER (S)-N-BOC-2,2-DIMETHYLOXAZOLINDINE-4-CARBOXALDEHYDE TERT-BUTYL (S)-(-)-4-FORMYL-2,2-DIMETHYL-3-OXAZOLIDINECARBOXYLATE TERT-BUTYL (S)-4-FORMYL-2,2-DIMETHYL-3-OXAZOLIDINECARBOXYLATE (S)-(-)-3-tert-Butoxycarbonyl-4-formyl-2,2-dimethyl (S)-4-Formyl-2,2-dimethyl-oxazolidine-3-carboxylictert-butylester (-)-n-boc-n,o-isopropylidene-l-serinal (s)-(-)-3-boc-2,2-dimethyloxazolidine-4-carboxaldehyde (s)-(-)-3-tert-butoxycarbonyl-4-formyl-2,2- 1,1-dimethylethyl-(S)-4-formyl-2,2-dimethyl-3-oxazolidinecarboxylate, 95 % (S)-tert-butyl 4-formyl-2,2-dimethyloxazolidine-3-carboxylate Garners aldehyde, (-)-N-Boc-N,O-isopropylidene-L-serinal, tert-Butyl (S)-(-)-4-formyl-2,2-dimethyl-3-oxazolidinecarboxylate (4S)-2,2-Dimethyl-3-(tert-butoxycarbonyl)oxazolidine-4-carbaldehyde (4S)-2,2-Dimethyl-4α-formyl-3-oxazolidinecarboxylic acid tert-butyl ester (4S)-3-(tert-Butoxycarbonyl)-2,2-dimethyl-1,3-oxazolidine-4-carbaldehyde | [Molecular Formula]
C11H19NO4 | [MDL Number]
MFCD00209557 | [Molecular Weight]
229.27 | [MOL File]
102308-32-7.mol |
Chemical Properties | Back Directory | [Appearance]
Clear colorless to yellow oil | [alpha ]
D -91.7° (c = 1.34 in CHCl3) | [Boiling point ]
83-88 °C1 mm Hg(lit.) | [density ]
1.06 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.445(lit.)
| [Fp ]
226 °F
| [storage temp. ]
Inert atmosphere,2-8°C | [solubility ]
Chloroform (Slightly), Methanol (Slightly) | [form ]
Oil | [pka]
-3.26±0.60(Predicted) | [color ]
Clear colorless to yellow | [optical activity]
[α]20/D 90°, c = 1 in chloroform | [Water Solubility ]
Slightly soluble in water. | [Sensitive ]
Air Sensitive | [BRN ]
3591324 | [CAS DataBase Reference]
102308-32-7(CAS DataBase Reference) |
Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36:Wear suitable protective clothing . S37/39:Wear suitable gloves and eye/face protection . | [WGK Germany ]
3
| [HS Code ]
29349990 |
Hazard Information | Back Directory | [Chemical Properties]
Clear colorless to yellow oil | [Uses]
Widely utilized in the asymmetric synthesis of natural products. | [Uses]
Chiral, non-racemic synthon for asymmetric synthesis of amino sugars and other nitrogen-containing targets. |
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