ChemicalBook CAS DataBase List Thianthrene

Thianthrene synthesis

8synthesis methods

Product Name:Thianthrene
CAS Number:92-85-3
Molecular formula:C12H8S2
Molecular Weight:216.32

Thianthrene was first synthesized by John Stenhouse by dry distillation of sodium benzenesulfonate. Thianthrene can be prepared by treating benzene with disulfur dichloride in the presence of aluminium chloride.

615-42-9 Synthesis

615-42-9
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92-85-3
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Yield:92-85-3 82%

Reaction Conditions:

with 1,10-Phenanthroline;potassium carbonate;sulfur in dimethyl sulfoxide at 90; for 12 h;

Steps:

The present invention is achieved in such a way that,To a 25 mL round bottom flask was added o-diiodobenzene (0.5 mmol)Sulfur powder (0.5 mmol),Cuprous iodide (0.05 mmol),1,10-phenanthroline (0.1 mmol),Potassium carbonate (1.0 mmol) andDimethyl sulfoxide (2 mL).The resulting mixture was stirred at 90 ° C for 12 hours.After cooling to room temperature, add 10 mL of water to the system,Then extracted with ethyl acetate (3 x 10 mL) and dried over anhydrous sodium sulfate. After the solvent was distilled off,The resulting residue was purified by silica gel column chromatography in 82% yield.

References:

Jiangxi Normal University;Wan Jieping;Liu Yunyun;Zhang Yi CN104844565, 2017, B Location in patent:Paragraph 0006; 0009; 0010; 0011

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139-66-2 Synthesis