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ChemicalBook CAS DataBase List TITANIUM MONOXIDE
12137-20-1

TITANIUM MONOXIDE synthesis

2synthesis methods
Titanium monoxide or hongquiite (TiO) may be prepared by direct reduction by mixing stoichiometric amounts of titanium metal and titanium dioxide into a molybdenum crucible at 1600°C or reduction of the titanium dioxide with hydrogen under pressure at 130 atm and 2000°C.
Ti (s) + TiO2(s) —> 2 TiO(s) (1600°C)
-

Yield:-

Reaction Conditions:

with carbon monoxide;ozone in gas;byproducts: O2; titanium atoms vaporized from a filament of Ti deposited on a molybdenum base (heating to 1350-2400 K, vapor pressure: 1E-2 to 1E-1 Torr), entrained in CO (ca. 2.5 Torr), oxidized with O3, Ti(CO)x as intermediate, TiO formed in excited states; luminescence spectroscopy;

References:

McQuaid, M. J.;Morris, K.;Gole, J. L. [Journal of the American Chemical Society,1988,vol. 110,# 16,p. 5280 - 5285]

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