| Identification | More | [Name]
4,4'-Methylenebis(N,N-dimethylaniline) | [CAS]
101-61-1 | [Synonyms]
4,4'-BIS(DIMETHYLAMINO)DIPHENYLMETHANE
4,4-BIS(DIMETHYLAMINO)DIPHENYLMETHANE
4,4'-METHYLENEBIS(N,N'-DIMETHYLANILINE)
4,4'-METHYLENEBIS(N,N-DIMETHYLANILINE)
4,4'-TETRAMETHYLDIAMINODIPHENYLMETHANE
ARNOLDS BASE
BIS[4-(DIMETHYLAMINO)PHENYL]METHANE
BIS(P-DIMETHYLAMINOPHENYL)METHANE
METHANE BASE
MICHLER'S HYDRIDE
N,N,N',N'-TETRAMETHYL-4,4'-DIAMINODIPHENYLMETHANE
N,N,N',N'-TETRAMETHYL-4,4'-METHYLENEDIANILINE
P,P'-TETRAMETHYLDIAMINDIPHENYLMETHANE
P,P'-TETRAMETHYLDIAMINODIPHENYLMETHANE
TETRA BASE
TETRAMETHYLDIAMINODIPHENYLMETHANE
,4'-Methylenebisn,N-dimethylaniline
4,4'-(Dimethylamino)diphenylmethane
4,4’-(dimethylamino)diphenylmethane
4,4’-methylenebis(n,n-dimethyl)benzenamine | [EINECS(EC#)]
202-959-2 | [Molecular Formula]
C17H22N2 | [MDL Number]
MFCD00008317 | [Molecular Weight]
254.37 | [MOL File]
101-61-1.mol |
| Chemical Properties | Back Directory | [Appearance]
4,40
-Methylenebis(N,N-dimethyl)benzenamine
is a yellow crystalline compound. | [Melting point ]
88-89 °C(lit.)
| [Boiling point ]
390 °C
| [density ]
1.0344 (rough estimate) | [refractive index ]
1.5794 (estimate) | [Fp ]
178 °C
| [storage temp. ]
2-8°C | [form ]
Crystalline Powder, Crystals and/or Chunks | [pka]
5.57±0.12(Predicted) | [color ]
Off-white or light gray or beige-brown | [Stability:]
Stable. Combustible. Incompatible with strong oxidizing agents, acids, acid chlorides, acid anhydrides, active metals, oxides, chlorates, halogenated compounds, iron chloride, nitro acompounds, peroxides, strong ammonia solution, sulfides, vinyl polymers. | [Water Solubility ]
Insoluble | [Merck ]
14,6176 | [BRN ]
479956 | [InChIKey]
JNRLEMMIVRBKJE-UHFFFAOYSA-N | [CAS DataBase Reference]
101-61-1(CAS DataBase Reference) | [IARC]
2B (Vol. 27, Sup 7, 99) 2010 | [NIST Chemistry Reference]
Benzenamine, 4,4'-methylenebis[N,N-dimethyl-(101-61-1) | [EPA Substance Registry System]
101-61-1(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
T,N,Xi | [Risk Statements ]
R45:May cause cancer.
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment . | [Safety Statements ]
S53:Avoid exposure-obtain special instruction before use .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet . | [RIDADR ]
UN 3077 9/PG 3
| [WGK Germany ]
3
| [RTECS ]
BY5250000
| [Hazard Note ]
Harmful/Irritant | [TSCA ]
Yes | [HazardClass ]
6.1(b) | [PackingGroup ]
III | [HS Code ]
29215990 | [Safety Profile]
Confirmed carcinogen
with experimental carcinogenic,
neoplastigenic, and tumorigenic data.
Moderately toxic by ingestion. Mutation data
reported. A flammable liquid. When heated
to decomposition it emits toxic fumes of
NOx. | [Hazardous Substances Data]
101-61-1(Hazardous Substances Data) |
| Hazard Information | Back Directory | [General Description]
Yellowish glistening leaflets or plates or tan crystals. Weak odor. Sublimes without decomposition. | [Reactivity Profile]
4,4'-METHYLENEBIS(N,N-DIMETHYL)BENZENAMINE(101-61-1) is incompatible with acids, acid chlorides, acid anhydrides and oxidizing agents. 4,4'-METHYLENEBIS(N,N-DIMETHYL)BENZENAMINE(101-61-1) is also incompatible with active metals, potassium, oxides, chlorates, halogenated compounds, iron chloride, nitro compounds, peroxides, strong ammonia solutions, sulfides and vinyl polymers . | [Air & Water Reactions]
Insoluble in water. | [Potential Exposure]
4,40
-methylenebis(N,N-dimethyl) benzenamine is used as an intermediate in dye manufacture
and as an analytical reagent in the determination of lead. | [Fire Hazard]
This chemical is combustible. | [First aid]
Move victim to fresh air. Call 911 or emergency
medical service. Give artificial respiration if victim is not
breathing. Do not use mouth-to-mouth method if victim
ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a oneway valve or other proper respiratory medical device.
Administer oxygen if breathing is difficult. Remove and
isolate contaminated clothing and shoes. In case of contact
with substance, immediately flush skin or eyes with running water for at least 20 minutes. For minor skin contact, avoid spreading material on unaffected skin. Keep
victim warm and quiet. Effects of exposure (inhalation,
ingestion, or skin contact) to substance may be delayed.
Ensure that medical personnel are aware of the material
(s) involved and take precautions to protect themselves.
| [Shipping]
UN3259 Amines, solid, corrosive, n.o.s, or
Polyamines, solid, corrosive, n.o.s., Hazard class: 8;
Labels: 8-Corrosive material, Technical Name Required.
UN3077 Environmentally hazardous substances, solid,
n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous
material, Technical Name Required. | [Incompatibilities]
Strong acids, oxidizers, acid chlorides;
acid anhydrides. | [Description]
4,4-Methylenebis(N,N-dimethyl)benzenamineis a yellow crystalline compound. Molecular weight =254.41; Boiling point = 390℃; Freezing/Melting point =90- 91℃. Hazard Identification (based on NFPA-704 MRating System): Health 2, Flammability 1, Reactivity 0.Insoluble in water. | [Chemical Properties]
4,40
-Methylenebis(N,N-dimethyl)benzenamine
is a yellow crystalline compound. | [Chemical Properties]
yellow to tan crystals | [Uses]
Has been used in manufacture of dyes. As reagent for lead: Dtsch. Med. Wochenschr. 52, 1855 (1926). | [Definition]
ChEBI: 4,4'-Methylenebis(N,N-dimethylaniline) is a diarylmethane. | [Carcinogenicity]
4,4′-Methylenebis(N,N-dimethyl)benzenamine is reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity from studies in experimental animals. | [storage]
Color Code—Blue: Health Hazard/Poison: Store ina secure poison location. Prior to working with this chemicalyou should be trained on its proper handling and storage.4,40-Methylenebis(N,N-dimethyl)benzenamine must be storedto avoid contact with oxidizers (such as perchlorates, peroxides, permanganates, chlorates, and nitrates) and strong acids(such as hydrochloric, sulfuric, and nitric), since violent reactions occur. Store in tightly closed containers in a cool, wellventilated area. A regulated, marked area should be established where this chemical is handled, used, or stored in compliance with OSHA Standard 1910.1045. | [Purification Methods]
Crystallise the base from EtOH (2mL/g) or 95% EtOH (ca 12mL/g). It sublimes on heating. [Beilstein 13 IV 390.] |
| Spectrum Detail | Back Directory | [Spectrum Detail]
4,4'-Methylenebis(N,N-dimethylaniline)(101-61-1)MS
4,4'-Methylenebis(N,N-dimethylaniline)(101-61-1)1HNMR
4,4'-Methylenebis(N,N-dimethylaniline)(101-61-1)13CNMR
4,4'-Methylenebis(N,N-dimethylaniline)(101-61-1)IR1
4,4'-Methylenebis(N,N-dimethylaniline)(101-61-1)IR2
4,4'-Methylenebis(N,N-dimethylaniline)(101-61-1)Raman
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