成人免费xx,国产又黄又湿又刺激不卡网站,成人性视频app菠萝网站,色天天天天

ChemicalBook--->CAS DataBase List--->10102-44-0

10102-44-0

10102-44-0 Structure

10102-44-0 Structure
IdentificationMore
[Name]

NITROGEN DIOXIDE
[CAS]

10102-44-0
[Synonyms]

NITROGEN DIOXIDE
Azote
NA 1067
Nitrito
Nitro
Nitrogen oxide
Nitrous gas or air
Oxoazane oxide
Rcra waste number P078
Stickstoffdioxid
Stikstofdioxyde
NITROGEN DIOXIDE, >=99.5%
Nitrogen oxide (NO2)
NITRICDIOXIDE
Dinitrogen tetroxide, Nitrogen peroxide, Nitrogen tetroxide
[EINECS(EC#)]

233-272-6
[Molecular Formula]

NO2 *
[MDL Number]

MFCD00085341
[Molecular Weight]

46.01
[MOL File]

10102-44-0.mol
Chemical PropertiesBack Directory
[Appearance]

Nitrogen dioxide (and nitrogen tetroxide, the solid dimer) is a dark brown gas (above 21 C) or a yellow, fuming liquid or colorless solid with a pungent, acrid odor. The solid form is colorless below about 11 C; it is found structurally as N2O4.
[Melting point ]

−11 °C(lit.)
[Boiling point ]

21 °C(lit.)
[density ]

2.62 g/mL at 25 °C(lit.)
[vapor density ]

1.58 (21 °C, vs air)
[vapor pressure ]

14.33 psi ( 20 °C)
[solubility ]

reacts with H2O
[form ]

brown gas
[color ]

brown gas; equil with NO 4
[Odor]

Pungent, acrid odor detectable at 0.12 ppm
[Odor Threshold]

0.12ppm
[Water Solubility ]

decomposes in H2O to HNO3 and releases NO; soluble conc H2SO4, HNO3 [MER06]
[Exposure limits]

TLV-TWA 3 ppm (~6 mg/m3) (ACGIH), ceiling in air 5 ppm (MSHA and OSHA); STEL 5 ppm (ACGIH); IDLH 50 ppm (NIOSH).
[CAS DataBase Reference]

10102-44-0(CAS DataBase Reference)
[EPA Substance Registry System]

Nitrogen dioxide (10102-44-0)
Hazard InformationBack Directory
[Chemical Properties]

Nitrogen dioxide (and nitrogen tetroxide, the solid dimer) is a dark brown gas (above 21 C) or a yellow, fuming liquid or colorless solid with a pungent, acrid odor. The solid form is colorless below about 11 C; it is found structurally as N2O4.
[Chemical Properties]

Red to brown gas above 21.1C, brown liquid below 21.1C; colorless solid approximately ?11C.The pressurized liquid is nitrogen tetroxide (dinitrogen tetroxide) because of admixture of N 2O4 with NO2,Noncombustible but supports combustion.
[Uses]

Nitrogen dioxide is an intermediate in producing nitric acid. It also is used in the lead chamber process for making sulfuric acid. It is used as a nitrating and oxidizing agent, in rocket fuels, in the manufacture of hemostatic cotton and other oxidized cellulose compounds, and in bleaching flour. Nitrogen dioxide occurs in trace concentrations in the atmosphere due to oxidation of nitric oxide in air. It also is found in exhaust gases of internal combustion engines, in industrial waste gases from plants using nitric acid, and in cigarette smoke. Brown color of smog in many industrial urban areas is attributed to nitrogen dioxide.
[General Description]

A reddish brown gas or yellowish-brown liquid when cooled or compressed. Shipped as a liquefied gas under own vapor pressure. Vapors are heavier than air. Toxic by inhalation (vapor) and skin absorption. Noncombustible, but accelerates the burning of combustible materials. Cylinders and ton containers may not be equipped with a safety relief device.
[Reactivity Profile]

Nitrogen Dioxide (nitrogen peroxide) is a strong oxidizing agent. Powdered aluminum burns in the vapor of carbon disulfide, sulfur dioxide, sulfur dichloride, nitrous oxide, nitric oxide, or nitrogen peroxide [Mellor 5:209-212. 1946-47]. Boron trichloride reacts energetically with nitrogen peroxide, phosphine, or fat and grease [Mellor 5:132. 1946-47]. Nitrogen peroxide and acetic anhydride reacted to form tetranitromethane, but resulted in an explosion [Van Dolah 1967]. Nitrogen peroxide forms explosive mixtures with incompletely halogenated hydrocarbons [Chem. Eng. News 42(47):53. 1964]. During an experiment to produce lactic acid by oxidizing propylene with nitrogen peroxide, a violent explosion occurred. These mixtures (olefins and nitrogen peroxide) form extremely unstable nitrosates or nitrosites [Comp. Rend. 116:756. 1893]. Contact of very cold liquefied gas with water may result in vigorous or violent boiling of the product and extremely rapid vaporization due to the large temperature differences involved. If the water is hot, there is the possibility that a liquid "superheat" explosion may occur. Pressures may build to dangerous levels if liquid gas contacts water in a closed container [Handling Chemicals Safely 1980]. Corrosive to steel when wet, but may be stored in steel cylinders when moisture content is 0.1% or less.
[Fire Hazard]

Nitrogen dioxide is not combustible (NFPA rating = 0) but is a strong oxidizing agent and will support combustion. Cylinders of NO2 gas exposed to fire or intense heat may vent rapidly or explode.
[Air & Water Reactions]

Combines with oxygen to form NITROGEN DIOXIDE(10102-44-0), a brown gas that is deadly poisonous [Merck 11th ed. (1989]. Decomposes in water to form nitric acid and nitric oxide, reacts with alkalis to form nitrate and nitrites [Merck 11th ed. 1989]. The liquid nitrogen oxide is very sensitive to detonation, in the presence of water.
[Hazard]

Inhalation may be fatal. Can react strongly with reducing materials. Lower respiratory tract irritant. Questionable carcinogen.
[Health Hazard]

Severe exposures may be fatal. Contact may cause burns to skin and eyes. Contact with liquid may cause frostbite. This compound was reported to react with blood to form methemoglobin. The lowest lethal human inhalation dose has been reported at 200 ppm/1 min.
[Potential Exposure]

Nitrogen dioxide is found in automotive and diesel emissions. Nitrogen dioxide is an industrial chemical used as an intermediate in nitric and sulfuric acid manufacture; it is used in the nitration of organic compounds; it is used as an oxidizer in liquid propellant rocket fuel combinations. It is also used in firefighting, welding and brazing.
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and do not induce vomiting. Do not make an unconscious person vomit. Medical observation is recommended for 24 48 hours after breathing overexposure, as pulmonary edema may be delayed. As first aid for pulmonary edema, a doctor or authorized paramedic may consider administering a drug or other inhalation therapy. If frostbite has occurred, seek medical attention immediately; do NOT rub the affected areas or flush them with water. In order to prevent further tissue damage, do NOT attempt to remove frozen clothing from frostbitten areas. If frostbite has NOT occurred, immediately and thoroughly wash contaminated skin with soap and water.
[Shipping]

UN1067/124 Dinitrogen tetroxide, Hazard Class: 2.3; Labels: 2.3-Poisonous gas, 5.1-Oxidizer, 8-Corrosive material, Inhalation Hazard Zone A. UN1975 Nitric oxide and dinitrogen tetroxide mixtures or Nitric oxide and nitrogen dioxide mixtures, Hazard Class: 2.3; Labels: 2.3-Poisonous gas, 5.1-Oxidizer, 8-Corrosive material, Inhalation Hazard Zone A. Cylinders must be transported in a secure upright position, in a well-ventilated truck. Protect cylinder and labels from physical damage. The owner of the compressed gas cylinder is the only entity allowed by federal law (49CFR) to transport and refill them. It is a violation of transportation regulations to refill compressed gas cylinders without the express written permission of the owner.
[Incompatibilities]

A strong oxidizer. Reacts violently with combustible matter, chlorinated hydrocarbons; ammonia, carbon disulfide; reducing materials. Reacts with water, forming nitric acid and nitric oxide. Attacks steel in the presence of moisture.
[Description]

nitrogen dioxide is a reddish-brown gas (or yellow liquid) with a strong, acrid odor. Nitrogen dioxide readily dimerizes to produce N2O4.nitrogen dioxide are nonfl ammable, toxic gases.The federal government has established air quality standards for nitrogen dioxide at 0.053 partsper million (ppm), which equals 100μg (micrograms) per cubic meter.Nitrogen dioxide is highly soluble in water and forms nitric acid (HNO3), and nitric oxide is slightly soluble and forms nitrous acid (HNO2).
Nitrogen dioxide is a strong oxidizing agent and causes corrosion.Nitrogen dioxide is used as an oxidizing agent, a catalyst in oxidation reactions, an inhibitor, as a nitrating agent for organic reactions, as a flour bleaching agent, and in increasing the wet strength of paper.
[Waste Disposal]

Destroy by incineration with the addition of hydrocarbon fuel, controlled in such a way that combustion products are elemental nitrogen, CO2, and water. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal.
[Physical properties]

Reddish-brown gas; pungent irritating odor; liquefies to a yellow liquid at 21.2°C; liquefies under pressure to a brown fuming liquid, commercially known as nitrogen tetroxide which actually is an equilibrium mixture of nitrogen dioxide and dinitrogen tetroxide, N2O4; converts to a colorless crystalline solid at -11.2°C; refractive index 1.40 at 20°C; density of gas in air 1.58 (air=1); density of liquid 1.449 g/mL at 20°C; critical temperature 158.2°C; critical pressure 99.96 atm; decomposes in water forming nitric acid; reacts with alkalies; soluble in concentrated nitric and sulfuric acids; soluble in chloroform and carbon disulfide.
[Occurrence]

Nitrogen dioxide is an intermediate in producing nitric acid. It also is used in the lead chamber process for making sulfuric acid. It is used as a nitrating and oxidizing agent, in rocket fuels, in the manufacture of hemostatic cotton and other oxidized cellulose compounds, and in bleaching flour. Nitrogen dioxide occurs in trace concentrations in the atmosphere due to oxidation of nitric oxide in air. It also is found in exhaust gases of internal combustion engines, in industrial waste gases from plants using nitric acid, and in cigarette smoke. Brown color of smog in many industrial urban areas is attributed to nitrogen dioxide.
[History]

nitrogen dioxide was prepared in 1772 by Joseph Priestley (1733–1804) and described in his volumes Experiments and Observations of Different Kinds of Air published between 1774 and 1786. Priestley called nitric oxide nitrous air, nitrogen dioxide nitrous acid vapor, and nitrous oxide phlogisticated nitrous air, but also referred to the dioxide. Priestley prepared nitric oxide by reacting nitric acid with a metal such as copper: 3Cu(s) + 8HNO3(aq) → 2NO(g) + 3Cu(NO3)2(aq) + 4H2O(l).
[Definition]

A brown gas produced by the dissociation of dinitrogen tetroxide (with which it is in equilibrium), the dissociation being complete at 140°C. Further heating causes dissociation to colorless nitrogen monoxide and oxygen:
2NO2(g) = 2NO(g) + O2(g)
Nitrogen dioxide can also be made by the action of heat on metal nitrates (not the nitrates of the alkali metals or some of the alkaline-earth metals).
[Production Methods]

Nitric oxide (nitrogen monoxide, mononitrogen monoxide; NO) and nitrogen dioxide [nitrogen peroxide, nitrogen tetroxide (NTO); NO2] are often found in dynamic equilibrium. Historically, these compounds sometimes have been erroneously described as “nitrous fumes.” In air, NO is readily oxidized to NO2, and liquefied NO2 (existing principally as its dimer nitrogen tetroxide, N2O4) releases NO2 at room temperature. Thus, these compounds are often grouped as nitrogen oxides (NOx). Other nitrogen oxides include nitrogen trioxide (NO3), dinitrogen trioxide (N2O3), and dinitrogen pentoxide (N2O5). Of all the oxides of nitrogen, NO2 is the most acutely toxic and has been most extensively studied. Accordingly, much of this section focuses on the toxicity of this compound.
Discoveries on the role forNOin biology and medicine led to a 1998 Nobel Prize for Robert Furchgott, Louis J. Ignarro, and Ferid Murad. Nitric oxide and NO2 occur naturally by bacterial degradation of nitrogenous compounds and to a lesser extent from fires, volcanic action, and fixation by lightning. NO has been the subject of intense and extensive research in a vast array of fields including chemistry, molecular biology, pharmaceuticals, and gene therapy. Formed endogenously, NO has a physiological role in blood flow regulation, thrombosis, and neurotransmission, and a pathophysiological role in inflammation, oxidative stress, and host defense. NO is derived from the amino acid L-arginine by five-electron oxidation catalyzed by NO synthase (requiring reduced pyridine nucleotides, reduced biopteridines, and calmodulin). The by-product, citrulline, is recycled back to L-arginine. In the bloodstream, NO binds primarily hemoglobin, is converted to NO3, and is eliminated in the urine with a half-life of 5–8 h.
Nitric oxide is manufactured by passing air through an electric arc or by oxidation of ammonia over platinum gauze.
[Flammability and Explosibility]

Nitrogen dioxide is not combustible (NFPA rating = 0) but is a strong oxidizing agent and will support combustion. Cylinders of NO2 gas exposed to fire or intense heat may vent rapidly or explode.
[Materials Uses]

When dry (0.1 percent moisture or less), nitrogen dioxide is not corrosive to mild steel at ordinary temperatures and pressures. Numerous metals and alloys such as carbon steel, stainless steel, aluminum, nickel, and Inconel are satisfactory for handling and storage. Under wet conditions, stainless steels resistant to about 60 percent nitric acid serve best.
Equipment parts, such as valve stems, which are partly in contact with the atmosphere, should be stainless steel with sufficient chromium content to resist corrosion caused by leaks through stuffing boxes. Good quality ceramic bodies and Pyrex are satisfactory for handling wet or dry nitrogen dioxide.
Among the plastics, Teflon and Kel-F films are most satisfactory. Koroseal and Saran are useful but have a limited service life. In general, the vinyl plastics do not hold up well with nitrogen dioxide. Asbestos and asbestos-graphite are satisfactory for valve stuffing boxes. Koroseal has given reasonably good service in this use. For use on pipe threads, graphite-disodium silicate (waterglass) is recommended, and hydrocarbon lubricants should be avoided.
[Physiological effects]

A major hazard regarding exposure to nitrogen dioxide is that serious effects are not felt until several hours after the exposure. Exposure to nitrogen dioxide at levels of 90 ppm and higher has resulted in delayed pulmonary edema occurring anywhere from a few hours to 72 hours after exposure ceases. Symptoms include cyanosis, shortness of breath, restlessness, headache, and the production of a frothy yellow or brown sputum. With appropriate treatment, symptoms usually resolve rapidly, but can persist for several weeks.
Exposures to nitrogen dioxide of 10 minutes or less at a level of about 150 ppm produces cough, nose and throat irritation, tearing, headache, nausea, and vomiting. Exposures ranging from 50 ppm to 150 ppm have been associated with moderate irritation to the eyes and mucous membranes. Permanent eye damage can occur, however, if exposures at these levels are prolonged. Delayed pulmonary edema may follow exposure to 100 ppm to 150 ppm for only 30-60 minutes, while a few breaths at a concentration of 200 ppm to 700 ppm will produce severe pulmonary damage that may result in fatal pulmonary edema after 5 to 8 hours have elapsed.
Nitrogen dioxide in 10 ppm to 20 ppm concentrations in air is slightly irritating to mucous membranes and the upper respiratory tract. The odor is distinct in concentrations of 5 ppm.Concentrations above 100 ppm in air cause immediate distress. Exposure of the skin to liquid nitrogen dioxide can cause severe bums.
ACGIH recommends the Threshold Limit Value-Time-Weighted Average (TLV-TWA) of 3 ppm (5.6 mg/m3) for nitrogen dioxide. The TLV-TWA is the time-weighted average concentration for a normal 8-hour workday and a 40-hour workweek, to which nearly all workers may be repeatedly exposed, day after day, without adverse effect. ACGIH also recommends the Threshold Limit Value-Short Term Exposure Limit (TLV-STEL) of 5 ppm (904 mg/m3) for nitrogen dioxide. The TLV-STEL is the IS-minute TWA exposure that should not be exceeded at any time during a workday even if the 8-hour TWA is within the TLV-TWA. Exposures above the TLV- TWA up to the STEL should not be longer than 15 minutes and should not occur more than 4 times per day. There should be at least 60 minutes between successive exposures in this range.
OSHA lists a Ceiling Value of 5 ppm (9 mg/m3) for nitrogen dioxide. The Ceiling Value is the exposure limit that shall not be exceeded at any time during the working day. If instantaneous monitoring is not feasible, then the ceiling shall be assessed as a IS-minute TWA exposure that shall not be exceeded at any time during the working day.
[storage]

Cylinders of nitrogen dioxide should be stored and used in a continuously ventilated gas cabinet or fume hood.
[GRADES AVAILABLE]

Nitrogen dioxide is available in grades of 99.5 percent or 99.995 percent.
Safety DataBack Directory
[Hazard Codes ]

T+
[Risk Statements ]

R26:Very Toxic by inhalation.
R34:Causes burns.
[Safety Statements ]

S9:Keep container in a well-ventilated place .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 1067 2.3
[WGK Germany ]

1
[RTECS ]

QX1575000
[DOT Classification]

2.3, Hazard Zone A (Gas poisonous by inhalation)
[HazardClass ]

2.3
[HS Code ]

28112900
[Safety Profile]

Experimental poison by inhalation. Moderately toxic to humans by inhalation. An experimental teratogen. Other experimental reproductive effects. Human systemic effects by inhalation: pulmonary vascular resistance changes, cough, dpspnea, and other pulmonary changes. Mutation data reported. Violent reaction with cyclohexane, F2, formaldehyde, alcohols, nitrobenzene, petroleum, toluene. When heated to decomposition it emits toxic fumes of NOx. See also NITRIC OXIDE.
[Hazardous Substances Data]

10102-44-0(Hazardous Substances Data)
[Toxicity]

LC50 inhal (rat)
88 ppm (4 h)
PEL (OSHA)
5 ppm (9 mg/m3; ceiling)
TLV-TWA (ACGIH)
3 ppm (5.6 mg/m3)
STEL (ACGIH)
5 ppm (9.4 mg/m3)
[IDLA]

13 ppm?
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Nitrogen Tetroxide-->Ozone
[Preparation Products]

2,4,6-TRIFLUOROPHENYL ISOTHIOCYANATE-->Calcium nitrate tetrahydrate-->Hydroxyl Radical-->dinitrogen trioxide-->Water-->potassium L-ascorbate-->NITROUS ACID-->NITRIC OXIDE-->Nitric acid
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

nitrogen dioxide(10102-44-0).msds
Questions And AnswerBack Directory
[Chemical Properties]

Nitrogen dioxide may be present in the form of a yellowish-brown liquid or a reddish-brown gas above 21.1 °C (70 °F) with a pungent acrid odor. It reacts with water to form nitric and nitrous acid and has a vapor pressure of 720 mmHg. It is also a noncombustible liquid or gas that accelerates the burning of combustible materials. Nitrogen dioxide is more toxic than nitrogen oxide.
Nitrogen dioxide
[Preparation]

Nitrogen dioxide may be prepared by several methods. It is produced when an electric discharge is passed through air. It is made commercially from nitric oxide and air. Nitric oxide made by various processes (See Nitric Oxide) rapidly oxidizes to nitrogen dioxide. It is formed by decomposing nitric acid or by oxidizing ammonia with air:
HNO3 → NO2 + H2O
4NH3 + 7O2 → 4NO2 + 6H2O
Also, nitrogen dioxide can be made by heating copper with nitric acid.
In the laboratory, nitrogen dioxide is formed by heating lead nitrate or nitrate of another heavy metal:
2Pb(NO3)2 → 2PbO + 4NO2 + O2
Gaseous mixture of nitrogen dioxide and oxygen is passed through a U-tube placed in a freezing mixture. Nitrogen dioxide condenses and is collected as liquid.
[Reaction]

The oxidation state of nitrogen in nitrogen dioxide is +4. The molecule has an unpaired electron. Both these factors contribute to its reactivity. Nitrogen dioxide readily converts to other forms of nitrogen oxides. It coexists in equilibrium with its dimeric form, N2O4. The latter is more stable at ordinary temperatures.
When heated above 150°C, nitrogen dioxide dissociates to nitric oxide and oxygen:
2NO2 → 2NO + O2
Nitrogen dioxide dissolves in cold water, forming a mixture of nitrous acid and nitric acid:
2NO2 + H2O → HNO2 + HNO3
Nitrous acid readily decomposes to nitric acid and nitric oxide:
3HNO2 → HNO3 + NO + H2O
The overall reaction is as follows:
3NO2 + H2O → 2HNO3 + NO
When dissolved in warm water, no nitrous acid forms.
Nitrogen dioxide is a strong oxidizing agent. It oxidizes both nonmetals and metals, forming their oxides and itself reduced to nitrogen. Thus, sulfur, phosphorus and charcoal burn in nitrogen dioxide to yield oxides of these elements and nitrogen:
2NO2 + 2S → 2SO2 + N2
2NO2 + 2C → 2CO2 + N2
Copper, zinc, iron and many other metals are similarly converted to their oxides when heated with nitrogen dioxide:
2NO2 + 2Cu → 2CuO + N2
2NO2 + 4Zn → 4ZnO + N2
Nitrogen dioxide oxidizes an aqueous solution of iodide to iodine, hydrogen sulfide to sulfur, and carbon monoxide to carbon dioxide. In such reaction, it is reduced to nitric oxide, rather than nitrogen:
NO2 + 2I¯ + H2O → I2 + NO + 2OH¯
NO2 + H2S → NO + H2O + S
NO2 + CO → NO + CO2
With stronger oxidizing agents, nitrogen dioxide acts as a reducing agent.
Thus, it reduces per manganate, MnO4¯, to Mn2+ ion, decolorizing its solution. In this reaction, it is oxidized to nitrate ion:
MnO4¯ + 5NO2 + H2O → Mn2+ +2H+ + 5NO3¯
Reaction with fluorine forms nitryl fluoride, NO2F:
2NO2 + F2 → 2NO2F
Nitrogen dioxide reacts with alkalies, giving a mixture of nitrite and nitrate:
2NO2 + 2OH¯ → NO2¯ + NO3¯ + H2O
Spectrum DetailBack Directory
[Spectrum Detail]

NITROGEN DIOXIDE(10102-44-0)ESR
Tags:10102-44-0 Related Product Information
10102-43-9 10024-97-2 302-01-2 7446-11-9 10544-73-7 7727-43-7 7727-37-9 10102-44-0